Composition comprising HF and 3,3,3-trifluoropropene

ABSTRACT

An azeotropic or quasi-azeotropic composition including hydrogen fluoride, 3,3,3-trifluoropropene and one or more (hydro)halogen-carbon compounds including between 1 and 3 carbon atoms. Also, a preferred azeotropic or quasi-azeotropic composition including hydrogen fluoride, 3,3,3-trifluoropropene, and one or more compounds selected from among 1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene, 1,3,3,3-tetrafluoropropene, 3,3,3-trifluoro-2-chloropropene, E-3,3,3-trifluoro-l-chloropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro, 1,1,1,2-tetrafluoropropane.

The present invention relates to azeotropic or quasi-azeotropiccompositions comprising 3,3,3-trifluoropropene and hydrogen fluoride.These compositions may originate from intermediate compositions in theproduction of 3,3,3-trifluoropropene and are generally useful inprocesses for recycling hydrogen fluoride.

The manufacture of 3,3,3-trifluoropropene accompanied by a multitude ofby-products, having a boiling point close to HFO-1243zf, leads torelatively complex and expensive purification steps. The difficultyencountered during the purification of HFO-1243zf generally implies anappreciable loss of desired product. Furthermore, these by-products mayform azeotropic compositions with 1,3,3,3-tetrafluoropropene, makingseparation by distillation simple, very difficult, or even impossible.

Fluids based on 3,3,3-trifluoropropene have found numerous applicationsin varied industrial fields, especially as heat-transfer fluid,propellants, foaming agents, swelling agents, gaseous dielectrics,polymerization medium or monomer, support fluids, abrasive agents,drying agents and fluids for power production units.

Particular importance is given to fluids that have a low impact on theenvironment.

The subject of the present invention is an azeotropic orquasi-azeotropic composition comprising hydrogen fluoride,3,3,3-trifluoropropene and one or more (hydro)halocarbon compoundscomprising between 1 and 3 carbon atoms. According to one embodiment ofthe invention, the composition is heteroazeotropic orquasi-heteroazeotropic.

A heteroazeotropic or quasi-heteroazeotropic mixture is an azeotropic orquasi-azeotropic mixture in which the condensed liquid forms twoimmiscible solutions that can be readily separated, for example bydecantation.

The term “quasi-azeotropic” or “quasi-heteroazeotropic” has a broadmeaning and is intended to include compositions that are strictlyazeotropic or strictly heteroazeotropic and those that behave like anazeotropic or heteroazeotropic mixture.

A mixture is azeotropic when the pressure at the dew point is equal tothat at the bubble formation point, which means that the vaporcomposition is equal to that of the condensed liquid.

A mixture is considered as quasi-azeotropic when the pressure at the dewpoint is substantially equal to that at the bubble formation point,which means that the vapor composition is substantially equal to that ofthe condensed liquid.

Another way of characterizing a mixture as quasi-azeotropic when thepressure difference between the pressure at the dew point and thepressure at the bubble formation point is low, preferentially less thanor equal to 5%, on the basis of the pressure at the bubble formationpoint.

The compositions according to the invention especially concern thefollowing compounds, the acronyms of which represent:

-   -   HF: hydrogen fluoride    -   HCC-40: chloromethane, or CH₃Cl    -   HCFC-115: chloropentafluoroethane, or C₂F₅Cl    -   HCFC-124: chlorotetrafluoroethane, or C₂HF₄Cl    -   HFC-125: pentafluoroethane, or C₂HF₅    -   HCFC-133a: 1-chloro-2,2,2-trifluoroethane, or C₂H₂F₃Cl    -   HFC-134a: 1,1,1,2-tetrafluoroethane, or C₂H₂F₄    -   HCFC-142b: 1-chloro-1,1-difluoroethane, or C₂H₃F₂Cl    -   HFC-143a: 1,1,1-trifluoroethane, or C₂H₃F₃    -   HFC-152a: 1,1-difluoroethane, or C₂H₄F₂    -   HFO-1132: 1,2-difluoroethylene, or C₂H₂F₂    -   HFO-1141: fluoroethylene, or C₂H₃F    -   HFO-1234yf: 2,3,3,3-tetrafluoropropene or CH₂═CF—CF₃    -   HFC-245cb: 1,1,1,2,2-pentafluoropropane or CF₃—CF₂—CH₃    -   HFO-1234zeE: E-1,3,3,3-tetrafluoropropene or E-CF₃—CH═CHF    -   HFO-1234zeZ: Z-1,3,3,3-tetrafluoropropene or Z—CF₃—CH═CHF    -   HFO-1243zf: 3,3,3-trifluoropropene or CF₃—CH═CH₂    -   HCFO-1233xf: 3,3,3-trifluoro-2-chloropropene or CF₃—CCl═CH₂    -   HCFO-1233zdE: E-3,3,3-trifluoro-1-chloropropene or E-CF₃—CH═CHCl    -   HCFO-1233zdZ: Z-3,3,3-trifluoro-1-chloropropene or Z—CF₃—CH═CHCl    -   HFO-1225yeZ: Z-1,1,1,2,3-pentafluoropropene or Z—CHF═CF—CF₃    -   HFO-1225yeE: E-1,1,1,2,3-pentafluoropropene or E-CHF═CF—CF₃    -   HFO-1225zc: 1,1,3,3,3-pentafluoropropene or CF₂═CH—CF₃    -   HFO-1225yc: 1,1,2,3,3-pentafluoropropene or CF₂═CF—CF₂    -   HCFC-1214: dichlorotetrafluoropropene, or C₃F₄Cl₂    -   HCFO-1215: chloropentafluoropropene, or C₃F₅Cl    -   HFO-1216: hexafluoropropene, or C₃F₆    -   HCFO-1223: dichlorotrifluoropropene, or C₃HF₃Cl₂    -   HCFO-1224: chlorotetrafluoropropene, or C₃HF₄Cl    -   HCFO-1232: dichlorodifluoropropene, or C₃H₂F₂Cl₂    -   HCFO-1233xc: 1,1,3-trifluoro-2-chloropropene or CH₂F—CCl═CF₂    -   HCFO-1233xe: 1,3,3-trifluoro-2-chloropropene or CHF₂—CCl═CHF    -   HCFO-1233yb: 1,2,3-trifluoro-1-chloropropene or CH₂F—CF═CFCl    -   HCFO-1233yc: 1,1,2-trifluoro-3-chloropropene or CH₂Cl—CF═CF₂    -   HCFO-1233yd: 2,3,3-trifluoro-1-chloropropene or CHF₂—CF═CHCl    -   HCFO-1233ye: 1,2,3-trifluoro-3-chloropropene or CHClF—CF═CHF    -   HCFO-1233yf: 2,3,3-trifluoro-3-chloropropene or CClF₂—CF═CH₂    -   HCFO-1233zb: 1,3,3-trifluoro-1-chloropropene or CHF₂—CH═CFCl    -   HCFO-1233zc: 1,1,3-trifluoro-3-chloropropene or CHClF—CH═CF₂    -   HCFO-1233ze: 1,3,3-trifluoro-3-chloropropene or CClF₂—CH═CHF    -   HFO-1234yc: 1,2,3-tetrafluoropropene or CF₂═CF—CH₂F    -   HFO-1234ye: 2,3,3-tetrafluoropropene or CHF═CF—CHF₂    -   HFO-1234zc: 1,3,3-tetrafluoropropene or CF₂═CH—CHF₂    -   HCFO-1242: chlorodifluoropropene, or C₃H₃F₂Cl    -   HFO-1243yc: 1,1,2-trifluoropropene or CH₃—CF═CF₂    -   HFO-1243ye: 1,2,3-trifluoropropene or CH₂F—CF═CHF    -   HFO-1243yf: 2,3,3-trifluoropropene or CHF₂—CF═CH₂    -   HFO-1243zc: 1,1,3-trifluoropropene or CH₂F—CH═CF₂    -   HFO-1243ze: 1,3,3-trifluoropropene or CHF₂—CH═CHF    -   HCFO-1251: chlorofluoropropene, or C₃H₄FCl    -   HFO-1252: difluoropropene, or C₃H₄F₂    -   HFO-216: hexafluoropropene, or C₃F₆Cl₂    -   HCFO-217: chloroheptafluoropropane, or C₃F₇Cl    -   HFC-218: octafluoropropane, or C₃F₈    -   HCFC-225: dichloropentafluoropropane, or C₃HF₅Cl₂    -   HCFC-226: chlorohexafluoropropane, or C₃HF₆Cl    -   HFC-227: heptafluoropropane, or C₃HF₇    -   HCFC-234: dichlorotetrafluoropropane, or C₃H₂F₄Cl₂    -   HCFC-235: chloropentafluoropropane, or C₃H₂F₅Cl    -   HFC-236: hexafluoropropane, or C₃H₂F₆    -   HCFC-243: dichlorotrifluoropropane, or C₃H₃F₃Cl₂    -   HCFC-244: chlorotetrafluoropropane, or C₃H₃F₄Cl    -   HCFC-244bb: 2-chloro-1,1,1,2-tetrafluoropropane or CF₃—CFCl—CH₃    -   HFC-245fa: 1,1,1,3,3-pentafluoropropane or CF₃—CH₂—CHF₂    -   HFC-245ea: 1,1,2,3,3-pentafluoropropane or CHF₂—CHF—CHF₂    -   HFC-245eb: 1,1,1,2,3-pentafluoropropane or CF₃—CHF—CH₂F    -   HFC-245ca: 1,1,2,2,3-pentafluoropropane or CHF₂—CF₂—CH₂F    -   HCFC-253: chlorotrifluoropropane, or C₃H₄F₃Cl    -   HFC-254: tetrafluoropropane, or C₃H₄F₄    -   HCFC-262: chlorodifluoropropane, or C₃H₅F₂Cl    -   HFC-263: trifluoropropane, or C₃H₅F₃    -   trifluoropropyne: CF₃—C≡CH

The composition according to the invention may optionally be a mixtureof one or more azeotropes and/or heteroazeotropes of ternary,quaternary, penternary systems, systems with six compounds, systems withseven compounds, systems with eight or more compounds.

The compound(s) containing 1 and/or 2 carbon atoms may be chosenespecially from chloromethane, chloropentafluoroethane,1-chloro-1,2,2,2-tetrafluoroethane, 1-chloro-1,1,2,2-tetrafluoroethane,pentafluoroethane, 1-chloro-1,2,2-trifluoroethane,1-chloro-2,2,2-trifluoroethane, 1,1,2,2-tetrafluoroethane,1,1,1,2-tetrafluoroethane, 1-chloro-1,2-difluoroethane,1-chloro-1,1-difluoroethane, 1,1,2-trifluoroethane,1,1,1-trifluoroethane, 1,1,2-trifluoroethane, 1,1-difluoroethane,1,2-difluoroethylene and fluoroethylene.

The compound(s) containing 3 carbon atoms may be chosen especially from1,2-dichloro-1,1,2,3,3,3-hexafluoropropane,1,3-dichloro-1,1,2,2,3,3-hexafluoropropane,1,1-dichloro-1,2,2,3,3,3-hexafluoropropane,2,2-dichloro-1,1,1,3,3,3-hexafluoropropane,1-chloro-1,1,2,2,3,3,3-heptafluoropropane,2-chloro-1,1,1,2,3,3,3-heptafluoropropane, octafluoropropane,dichloropentafluoropropane, 2,2-dichloro-1,1,1,3,3-pentafluoropropane,2,3-dichloro-1,1,1,2,3-pentafluoropropane,1,2-dichloro-1,1,2,3,3-pentafluoropropane,3,3-dichloro-1,1,1,2,2-pentafluoropropane,1,3-dichloro-1,1,2,2,3-pentafluoropropane,1,1-dichloro-1,2,2,3,3-pentafluoropropane,1,2-dichloro-1,1,3,3,3-pentafluoropropane,1,3-dichloro-1,1,2,3,3-pentafluoropropane,1,1-dichloro-1,2,3,3,3-pentafluoropropane, chlorohexafluoropropane,2-chloro-1,1,1,2,3,3-hexafluoropropane,3-chloro-1,1,1,2,2,3-hexafluoropropane,1-chloro-1,1,2,2,3,3-hexafluoropropane,2-chloro-1,1,1,3,3,3-hexafluoropropane,1-chloro-1,1,2,3,3,3-hexafluoropropane,1,1,2,2,3,3,3-heptafluoropropane, 1,1,1,2,3,3,3-Heptafluoropropane,dichlorotetrafluoropropane, 2,2-dichloro-1,1,3,3-tetrafluoropropane,2,2-dichloro-1,1,1,3-tetrafluoropropane,1,2-dichloro-1,2,3,3-tetrafluoropropane,2,3-dichloro-1,1,1,2-tetrafluoropropane,1,2-dichloro-1,1,2,3-tetrafluoropropane,1,3-dichloro-1,2,2,3-tetrafluoropropane,1,1-dichloro-2,2,3,3-tetrafluoropropane,1,3-dichloro-1,1,2,2-tetrafluoropropane,1,1-dichloro-1,2,2,3-tetrafluoropropane,2,3-dichloro-1,1,1,3-tetrafluoropropane,1,3-dichloro-1,1,3,3-tetrafluoropropane,1,3-dichloro-1,1,3,3-tetrafluoropropane,1,1-dichloro-1,3,3,3-tetrafluoropropane,1,1-dichloro-2,3,3,3-tetrafluoropropane,1,3-dichloro-1,1,2,3-tetrafluoropropane,1,1-dichloro-1,2,3,3-tetrafluoropropane, chloropentafluoropropane,1-chloro-1,2,2,3,3-pentafluoropropane,3-chloro-1,1,1,2,3-pentafluoropropane,1-chloro-1,1,2,2,3-pentafluoropropane,2-chloro-1,1,1,3,3-pentafluoropropane,1-chloro-1,1,3,3,3-pentafluoropropane,1-chloro-1,1,2,3,3-pentafluoropropane,3-chloro-1,1,1,2,2-pentafluoropropane,2-chloro-1,1,2,3,3-pentafluoropropane,2-chloro-1,1,1,2,3-pentafluoropropane, 1,1,1,2,2,3-hexafluoropropane,1,1,1,2,3,3-hexafluoropropane, 1,1,1,3,3,3-hexafluoropropane,1,1,2,2,3,3-hexafluoropropane, dichlorotrifluoropropane,1,1-dichloro-3,3,3-trifluoropropane,1,3-dichloro-1,1,3-trifluoropropane,1,1-dichloro-1,3,3-trifluoropropane,1,3-dichloro-1,2,3-trifluoropropane,1,1-dichloro-2,3,3-trifluoropropane,1,3-dichloro-1,1,2-trifluoropropane,1,1-dichloro-1,2,3-trifluoropropane,1,2-dichloro-1,3,3-trifluoropropane,2,3-dichloro-1,1,1-trifluoropropane,1,2-dichloro-1,1,3-trifluoropropane,1,3-dichloro-1,2,2-trifluoropropane,1,1-dichloro-2,2,3-trifluoropropane,1,1-dichloro-1,2,2-trifluoropropane,2,3-dichloro-1,1,2-trifluoropropane,1,2-dichloro-1,2,3-trifluoropropane,1,2-dichloro-1,1,2-trifluoropropane,2,2-dichloro-1,1,3-trifluoropropane,2,2-dichloro-3,3,3-trifluoropropane, chlorotetrafluoropropane,2-chloro-1,2,3,3-tetrafluoropropane,2-chloro-1,1,1,2-tetrafluoropropane,3-chloro-1,1,2,2-tetrafluoropropane,1-chloro-1,2,2,3-tetrafluoropropane,1-chloro-1,1,2,2-tetrafluoropropane,2-chloro-1,1,3,3-tetrafluoropropane,2-chloro-1,1,1,3-tetrafluoropropane,3-chloro-1,1,2,3-tetrafluoropropane,3-chloro-1,1,1,2-tetrafluoropropane,1-chloro-1,1,2,3-tetrafluoropropane,3-chloro-1,1,1,3-tetrafluoropropane,1-chloro-1,1,3,3-tetrafluoropropane, pentafluoropropane,1,1,2,2,3-pentafluoropropane, 1,1,2,3,3-pentafluoropropane,1,1,1,2,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropane,chlorotrifluoropropane, 2-chloro-1,2,3-trifluoropropane,2-chloro-1,1,2-trifluoropropane, 1-chloro-2,2,3-trifluoropropane,1-chloro-1,2,2-trifluoropropane, 3-chloro-1,1,2-trifluoropropane,1-chloro-1,2,3-trifluoropropane, 1-chloro-1,1,2-trifluoropropane,3-chloro-1,3,3-trifluoropropane, 3-chloro-1,1,1-trifluoropropane,1-chloro-1,1,3-trifluoropropane, 2-chloro-1,1,3-trifluoropropane,2-chloro-1,1,1-trifluoropropane, 1,1,2,2-tetrafluoropropane,1,1,1,3-tetrafluoropropane, 1,1,2,3-tetrafluoropropane,1,1,1,2-tetrafluoropropane, 1,2,2,3-tetrafluoropropane,1,1,3,3-tetrafluoropropane, chlorodifluoropropane,1-chloro-2,2-difluoropropane, 3-chloro-1,1-difluoropropane,1-chloro-1,3-difluoropropane, 1-chloro-1,1-difluoropropane,1-chloro-2,3-difluoropropane, 1-chloro-1,2-difluoropropane,2-chloro-1,3-difluoropropane, 2-chloro-1,1-difluoropropane,2-chloro-1,2-difluoropropane, trifluoropropane, 1,1,1-trifluoropropane,1,1,3-trifluoropropane, 1,2,3-trifluoropropane, 1,1,2-trifluoropropane,1,2,2-trifluoropropane, dichlorotetrafluoropropene,1,2-dichloro-1,3,3,3-tetrafluoropropene,1,1-dichloro-2,3,3,3-tetrafluoropropene,1,3-dichloro-1,2,3,3-tetrafluoropropene,2,3-dichloro-1,1,3,3-tetrafluoropropene,3,3-dichloro-1,1,2,3-tetrafluoropropene, chloropentafluoropropene,1-chloropentafluoropropene, 2-chloropentafluoropropene,3-chloropentafluoropropene, hexafluoropropene, dichlorotrifluoropropene,1,1-dichloro-3,3,3-trifluoropropene,1,2-dichloro-3,3,3-trifluoropropene,2,3-dichloro-1,3,3-trifluoropropene,1,3-dichloro-2,3,3-trifluoropropene,1,2-dichloro-1,3,3-trifluoropropene,2,3-dichloro-1,1,3-trifluoropropene,1,1-dichloro-2,3,3-trifluoropropene,1,3-dichloro-1,2,3-trifluoropropene,3,3-dichloro-1,1,2-trifluoropropene,3,3-dichloro-1,2,3-trifluoropropene,1,3-dichloro-1,3,3-trifluoropropene,3,3-dichloro-1,1,3-trifluoropropene,1-chloro-2,3,3,3-tetrafluoropropene,1-chloro-1,3,3,3-tetrafluoropropene,2-chloro-1,3,3,3-tetrafluoropropene,3-chloro-1,2,3,3-tetrafluoropropene,3-chloro-1,1,3,3-tetrafluoropropene,2-chloro-1,1,3,3-tetrafluoropropene,1-chloro-1,2,3,3-tetrafluoropropene,3-chloro-1,1,2,3-tetrafluoropropene, 1,2,3,3,3-pentafluoropropene,1,1,3,3,3-pentafluoropropene, 1,1,2,3,3-pentafluoropropene,dichlorodifluoropropene, 2,3-dichloro-3,3-difluoropropene,1,2-dichloro-1,3-difluoropropene, 2,3-dichloro-1,1-difluoropropene,1,2-dichloro-3,3-difluoropropene, 2,3-dichloro-1,3-difluoropropene,1,1-dichloro-2,3-difluoropropene, 1,3-dichloro-1,2-difluoropropene,1,3-dichloro-2,3-difluoropropene, 3,3-dichloro-1,2-difluoropropene,3,3-dichloro-2,3-difluoropropene, 1,1-dichloro-3,3-difluoropropene,1,3-dichloro-1,3-difluoropropene, 3,3-dichloro-1,1-difluoropropene,1,3-dichloro-3,3-difluoropropene, 3,3-dichloro-1,3-difluoropropene,chlorotrifluoropropene, 2-chloro-1,1,3-trifluoropropene,2-chloro-1,3,3-trifluoropropene, 1-chloro-1,2,3-trifluoropropene,3-chloro-1,1,2-trifluoropropene, 1-chloro-2,3,3-trifluoropropene,3-chloro-1,2,3-trifluoropropene, 3-chloro-2,3,3-trifluoropropene,1-chloro-1,3,3-trifluoropropene, 3-chloro-1,1,3-trifluoropropene,3-chloro-1,3,3-trifluoropropene, 1,1,2,3-tetrafluoropropene,1,2,3,3-tetrafluoropropene, 1,1,3,3-tetrafluoropropene,chlorodifluoropropene, 3-chloro-3,3-difluoropropene,3-chloro-1,3-difluoropropene, 2-chloro-1,1-difluoropropene,2-chloro-1,3-difluoropropene, 2-chloro-3,3-difluoropropene,1-chloro-1,2-difluoropropene, 1-chloro-2,3-difluoropropene,3-chloro-1,2-difluoropropene, 3-chloro-2,3-difluoropropene,1-chloro-1,3-difluoropropene, 3-chloro-1,1-difluoropropene,1-chloro-3,3-difluoropropene, trifluoropropene, 1,1,2-trifluoropropene,1,2,3-trifluoropropene, 2,3,3-trifluoropropene, 1,1,3-trifluoropropene,1,3,3-trifluoropropene, chlorofluoropropene, 1-chloro-3-fluoropropene,1-chloro-1-fluoropropene, 1-chloro-2-fluoropropene,2-chloro-1-fluoropropene, 2-chloro-3-fluoropropene,3-chloro-2-fluoropropene, 3-chloro-1-fluoropropene,3-chloro-3-fluoropropene, difluoropropene, 1,2-difluoropropene,2,3-difluoropropene, 1,1-difluoropropene, 1,3-difluoropropene,3,3-difluoropropene, 1,1,1,2,2-pentafluoropropane,E-1,3,3,3-tetrafluoropropene, Z-1,3,3,3-tetrafluoropropene,3,3,3-trifluoropropene, 3,3,3-trifluoro-2-chloropropene,E-3,3,3-trifluoro-1-chloropropene, Z-3,3,3-trifluoro-1-chloropropene andtrifluoropropyne.

A subject of the present invention is also an azeotropic orquasi-azeotropic composition comprising hydrogen fluoride,3,3,3-trifluoropropene, and one or more compounds chosen from1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene,E-3,3,3-trifluoro-1-chloropropene, 3,3,3-trifluoro-2-chloropropene,1,3,3,3-tetrafluoropropene, trifluoropropyne,1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene,1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.

A subject of the present invention is also a composition comprisinghydrogen fluoride, 3,3,3-trifluoropropene and at least one or moreorganic compounds chosen from E-1,3,3,3-tetrafluoropropene,Z-1,3,3,3-tetrafluoropropene, 3,3,3-trifluoro-2-chloropropene,E-3,3,3-trifluoro-1-chloropropene, 1,1,1,2,2-pentafluoropropane and2,3,3,3-tetrafluoropropene.

According to one embodiment, the composition according to the inventioncomprises hydrogen fluoride, 3,3,3-trifluoropropene,1,1,1,2,2-heptafluoropropane and optionally one or more compounds chosenfrom 2,3,3,3-tetrafluoropropene, E-3,3,3-trifluoro-1-chloropropene,3,3,3-trifluoro-2-chloropropene, 1,3,3,3-tetrafluoropropene,trifluoropropyne, 1,1,1,3,3-pentafluoropropane,1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and2-chloro-1,1,1,2-tetrafluoropropane.

According to another embodiment, the composition according to theinvention comprises hydrogen fluoride, 3,3,3-trifluoropropene,2,3,3,3-tetrafluoropropene and optionally one or more compounds chosenfrom E-3,3,3-trifluoro-1-chloropropene, 3,3,3-trifluoro-2-chloropropene,1,3,3,3-tetrafluoropropene, trifluoropropyne,1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene,1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.

According to one embodiment, the composition according to the inventioncomprises hydrogen fluoride, 3,3,3-trifluoropropene,E-3,3,3-trifluoro-1-chloropropene and optionally one or more compoundschosen from 3,3,3-trifluoro-2-chloropropene, 1,3,3,3-tetrafluoropropene,trifluoropropyne, 1,1,1,3,3-pentafluoropropane,1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and2-chloro-1,1,1,2-tetrafluoropropane.

According to another embodiment, the composition according to theinvention comprises hydrogen fluoride, 3,3,3-trifluoropropene,3,3,3-trifluoro-2-chloropropene and optionally one or more compoundschosen from 1,3,3,3-tetrafluoropropene, trifluoropropyne,1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene,1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.

According to one embodiment, the composition according to the inventioncomprises hydrogen fluoride, 3,3,3-trifluoropropene,1,3,3,3-tetrafluoropropene and optionally one or more compounds chosenfrom trifluoropropyne, 1,1,1,3,3-pentafluoropropene,1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and2-chloro-1,1,1,2-tetrafluoropropane.

According to another embodiment, the composition according to theinvention comprises hydrogen fluoride, 3,3,3-trifluoropropene,trifluoropropyne and optionally one or more compounds chosen from1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene,1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.

According to one embodiment, the composition according to the inventioncomprises hydrogen fluoride, 3,3,3-trifluoropropene,1,1,1,3,3-pentafluoropropane and optionally one or more compounds chosenfrom 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and2-chloro-1,1,1,2-tetrafluoropropane.

According to another embodiment, the composition according to theinvention comprises hydrogen fluoride, 3,3,3-trifluoropropene,1,1,1,3,3-pentafluoropropene and optionally one or more compounds chosenfrom 1,1,1,2,3-pentafluoropropene and2-chloro-1,1,1,2-tetrafluoropropane.

According to one embodiment, the composition according to the inventioncomprises hydrogen fluoride, 3,3,3-trifluoropropene,1,1,1,2,3-pentafluoropropene and optionally2-chloro-1,1,1,2-tetrafluoropropane.

According to another embodiment, the composition according to theinvention comprises hydrogen fluoride, 3,3,3-trifluoropropene and2-chloro-1,1,1,2-tetrafluoropropane.

According to another embodiment, the composition according to theinvention comprises hydrogen fluoride, 3,3,3-trifluoropropene,E-1,3,3,3-tetrafluoropropene and optionally one or more compounds chosenfrom Z-1,3,3,3-tetrafluoropropene, 3,3,3-trifluoro-2-chloropropene,E-3,3,3-trifluoro-1-chloropropene, 1,1,1,2,2-pentafluoropropane,2,3,3,3-tetrafluoropropene, trifluoropropyne,1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene,1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.

According to one embodiment of the invention, the composition compriseshydrogen fluoride, 3,3,3-trifluoropropene, Z-1,3,3,3-tetrafluoropropeneand optionally one or more compounds chosen from3,3,3-trifluoro-2-chloropropene, E-3,3,3-trifluoro-1-chloropropene,1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene,trifluoropropyne, 1,1,1,3,3-pentafluoropropane,1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and2-chloro-1,1,1,2-tetrafluoropropane.

According to another embodiment, the composition according to theinvention comprises hydrogen fluoride, 3,3,3-trifluoropropene,3,3,3-trifluoro-2-chloropropene and optionally one or more compoundschosen from E-3,3,3-trifluoro-1-chloropropene,1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene,trifluoropropyne, 1,1,1,3,3-pentafluoropropane,1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and2-chloro-1,1,1,2-tetrafluoropropane.

According to one embodiment of the invention, the composition compriseshydrogen fluoride, 3,3,3-trifluoropropene,E-3,3,3-trifluoro-1-chloropropene and optionally one or more compoundschosen from 1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene,trifluoropropyne, 1,1,1,3,3-pentafluoropropane,1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and2-chloro-1,1,1,2-tetrafluoropropane.

According to another embodiment, the composition according to theinvention comprises hydrogen fluoride, 3,3,3-trifluoropropene,1,1,1,2,2-pentafluoropropane and optionally one or more compounds chosenfrom 2,3,3,3-tetrafluoropropene, trifluoropropyne,1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene,1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.

According to one embodiment of the invention, the composition compriseshydrogen fluoride, 3,3,3-trifluoropropene, 2,3,3,3-tetrafluoropropeneand optionally one or more compounds chosen from trifluoropropyne,1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene,1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.

Irrespective of the embodiment, the composition preferably comprisesfrom 1% to 95% and advantageously from 5% to 80% by weight of hydrogenfluoride and from 99% to 5% and advantageously from 20% to 95% by weightof the sum of the organic compounds; more particularly, the compositioncomprises from 1% to 85% by weight of hydrogen fluoride and from 99% to15% by weight of the sum of the organic compounds (HFO-1243zf and the(hydro)halocarbon compounds).

Irrespective of the embodiment, the boiling point of the compositionaccording to the invention is between −20° C. and 80° C. and at apressure between 0.1 and 44 bar absolute, preferentially between 0° C.and 40° C. and preferentially at a pressure of between 0.7 and 18 barabsolute, advantageously between 0.9 and 12.5 bar absolute.

The Applicant has discovered that the compositions according to theinvention have advantageous properties in particular for the recyclingof HF in the reaction step. Thus, the condensed phase of thesecompositions, optionally when they are subjected to a distillation stepand/or a liquid/liquid separation step, such as by decantation, form twoimmiscible liquid phases.

By way of example, for the ternary compounds containing hydrogenfluoride, 3,3,3-trifluoropropene and a compound chosen from1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene,3,3,3-trifluoro-2-chloropropene, 1,3,3,3-tetrafluoropropene andE-3,3,3-trifluoro-1-chloropropene, the appearance of a heteroazeotropecharacterized by two liquid phases, one rich in HF and the otherdepleted in HF, depends on the amount of HF in the composition. Thesedecantation ranges as a function of the HF content in the compositionswere characterized for at least isotherms at 0° C., 25° C. and 40° C.

Similarly, the decantation ranges for the ternary compounds containinghydrogen fluoride, 3,3,3-trifluoropropene and a compound chosen fromtrifluoropropyne, 1,1,1,3,3-pentafluoropropane,1,1,1,3,3-pentafluoropropene, Z-1,1,1,2,3-pentafluoropropene and2-chloro-1,1,1,2-tetrafluoropropane are characterized by a phasedepleted in HF and a phase enriched in HF for at least isotherms at 0°C., 25° C. and 40° C.

An azeotropic or quasi-azeotropic composition that is preferredaccording to the invention comprises from 1% to 85% by weight ofhydrogen fluoride and from 99% to 15% by weight of the sum of HFO-1243zfand of HFC-245cb, the boiling point of this preferred composition isbetween 0 and 40° C. at a pressure of between 0.9 and 11.6 bar absolute.

An azeotropic or quasi-azeotropic composition that is preferredaccording to the invention preferably comprises from 5% to 80% by weightof hydrogen fluoride and from 95% to 20% by weight of the sum ofHFO-1243zf and of HFC-245cb, the boiling point of this preferredcomposition is between 0 and 40° C. at a pressure of between 0.9 and11.6 bar absolute.

An azeotropic or quasi-azeotropic composition that is preferredaccording to the invention preferably comprises from 1% to 85% by weightof hydrogen fluoride and from 99% to 15% by weight of the sum ofHFO-1243zf, of HCFC-244bb, of HFC-245fa, of trifluoropropyne, ofHFO-1225yeZ and of HFO-1225zc, the boiling point of this preferredcomposition is between 0 and 40° C. at a pressure of between 0.7 and 18bar absolute.

An azeotropic or quasi-azeotropic composition that is preferredaccording to the invention preferably comprises from 5% to 80% by weightof hydrogen fluoride and from 95% to 20% by weight of the sum ofHFO-1243zf, of HCFC-244bb, of HFC-245fa, of trifluoropropyne, ofHFO-1225yeZ and of HFO-1225zc, the boiling point of this preferredcomposition is between 0 and 40° C. at a pressure of between 0.7 and 18bar absolute.

The pressure characteristics of the mixtures of Examples 1, 4, 7, 10,13, 16 and 19 were calculated for an isotherm at 25° C.

Examples 2, 5, 8, 11, 14, 17 and 20 represent the boiling point andpressure ranges of the mixtures and Examples 3, 6, 9, 12, 15, 18 and 21represent the decantation ranges of the mixtures of Examples 1, 4, 7,10, 13, 16 and 19 as a function of the mass percentage of HFcharacterized for isotherms at 0° C., 25° C. and 40° C. The decantationranges of Examples 3, 6, 9, 12, 15, 18 and 21 are calculated formixtures of organic compounds having equal-mass contents. By way ofexample, for a ternary mixture, a mixture containing 50% by weight ofeach of the two organic compounds is considered; for a penternarymixture, a mixture containing 25% by weight of each of the four organiccompounds is considered, the mass fraction of HF ranging from 0 to 1.These calculations are performed at the liquid-vapor equilibrium, underazeotropic conditions.

EXAMPLE 1: TERNARY MIXTURES, ISOTHERM AT 25° C.

HF-HFO-1243zf-HFC-245cb HF-HFO-1234yf-HFO-1243zf

Organics Organics Organics 0.95 F1243zf + 0.5 F1243zf + 0.05 F1243zf +0.05 F245cb 0.5 F245cb 0.95 F245cb MASS- TOTAL MASS- TOTAL MASS- TOTALFRAC PRESSURE FRAC PRESSURE FRAC PRESSURE HF bar HF bar HF bar 0 5.8 05.4 0 4.7 0.05 6.7 0.05 6.4 0.05 5.9 0.1 6.8 0.1 6.4 0.1 5.9 0.15 6.80.15 6.4 0.15 5.9 0.2 6.8 0.2 6.4 0.2 5.9 0.25 6.8 0.25 6.4 0.25 5.9 0.36.8 0.3 6.4 0.3 5.9 0.35 6.8 0.35 6.4 0.35 5.9 0.4 6.8 0.4 6.4 0.4 5.90.45 6.8 0.45 6.4 0.45 5.9 0.5 6.7 0.5 6.4 0.5 5.9 0.55 6.7 0.55 6.40.55 5.9 0.6 6.7 0.6 6.4 0.6 5.9 0.65 6.7 0.65 6.4 0.65 5.9 0.7 6.6 0.76.4 0.7 5.9 0.75 6.4 0.75 6.3 0.75 5.9 0.8 6.1 0.8 6.2 0.8 5.9 0.85 5.60.85 5.7 0.85 5.9 0.9 4.8 0.9 4.9 0.9 5.0 0.95 3.4 0.95 3.5 0.95 3.6 11.2 1 1.2 1 1.2

Organics Organics Organics 0.95 F1243zf + 0.5 F1243zf + 0.05 F1243zf +0.05 F1234yf 0.5 F1234yf 0.95 F1234yf MASS- TOTAL MASS- TOTAL MASS-TOTAL FRAC PRESSURE FRAC PRESSURE FRAC PRESSURE HF bar HF bar HF bar 05.9 0 6.3 0 6.7 0.05 6.8 0.05 7.2 0.05 7.7 0.1 6.9 0.1 7.3 0.1 7.7 0.156.9 0.15 7.3 0.15 7.7 0.2 6.8 0.2 7.2 0.2 7.7 0.25 6.8 0.25 7.2 0.25 7.70.3 6.8 0.3 7.2 0.3 7.7 0.35 6.8 0.35 7.2 0.35 7.7 0.4 6.8 0.4 7.2 0.47.7 0.45 6.8 0.45 7.2 0.45 7.7 0.5 6.8 0.5 7.2 0.5 7.7 0.55 6.8 0.55 7.20.55 7.7 0.6 6.8 0.6 7.2 0.6 7.7 0.65 6.7 0.65 7.2 0.65 7.7 0.7 6.6 0.77.1 0.7 7.7 0.75 6.5 0.75 7.0 0.75 7.5 0.8 6.2 0.8 6.7 0.8 7.2 0.85 5.70.85 6.1 0.85 6.6 0.9 4.8 0.9 5.2 0.9 5.6 0.95 3.4 0.95 3.6 0.95 3.8 11.2 1 1.2 1 1.2

HF-HCFO-1233xf-HFO-1243zf HF-HCFO-1233zdE-HFO-1243zf

Organics Organics Organics 0.95 F1243zf + 0.5 F1243zf + 0.05 F1243zf +0.05 F1233xf 0.5 F1233xf 0.95 F1233xf MASS- TOTAL MASS- TOTAL MASS-TOTAL FRAC PRES FRAC PRES FRAC PRES HF bar HF bar HF bar 0 5.7 0 4.0 01.8 0.05 6.6 0.05 5.0 0.05 2.9 0.1 6.7 0.1 5.0 0.1 2.9 0.15 6.6 0.15 5.00.15 2.9 0.2 6.6 0.2 5.0 0.2 2.9 0.25 6.6 0.25 5.0 0.25 2.9 0.3 6.6 0.35.0 0.3 2.9 0.35 6.6 0.35 5.0 0.35 2.9 0.4 6.6 0.4 5.0 0.4 2.9 0.45 6.60.45 5.0 0.45 2.9 0.5 6.6 0.5 5.0 0.5 2.9 0.55 6.6 0.55 5.0 0.55 2.9 0.66.6 0.6 5.0 0.6 2.9 0.65 6.5 0.65 4.9 0.65 2.9 0.7 6.4 0.7 4.9 0.7 2.90.75 6.3 0.75 4.7 0.75 2.9 0.8 6.0 0.8 4.5 0.8 2.7 0.85 5.5 0.85 4.10.85 2.5 0.9 4.7 0.9 3.5 0.9 2.2 0.95 3.3 0.95 2.6 0.95 1.8 1 1.2 1 1.21 1.2

Organics Organics Organics 0.95 F1243zf + 0.5 F1243zf + 0.05 F1243zf +0.05 F1233zdE 0.5 F1233zdE 0.95 F1233zdE MASS- TOTAL MASS- TOTAL MASS-TOTAL FRAC PRESSURE FRAC PRESSURE FRAC PRESSURE HF bar HF bar HF bar 05.7 0 3.9 0 1.6 0.05 6.6 0.05 5.0 0.05 2.7 0.1 6.6 0.1 4.9 0.1 2.7 0.156.6 0.15 4.9 0.15 2.7 0.2 6.6 0.2 4.9 0.2 2.7 0.25 6.6 0.25 4.9 0.25 2.70.3 6.6 0.3 4.9 0.3 2.7 0.35 6.6 0.35 4.9 0.35 2.7 0.4 6.6 0.4 4.9 0.42.7 0.45 6.6 0.45 4.9 0.45 2.7 0.5 6.6 0.5 4.9 0.5 2.7 0.55 6.6 0.55 4.90.55 2.7 0.6 6.6 0.6 4.9 0.6 2.7 0.65 6.5 0.65 4.8 0.65 2.7 0.7 6.4 0.74.8 0.7 2.7 0.75 6.3 0.75 4.6 0.75 2.7 0.8 6.0 0.8 4.4 0.8 2.5 0.85 5.50.85 4.0 0.85 2.4 0.9 4.6 0.9 3.4 0.9 2.1 0.95 3.3 0.95 2.5 0.95 1.7 11.2 1 1.2 1 1.2

HF-HFO-1234zeE-HFO-1243zf HF-HFO-1234zeZ-HFO-1243zf

Organics Organics Organics 0.95 F1243zf + 0.5 F1243zf + 0.05 F1243zf +0.05 F1234zeE 0.5 F1234zeE 0.95 F1234zeE MASS- TOTAL MASS- TOTAL MASS-TOTAL FRAC PRESSURE FRAC PRESSURE FRAC PRESSURE HF bar HF bar HF bar 05.8 0 5.4 0 4.9 0.05 6.7 0.05 6.3 0.05 5.9 0.1 6.8 0.1 6.4 0.1 5.9 0.156.8 0.15 6.4 0.15 5.9 0.2 6.8 0.2 6.4 0.2 5.9 0.25 6.8 0.25 6.4 0.25 5.90.3 6.8 0.3 6.4 0.3 5.9 0.35 6.8 0.35 6.4 0.35 5.9 0.4 6.7 0.4 6.4 0.45.9 0.45 6.7 0.45 6.4 0.45 5.9 0.5 6.7 0.5 6.3 0.5 5.8 0.55 6.7 0.55 6.30.55 5.8 0.6 6.7 0.6 6.3 0.6 5.7 0.65 6.6 0.65 6.2 0.65 5.6 0.7 6.5 0.76.1 0.7 5.5 0.75 6.4 0.75 5.8 0.75 5.2 0.8 6.1 0.8 5.5 0.8 4.9 0.85 5.60.85 5.0 0.85 4.4 0.9 4.7 0.9 4.2 0.9 3.6 0.95 3.4 0.95 3.0 0.95 2.6 11.2 1 1.2 1 1.2

Organics Organics Organics 0.95 F1243zf + 0.5 F1243zf + 0.05 F1243zf +0.05 F1234zeZ 0.5 F1234zeZ 0.95 F1234zeZ MASS- TOTAL MASS- TOTAL MASS-TOTAL FRAC PRESSURE FRAC PRESSURE FRAC PRESSURE HF bar HF bar HF bar 05.7 0 4.0 0 2.0 0.05 6.6 0.05 5.0 0.05 3.1 0.1 6.6 0.1 5.0 0.1 3.1 0.156.6 0.15 5.0 0.15 3.1 0.2 6.6 0.2 5.0 0.2 3.1 0.25 6.6 0.25 5.0 0.25 3.10.3 6.6 0.3 5.0 0.3 3.1 0.35 6.6 0.35 5.0 0.35 3.1 0.4 6.6 0.4 5.0 0.43.1 0.45 6.6 0.45 5.0 0.45 3.1 0.5 6.6 0.5 5.0 0.5 3.1 0.55 6.6 0.55 5.00.55 3.1 0.6 6.6 0.6 5.0 0.6 3.1 0.65 6.5 0.65 5.0 0.65 3.1 0.7 6.4 0.74.9 0.7 3.1 0.75 6.3 0.75 4.8 0.75 3.1 0.8 6.0 0.8 4.5 0.8 3.0 0.85 5.50.85 4.2 0.85 2.8 0.9 4.7 0.9 3.6 0.9 2.4 0.95 3.3 0.95 2.6 0.95 1.9 11.2 1 1.2 1 1.2

EXAMPLE 2: TEMPERATURE AND PRESSURE RANGE OF TERNARY MIXTURES

Boiling point range Temperature Pressure Ternary ° C. bar absHF-HFO-1243zf-HFC-245cb 0 to 40 ~2.5 to ~10.4 HF-HFO-1234yf-HFO-1243zf 0to 40 ~3.0 to ~11.7 HF-HCFO-1233xf-HFO-1243zf 0 to 40 ~1.1 to ~10.2HF-HFO-1234zeE-HFO-1243zf 0 to 40 ~2.5 to ~10.4HF-HFO-1234zeZ-HFO-1243zf 0 to 40 ~1.2 to ~10.2HF-HCFO-1233zdE-HFO-1243zf 0 to 40 ~1.1 to ~10.2

EXAMPLE 3: DECANTATION RANGE OF TERNARY MIXTURES

Decantation ranges Mass percentage of HF Isotherm Isotherm IsothermTernary 0° C. 25° C. 40° C. HF-HFO-1243zf-HFC-245cb 5-75 10-75 40-70HF-HFO-1234yf-HFO-1243zf 5-70 * * HF-HCFO-1233xf-HFO-1243zf 5-75 10-6520-40 HF-HFO-1234zeE-HFO-1243zf 5-65 * * HF-HFO-1234zeZ-HFO-1243zf 5-7510-65 * HF-HCFO-1233zdE-HFO-1243zf 5-75  5-65 15-45

EXAMPLE 4: QUATERNARY MIXTURES, ISOTHERM AT 25° C.

HF-HCFO-1233xf-HFO-1243zf-HFC-245cb

Organics Organics Organics Organics 0.9 F1233xf + 0.4 F1233xf + 0.05F1233xf + 0.05 F1233xf + 0.05 F1243zf + 0.3 F1243zf + 0.9 F1243zf + 0.05F1243zf + 0.05 F245cb 0.3 F245cb 0.05 F245cb 0.9 F245cb TOTAL TOTALTOTAL TOTAL MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- FRAC SUREFRAC SURE FRAC SURE FRAC SURE HF bar HF bar HF bar HF bar 0 2.0 0 4.0 05.6 0 4.6 0.05 3.1 0.05 5.1 0.05 6.6 0.05 5.7 0.1 3.1 0.1 5.1 0.1 6.60.1 5.7 0.15 3.1 0.15 5.1 0.15 6.6 0.15 5.7 0.2 3.1 0.2 5.1 0.2 6.6 0.25.7 0.25 3.1 0.25 5.1 0.25 6.6 0.25 5.7 0.3 3.1 0.3 5.1 0.3 6.6 0.3 5.70.35 3.1 0.35 5.1 0.35 6.6 0.35 5.7 0.4 3.1 0.4 5.1 0.4 6.6 0.4 5.8 0.453.1 0.45 5.1 0.45 6.6 0.45 5.8 0.5 3.1 0.5 5.1 0.5 6.6 0.5 5.8 0.55 3.10.55 5.1 0.55 6.6 0.55 6.8 0.6 3.1 0.6 5.1 0.6 6.5 0.6 5.8 0.65 3.1 0.655.1 0.65 6.5 0.65 5.8 0.7 3.1 0.7 5.1 0.7 6.4 0.7 5.8 0.75 3.1 0.75 5.10.75 6.3 0.75 5.8 0.8 2.9 0.8 4.8 0.8 6.0 0.8 5.8 0.85 2.7 0.85 4.5 0.855.5 0.85 5.7 0.9 2.4 0.9 3.8 0.9 4.7 0.9 4.5 0.95 1.9 0.95 2.8 0.95 3.30.95 3.5 1 1.2 1 1.2 1 1.2 1 1.2

HF-HCFO-1233xf-HCFO-1233zdE-HFO-1243zf

Organics Organics Organics Organics 0.9 F1233xf + 0.05 F1233xf + 0.05F1233xf + 0.4 F1233xf + 0.05 F1233zdE + 0.9 F1233zdE + 0.05 F1233zdE +0.3 F1233zdE + 0.05 F1243zf 0.05 F1243zf 0.3 F1243zf 0.3 F1243zf TOTALTOTAL TOTAL TOTAL MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- FRACSURE FRAC SURE FRAC SURE FRAC SURE HF bar HF bar HF bar HF bar 0 1.8 01.6 0 5.5 0 3.0 0.05 2.9 0.05 2.7 0.05 6.4 0.05 4.1 0.1 2.9 0.1 2.7 0.16.5 0.1 4.1 0.15 2.9 0.15 2.7 0.15 6.5 0.15 4.1 0.2 2.9 0.2 2.7 0.2 6.50.2 4.1 0.25 2.9 0.25 2.7 0.25 6.5 0.25 4.1 0.3 2.9 0.3 2.7 0.3 6.5 0.34.1 0.35 2.9 0.35 2.7 0.35 6.5 0.35 4.1 0.4 2.9 0.4 2.7 0.4 6.5 0.4 4.10.45 2.9 0.45 2.7 0.45 6.5 0.45 4.1 0.5 2.9 0.5 2.7 0.5 6.4 0.5 4.1 0.552.9 0.55 2.7 0.55 6.4 0.55 4.1 0.6 2.9 0.6 2.7 0.6 6.4 0.6 4.0 0.65 2.90.65 2.7 0.65 6.4 0.65 4.0 0.7 2.9 0.7 2.7 0.7 6.3 0.7 4.0 0.75 2.9 0.752.7 0.75 6.1 0.75 3.9 0.8 2.7 0.8 2.6 0.8 5.8 0.8 3.7 0.85 2.5 0.85 2.40.85 5.3 0.85 3.4 0.9 2.2 0.9 2.1 0.9 4.5 0.9 2.9 0.95 1.8 0.95 1.7 0.953.2 0.95 2.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HCFO-1233xf-HFO-1234zeE-HFO-1243zf

Organics Organics Organics Organics 0.9 F1233xf + 0.05 F1233xf + 0.05F1233xf + 0.4 F1233xf + 0.05 F1234zeE + 0.9 F1234zeE + 0.05 F1234zeE +0.3 F1234zeE + 0.05 F1243zf 0.05 F1243zf 0.9 F1243zf 0.3 F1243zf TOTALTOTAL TOTAL TOTAL MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- FRACSURE FRAC SURE FRAC SURE FRAC SURE HF bar HF bar HF bar HF bar 0 2.0 04.8 0 5.6 0 4.0 0.05 3.1 0.05 5.7 0.05 6.6 0.05 5.1 0.1 3.1 0.1 5.8 0.16.6 0.1 5.1 0.15 3.1 0.15 5.8 0.15 6.6 0.15 5.1 0.2 3.1 0.2 5.8 0.2 6.60.2 5.1 0.25 3.1 0.25 5.8 0.25 6.6 0.25 5.1 0.3 3.1 0.3 5.8 0.3 6.6 0.35.0 0.35 3.1 0.35 5.7 0.35 6.6 0.35 5.0 0.4 3.1 0.4 5.7 0.4 6.6 0.4 5.00.45 3.1 0.45 5.7 0.45 6.6 0.45 5.0 0.5 3.1 0.5 5.7 0.5 6.6 0.5 5.0 0.553.1 0.55 5.7 0.55 6.6 0.55 5.0 0.6 3.1 0.6 5.6 0.6 6.5 0.6 5.0 0.65 3.10.65 5.5 0.65 6.5 0.65 4.9 0.7 3.0 0.7 5.3 0.7 6.4 0.7 4.8 0.75 3.0 0.755.1 0.75 6.2 0.75 4.7 0.8 2.9 0.8 4.8 0.8 5.9 0.8 4.4 0.85 2.6 0.85 4.30.85 5.4 0.85 4.0 0.9 2.3 0.9 3.6 0.9 4.6 0.9 3.4 0.95 1.8 0.95 2.6 0.953.3 0.95 2.5 1 1.2 1 1.2 1 1.2 1 1.2

HF-HCFO-1233xf-HFO-1234zeZ-HFO-1243zf

Organics Organics Organics Organics 0.9 F1233xf + 0.05 F1233xf + 0.05F1233xf + 0.4 F1233xf + 0.05 F1234zeZ + 0.9 F1234zeZ + 0.05 F1234zeZ +0.3 F1234zeZ + 0.05 F1243zf 0.05 F1243zf 0.9 F1243zf 0.3 F1243zf TOTALTOTAL TOTAL TOTAL MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- FRACSURE FRAC SURE FRAC SURE FRAC SURE HF bar HF bar HF bar HF bar 0 1.8 02.0 0 5.5 0 3.1 0.05 2.9 0.05 3.1 0.05 6.4 0.05 4.2 0.1 2.9 0.1 3.1 0.16.5 0.1 4.2 0.15 2.9 0.15 3.1 0.15 6.5 0.15 4.2 0.2 2.9 0.2 3.1 0.2 6.50.2 4.2 0.25 2.9 0.25 3.1 0.25 6.5 0.25 4.2 0.3 2.9 0.3 3.1 0.3 6.5 0.34.2 0.35 2.9 0.35 3.1 0.35 6.5 0.35 4.2 0.4 2.9 0.4 3.1 0.4 6.5 0.4 4.20.45 2.9 0.45 3.1 0.45 6.5 0.45 4.2 0.5 2.9 0.5 3.1 0.5 6.4 0.5 4.2 0.552.9 0.55 3.1 0.55 6.4 0.55 4.2 0.6 2.9 0.6 3.1 0.5 6.4 0.6 4.1 0.65 2.90.65 3.1 0.65 6.4 0.65 4.1 0.7 2.9 0.7 3.1 0.7 6.3 0.7 4.1 0.75 2.9 0.753.1 0.75 6.1 0.75 4.0 0.8 2.8 0.8 3.0 0.8 5.8 0.8 3.8 0.85 2.5 0.85 2.70.85 5.3 0.85 3.5 0.9 2.2 0.9 2.4 0.9 4.5 0.9 3.0 0.95 1.8 0.95 1.9 0.953.2 0.95 2.3 1 1.2 1 1.2 1 1.2 1 1.2

HF-HCFO-1233xf-HFO-1234yf-HFO-1243zf

Organics Organics Organics Organics 0.9 F1233xf + 0.05 F1233xf + 0.05F1233xf + 0.4 F1233xf + 0.05 F1234yf + 0.9 F1234yf + 0.05 F1234yf + 0.3F1234yf + 0.05 F1243zf 0.05 F1243zf 0.9 F1243zf 0.3 F1243zf TOTAL TOTALTOTAL TOTAL MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- FRAC SUREFRAC SURE FRAC SURE FRAC SURE HF bar HF bar HF bar HF bar 0 2.1 0 6.5 05.8 0 4.6 0.05 3.2 0.05 7.5 0.05 5.8 0.05 5.6 0.1 3.2 0.1 7.5 0.1 8.80.1 5.7 0.15 3.2 0.15 7.5 0.15 5.8 0.15 5.6 0.2 3.2 0.2 7.5 0.2 6.8 0.25.6 0.25 3.2 0.25 7.5 0.25 6.8 0.25 5.6 0.3 3.2 0.3 7.5 0.3 6.8 0.3 5.60.35 3.2 0.35 7.5 0.35 6.8 0.35 5.6 0.4 3.2 0.4 7.5 0.4 6.8 0.4 5.6 0.453.2 0.45 7.5 0.45 6.8 0.45 5.6 0.5 3.2 0.5 7.5 0.5 6.8 0.5 5.6 0.55 3.20.55 7.5 0.55 6.7 0.55 5.6 0.6 3.2 0.6 7.5 0.6 6.7 0.6 5.6 0.65 3.2 0.657.5 0.65 6.7 0.65 5.6 0.7 3.2 0.7 7.4 0.7 6.6 0.7 5.6 0.75 3.2 0.75 7.30.75 6.4 0.75 5.4 0.8 3.0 0.8 7.0 0.8 6.1 0.8 5.1 0.85 2.8 0.85 6.4 0.855.6 0.85 4.7 0.9 2.4 0.9 5.4 0.9 4.8 0.9 4.0 0.95 1.9 0.95 3.7 0.95 3.40.95 2.9 1 1.2 1 1.2 1 1.2 1 1.2

HF-HFC-245cb-HCFO-1233zdE-HFO-1243zf

Organics Organics Organics Organics 0.9 F245cb + 0.05 F245cb + 0.05F245cb + 0.4 F245cb + 0.05 F1233zdE + 0.9 F1233zdE + 0.05 F1233zdE + 0.3F1233zdE + 0.05 F1243zf 0.05 F1243zf 0.9 F1243zf 0.3 F1243zf TOTAL TOTALTOTAL TOTAL MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- FRAC SUREFRAC SURE FRAC SURE FRAC SURE HF bar HF bar HF bar HF bar 0 4.6 0 1.9 05.6 0 4.2 0.05 5.7 0.05 2.9 0.05 6.6 0.05 5.3 0.1 5.7 0.1 2.9 0.1 5.60.1 5.3 0.15 5.7 0.15 2.9 0.15 6.6 0.15 5.3 0.2 5.7 0.2 2.9 0.2 6.6 0.25.3 0.25 5.7 0.25 2.9 0.25 6.6 0.25 5.3 0.3 5.7 0.3 2.9 0.3 6.6 0.3 5.30.35 5.7 0.35 2.9 0.35 6.6 0.35 5.3 0.4 5.7 0.4 2.9 0.4 6.6 0.4 5.3 0.455.7 0.45 2.9 0.45 6.6 0.45 5.3 0.5 5.7 0.5 2.9 0.5 6.6 0.5 5.3 0.55 5.70.55 2.9 0.55 6.6 0.55 5.3 0.6 5.7 0.6 2.9 0.6 6.5 0.6 5.3 0.65 5.7 0.652.9 0.65 6.5 0.65 5.3 0.7 5.8 0.7 2.9 0.7 6.4 0.7 5.3 0.75 5.8 0.75 2.90.75 6.2 0.75 5.3 0.8 5.8 0.8 2.8 0.8 6.0 0.8 5.1 0.85 5.7 0.85 2.6 0.855.5 0.85 4.7 0.9 4.9 0.9 2.3 0.9 4.7 0.9 4.1 0.95 3.5 0.95 1.8 0.95 3.30.95 2.9 1 1.2 1 1.2 1 1.2 1 1.2

HF-HCFO-1233zdE-HFO-1234zeE-HFO-1243zf

Organics Organics Organics Organics 0.9 F1233zdE + 0.05 F1233zdE + 0.05F1233zdE + 0.4 F1233zdE + 0.05 F1234zeE + 0.9 F1234zeE + 0.05 F1234zeE +0.3 F1234zeE + 0.05 F1243zf 0.05 F1243zf 0.9 F1243zf 0.3 F1243zf PRES-PRES- PRES- PRES- SURE SURE SURE SURE HF PRES HF PRES HF PRES HF PRES HFbar HF bar HF bar HF bar 0 1.8 0 4.8 0 5.6 0 3.9 0.05 2.9 0.05 5.7 0.056.6 0.05 5.0 0.1 2.9 0.1 5.7 0.1 6.6 0.1 5.0 0.15 2.9 0.15 5.7 0.15 6.60.15 5.0 0.2 2.9 0.2 5.7 0.2 6.6 0.1 5.0 0.25 2.9 0.25 5.7 0.25 6.6 0.255.0 0.3 2.9 0.3 5.7 0.3 6.6 0.3 5.0 0.35 2.9 0.35 5.7 0.35 6.6 0.35 5.00.4 2.9 0.4 5.7 0.4 6.6 0.4 4.9 0.45 2.9 0.45 5.7 0.45 6.6 0.45 4.9 0.52.9 0.5 5.7 0.5 6.6 0.5 4.9 0.55 2.9 0.55 5.6 0.55 6.5 0.55 4.9 0.6 2.90.6 5.6 0.6 6.5 0.6 4.9 0.65 2.9 0.65 5.5 0.65 6.5 0.65 4.9 0.7 2.8 0.75.3 0.7 6.4 0.7 4.8 0.75 2.8 0.75 5.1 0.75 6.2 0.75 4.6 0.8 2.7 0.8 4.80.8 5.9 0.8 4.3 0.85 2.5 0.85 4.3 0.85 5.4 0.85 3.9 0.9 2.2 0.9 3.6 0.94.6 0.9 3.3 0.95 1.8 0.95 2.6 0.95 3.3 0.95 2.5 1 1.2 1 1.2 1 1.2 1 1.2

HF-HCFO-1233zdE-HFO-1234zeZ-HFO-1243zf

Organics Organics Organics Organics 0.9 F1233zdE + 0.05 F1233zdE + 0.05F1233zdE + 0.4 F1233zdE + 0.05 F1234zeZ + 0.9 F1234zeZ + 0.05 F1234zeZ +0.3 F1234zeZ + 0.05 F1243zf 0.05 F1243zf 0.9 F1243zf 0.3 F1243zf TOTALTOTAL TOTAL TOTAL MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- FRACSURE FRAC SURE FRAC SURE FRAC SURE HF bar HF bar HF bar HF bar 0 1.6 02.0 0 5.5 0 3.0 0.05 2.7 0.05 3.1 0.05 6.4 0.05 4.1 0.1 2.7 0.1 3.1 0.16.5 0.1 4.1 0.15 2.7 0.15 3.1 0.15 6.5 0.15 4.1 0.2 2.7 0.2 3.1 0.2 6.50.2 4.1 0.25 2.7 0.25 3.1 0.25 6.5 0.25 4.1 0.3 2.7 0.3 3.1 0.3 6.4 0.34.1 0.35 2.7 0.35 3.1 0.35 6.4 0.35 4.1 0.4 2.7 0.4 3.1 0.4 6.4 0.4 4.10.45 2.7 0.45 3.1 0.45 6.4 0.45 4.1 0.5 2.7 0.5 3.1 0.5 6.4 0.5 4.1 0.552.7 0.55 3.1 0.55 6.4 0.55 4.1 0.6 2.7 0.6 3.1 0.6 6.4 0.6 4.1 0.65 2.70.65 3.1 0.65 6.3 0.65 4.0 0.7 2.7 0.7 3.1 0.7 6.3 0.7 4.0 0.75 2.7 0.753.1 0.75 6.1 0.75 3.9 0.8 2.6 0.8 3.0 0.8 5.8 0.8 3.7 0.85 2.4 0.85 2.70.85 5.3 0.85 3.4 0.9 2.1 0.9 2.4 0.9 4.5 0.9 2.9 0.95 1.7 0.95 1.9 0.953.2 0.95 2.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HFO-1234yf-HCFO-1233zdE-HFO-1243zf

Organics Organics Organics Organics 0.9 F1234yf + 0.05 F1234yf + 0.05F1234yf + 0.4 F1234yf + 0.05 F1233zdE + 0.9 F1233zdE + 0.05 F1233zdE +0.3 F1233zdE + 0.05 F1243zf 0.05 F1243zf 0.9 F1243zf 0.3 F1243zf TOTALTOTAL TOTAL TOTAL MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- FRACSURE FRAC SURE FRAC SURE FRAC SURE HF bar HF bar HF bar HF bar 0 6.5 01.9 0 5.7 0 5.0 0.05 7.5 0.05 3.0 0.05 6.7 0.05 6.0 0.1 7.5 0.1 3.0 0.16.7 0.1 6.0 0.15 7.5 0.15 3.0 0.15 6.7 0.15 6.0 0.2 7.4 0.2 3.0 0.2 6.70.2 6.0 0.25 7.4 0.25 3.0 0.25 6.7 0.25 6.0 0.3 7.5 0.3 3.0 0.3 6.7 0.36.0 0.35 7.5 0.35 3.0 0.35 6.7 0.35 6.0 0.4 7.5 0.4 3.0 0.4 6.7 0.4 6.00.45 7.5 0.45 3.0 0.45 6.7 0.45 6.0 0.5 7.5 0.5 3.0 0.5 6.6 0.5 6.0 0.557.5 0.55 3.0 0.55 6.6 0.55 6.0 0.6 7.5 0.6 3.0 0.6 6.6 0.6 6.0 0.65 7.50.65 3.0 0.65 6.6 0.65 6.0 0.7 7.4 0.7 3.0 0.7 6.5 0.7 6.0 0.75 7.3 0.753.0 0.75 6.3 0.75 5.8 0.8 7.0 0.8 2.8 0.8 6.0 0.8 5.5 0.05 6.4 0.85 2.60.85 5.5 0.85 5.1 0.9 5.4 0.9 2.3 0.9 4.7 0.9 4.3 0.95 3.7 0.95 1.8 0.953.3 0.95 3.1 1 1.2 1 1.2 1 1.2 1 1.2

HF-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf

Organics Organics Organics Organics 0.9 F1234zeE + 0.05 F1234zeE + 0.05F1234zeE + 0.4 F1234zeE + 0.05 F1234zeZ + 0.9 F1234zeZ + 0.05 F1234zeZ +0.3 F1234zeZ + 0.05 F1243zf 0.05 F1243zf 0.9 F1243zf 0.3 F1243zf TOTALTOTAL TOTAL TOTAL MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- FRACSURE FRAC SURE FRAC SURE FRAC SURE HF bar HF bar HF bar HF bar 0 4.8 02.2 0 5.6 0 4.3 0.05 5.7 0.05 3.3 0.05 6.6 0.05 5.3 0.1 5.8 0.1 3.3 0.16.6 0.1 5.3 0.15 5.8 0.15 3.3 0.15 6.6 0.15 5.3 0.2 5.7 0.2 3.3 0.2 6.60.2 5.3 0.25 5.7 0.25 3.3 0.25 6.6 0.25 5.3 0.3 5.7 0.3 3.3 0.3 6.6 0.35.3 0.35 5.7 0.35 3.3 0.35 6.6 0.35 5.3 0.4 5.7 0.4 3.3 0.4 6.6 0.4 5.30.45 5.7 0.45 3.3 0.45 6.6 0.45 5.3 0.5 5.7 0.5 3.3 0.5 6.6 0.5 5.3 0.555.7 0.55 3.3 0.55 6.5 0.55 5.3 0.6 5.6 0.6 3.3 0.6 6.5 0.6 5.3 0.65 5.50.65 3.3 0.65 6.5 0.65 5.2 0.7 5.3 0.7 3.3 0.7 6.4 0.7 5.1 0.75 5.1 0.753.2 0.75 6.2 0.75 4.9 0.8 4.8 0.8 3.1 0.8 5.9 0.8 4.6 0.85 4.3 0.85 2.80.85 5.4 0.85 4.2 0.9 3.6 0.9 2.5 0.9 4.6 0.9 3.6 0.95 2.6 0.95 2.0 0.953.3 0.95 2.6 1 1.2 1 1.2 1 1.2 1 1.2

HF-HFO-1234yf-HFO-1234zeE-HFO-1243zf

Organics Organics Organics Organics 0.9 F1234yf + 0.05 F1234yf + 0.05F1234yf + 0.4 F1234yf + 0.05 F1234zeE + 0.9 F1234zeE + 0.05 F1234zeE +0.3 F1234zeE + 0.05 F1243zf 0.05 F1243zf 0.9 F1243zf 0.3 F1243zf TOTALTOTAL TOTAL TOTAL MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- FRACSURE FRAC SURE FRAC SURE FRAC SURE HF bar HF bar HF bar HF bar 0 6.7 05.0 0 5.8 0 5.9 0.05 7.6 0.05 6.0 0.05 6.8 0.05 6.9 0.1 7.6 0.1 6.0 0.16.8 0.1 6.9 0.15 7.6 0.15 6.0 0.15 6.8 0.15 6.9 0.2 7.6 0.2 6.0 0.2 6.80.2 6.9 0.25 7.5 0.25 6.0 0.25 6.8 0.25 6.9 0.3 7.6 0.3 6.0 0.3 6.8 0.36.9 0.35 7.6 0.35 6.0 0.35 6.8 0.35 6.9 0.4 7.6 0.4 6.0 0.4 6.8 0.4 6.90.45 7.6 0.45 6.0 0.45 6.8 0.45 6.9 0.5 7.6 0.5 6.0 0.5 6.8 0.5 6.9 0.557.6 0.55 5.9 0.55 6.8 0.55 6.9 0.6 7.6 0.6 5.8 0.6 6.7 0.5 6.9 0.65 7.60.65 5.7 0.65 6.7 0.65 6.8 0.7 7.6 0.7 5.6 0.7 6.6 0.7 6.7 0.75 7.4 0.755.4 0.75 6.4 0.75 6.5 0.8 7.1 0.8 5.0 0.8 6.1 0.8 6.2 0.85 6.5 0.85 4.50.85 5.6 0.85 5.7 0.9 5.5 0.9 3.8 0.9 4.8 0.9 4.8 0.95 3.8 0.95 2.7 0.953.4 0.95 3.3 1 1.2 1 1.2 1 1.2 1 1.2

HF-HFO-1234yf-HFO-1234zeZ-HFO-1243zf

Organics Organics Organics Organics 0.9 F1234yf + 0.05 F1234yf + 0.05F1234yf + 0.4 F1234yf + 0.05 F1234zeZ + 0.9 F1234zeZ + 0.05 F1234zeZ +0.3 F1234zeZ + 0.05 F1243zf 0.05 F1243zf 0.9 F1243zf 0.3 F1243zf TOTALTOTAL TOTAL TOTAL MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- FRACSURE FRAC SURE FRAC SURE FRAC SURE HF bar HF bar HF bar HF bar 0 6.5 02.3 0 5.7 0 5.0 0.05 7.5 0.05 3.4 0.05 6.7 0.05 6.0 0.1 7.5 0.1 3.4 0.16.7 0.1 6.1 0.15 7.5 0.15 3.4 0.15 6.7 0.15 6.1 0.2 7.4 0.2 3.4 0.2 6.70.2 6.1 0.25 7.4 0.25 3.4 0.25 6.7 0.25 6.1 0.3 7.4 0.3 3.4 0.3 6.7 0.36.1 0.35 7.5 0.35 3.4 0.35 6.7 0.35 6.1 0.4 7.5 0.4 3.4 0.4 6.7 0.4 6.10.45 7.5 0.45 3.4 0.45 6.7 0.45 6.1 0.5 7.5 0.5 3.4 0.5 6.7 0.5 6.1 0.557.5 0.55 3.4 0.55 6.6 0.55 6.1 0.6 7.5 0.6 3.4 0.6 6.6 0.6 6.1 0.65 7.50.65 3.4 0.65 6.6 0.55 6.1 0.7 7.4 0.7 3.4 0.7 6.5 0.7 6.0 0.75 7.3 0.753.3 0.75 6.3 0.75 5.9 0.8 7.0 0.8 3.2 0.8 6.0 0.8 5.6 0.85 6.4 0.85 3.00.85 5.5 0.85 5.1 0.9 5.4 0.9 2.6 0.9 4.7 0.9 4.4 0.95 3.7 0.95 2.0 0.953.3 0.95 3.1 1 1.2 1 1.2 1 1.2 1 1.2

HF-HFO-1234yf-HFO-1243zf-HFC-245cb

Organics Organics Organics Organics 0.9 F1234yf + 0.4 F1234yf + 0.05F1234yf + 0.05 F1234yf + 0.05 F1243zf + 0.3 F1243zf + 0.9 F1243zf + 0.05F1243zf + 0.05 F245cb 0.3 F245cb 0.05 F245cb 0.9 F245cb TOTAL TOTALTOTAL TOTAL MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- FRAC SUREFRAC SURE FRAC SURE FRAC SURE HF bar HF bar HF bar HF bar 0 6.7 0 5.9 05.8 0 4.9 0.05 7.6 0.05 6.9 0.05 6.8 0.05 6.0 0.1 7.6 0.1 7.0 0.1 6.80.1 6.0 0.15 7.6 0.15 6.9 0.15 6.8 0.15 6.0 0.2 7.6 0.2 6.9 0.2 6.8 0.26.0 0.25 7.6 0.25 6.9 0.25 6.8 0.25 6.0 0.3 7.6 0.3 6.9 0.3 6.8 0.3 6.00.35 7.6 0.35 6.9 0.35 6.8 0.35 6.0 0.4 7.6 0.4 6.9 0.4 6.8 0.4 6.0 0.457.6 0.45 6.9 0.45 6.8 0.45 6.0 0.5 7.6 0.5 6.9 0.5 6.8 0.5 6.0 0.55 7.60.55 6.9 0.55 6.8 0.55 6.0 0.6 7.6 0.6 6.9 0.6 6.8 0.6 6.0 0.65 7.6 0.656.9 0.65 6.7 0.65 6.0 0.7 7.6 0.7 6.9 0.7 6.6 0.7 6.0 0.75 7.5 0.75 6.90.75 6.5 0.75 6.0 0.8 7.2 0.8 6.6 0.8 6.2 0.8 6.0 0.85 6.6 0.85 6.1 0.855.7 0.85 5.9 0.9 5.5 0.9 5.2 0.9 4.8 0.9 5.1 0.95 3.8 0.95 3.6 0.95 3.40.95 3.6 1 1.2 1 1.2 1 1.2 1 1.2

HF-HFC-245th-HFO-1234zeE-HFO-1243zf

Organics Organics Organics Organics 0.9 F245cb + 0.05 F245cb + 0.05F245cb + 0.4 F245cb + 0.05 F1234zeE + 0.9 F1234zeE + 0.05 F1234zeE + 0.3F1234zeE + 0.05 F1243zf 0.05 F1243zf 0.9 F1243zf 0.3 F1243zf TOTAL TOTALTOTAL TOTAL MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- FRAC SUREFRAC SURE FRAC SURE FRAC SURE HF bar HF bar HF bar HF bar 0 4.8 0 4.9 05.8 0 5.2 0.05 5.9 0.05 5.9 0.05 6.7 0.05 6.2 0.1 5.9 0.1 5.9 0.1 6.70.1 6.2 0.15 5.9 0.15 5.9 0.15 6.7 0.15 6.2 0.2 5.9 0.2 5.9 0.2 6.7 0.26.2 0.25 5.9 0.25 5.9 0.25 6.7 0.25 6.2 0.3 5.9 0.3 5.9 0.3 6.7 0.3 6.20.35 5.9 0.35 5.9 0.35 6.7 0.35 6.2 0.4 5.9 0.4 5.9 0.4 6.7 0.4 6.2 0.455.9 0.45 5.9 0.45 6.7 0.45 6.2 0.5 5.9 0.5 5.9 0.5 6.7 0.5 6.2 0.55 5.90.55 5.8 0.55 6.7 0.55 6.2 0.6 5.9 0.6 5.8 0.6 6.7 0.6 6.2 0.05 5.9 0.655.7 0.65 6.6 0.65 6.2 0.7 5.9 0.7 5.5 0.7 6.5 0.7 6.2 0.75 5.9 0.75 5.30.75 6.4 0.75 6.1 0.8 5.9 0.8 5.0 0.8 6.1 0.8 5.8 0.85 5.8 0.85 4.5 0.855.6 0.85 5.3 0.9 5.0 0.9 3.7 0.9 4.7 0.9 4.5 0.95 3.5 0.95 2.7 0.95 3.40.95 3.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HFC-245cb-HFO-1234zeZ-HFO-1243zf

Organics Organics Organics Organics 0.9 F245cb + 0.05 F245cb + 0.05F245cb + 0.4 F245cb + 0.05 F1234zeZ + 0.9 F1234zeZ + 0.05 F1234zeZ + 0.3F1234zeZ + 0.05 F1243zf 0.05 F1243zf 0.9 F1243zf 0.3 F1243zf TOTAL TOTALTOTAL TOTAL MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- FRAC SUREFRAC SURE FRAC SURE FRAC SURE HF bar HF bar HF bar HF bar 0 4.6 0 2.2 05.6 0 4.2 0.05 5.7 0.05 3.3 0.05 6.6 0.05 5.3 0.1 5.7 0.1 3.3 0.1 6.60.1 5.3 0.15 5.7 0.15 3.3 0.15 6.6 0.15 5.3 0.2 5.7 0.2 3.3 0.2 6.6 0.25.3 0.25 5.7 0.25 3.3 0.25 6.6 0.25 5.3 0.3 5.7 0.3 3.3 0.3 6.6 0.3 5.30.35 5.7 0.35 3.3 0.35 6.6 0.35 5.3 0.4 5.7 0.4 3.3 0.4 6.6 0.4 5.3 0.455.7 0.45 3.3 0.45 6.6 0.45 5.3 0.5 5.7 0.5 3.3 0.5 6.6 0.5 5.3 0.55 5.70.55 3.3 0.55 6.6 0.55 5.3 0.6 5.8 0.6 3.3 0.6 6.5 0.6 5.3 0.65 5.8 0.653.3 0.65 6.5 0.65 5.3 0.7 5.8 0.7 3.3 0.7 6.4 0.7 5.4 0.75 5.8 0.75 3.30.75 6.3 0.75 5.4 0.8 5.8 0.8 3.1 0.8 6.0 0.8 5.2 0.85 5.7 0.85 2.9 0.855.5 0.85 4.8 0.9 4.9 0.9 2.6 0.9 4.7 0.9 4.1 0.95 3.5 0.95 2.0 0.95 3.30.95 3.0 1 1.2 1 1.2 1 1.2 1 1.2

EXAMPLE 5: TEMPERATURE AND PRESSURE RANGE OF QUATERNARY MIXTURES

Boiling point range Temperature Pressure Quaternary ° C. bar absHF-HCFO-1233xf-HFC-245cb-HFO- 0 to 40 ~1.2 to ~10.1 1243zfHF-HFO-1234yf-HFC-245cb-HFO- 0 to 40 ~2.5 to ~11.6 1243zfHF-HCFO-1233xf-HFO-1234yf- 0 to 40 ~1.3 to ~11.3 HFO-1243zfHF-HCFO-1233xf-HCFO-1233zdE- 0 to 40 ~1.0 to ~9.9  HFO-1243zfHF-HCFO-1233xf-HFO-1234zeE- 0 to 40 ~1.2 to ~10.1 HFO-1243zfHF-HCFO-1233xf-HFO-1234zeZ- 0 to 40 ~1.1 to ~9.9  HFO-1243zfHF-HFO-1234yf-HFO-1234zeE- 0 to 40 ~3.0 to ~11.6 HFO-1243zfHF-HFO-1234yf-HFO-1234zeZ- 0 to 40 ~1.3 to ~11.3 HFO-1243zfHF-HFC-245cb-HCFO-1233zdE- 0 to 40 ~1.1 to ~10.1 HFO-1243zfHF-HFC-245cb-HFO-1234zeE- 0 to 40 ~2.5 to ~10.3 HFO-1243zfHF-HFC-245cb-HFO-1234zeZ-HFO- 0 to 40 ~1.3 to ~10.1 1243zfHF-HCFO-1233zdE-HFO-1234zeE- 0 to 40 ~1.1 to ~10.1 HFO-1243zfHF-HCFO-1233zdE-HFO-1234zeZ- 0 to 40 ~1.0 to ~9.9  HFO-1243zfHF-HFO-1234zeE-HFO-1234zeZ- 0 to 40 ~1.3 to ~10.1 HFO-1243zfHF-HFO-1234yf-HCFO-1233zdE- 0 to 40 ~1.2 to ~11.3 HFO-1243zf

EXAMPLE 6: DECANTATION RANGE OF QUATERNARY MIXTURES

Decantation ranges Mass percentage of HF Isotherm Isotherm IsothermQuaternary 0° C. 25° C. 40° C. HF-HCFO-1233xf-HFC-245cb-HFO- 5-75  5-7015-60 1243zf HF-HFO-1234yf-HFC-245cb-HFO-1243zf 5-75 15-70 45-70HF-HCFO-1233xf-HFO-1234yf-HFO- 5-75 10-65 * 1243zfHF-HCFO-1233xf-HCFO-1233zdE-HFO- 5-75  5-70 10-60 1243zfHF-HCFO-1233xf-HFO-1234zeE-HFO- 5-70 10-60 * 1243zfHF-HCFO-1233xf-HFO-1234zeZ-HFO- 5-75  5-70 10-55 1243zfHF-HFO-1234yf-HFO-1234zeE-HFO- 5-65 * * 1243zfHF-HFO-1234yf-HFO-1234zeZ-HFO- 5-75 10-65 * 1243zfHF-HFC-245cb-HCFO-1233zdE-HFO- 5-75  5-70 15-65 1243zfHF-HFC-245cb-HFO-1234zeE-HFO- 5-75 15-65 * 1243zfHF-HFC-245cb-HFO-1234zeZ-HFO- 5-75 10-70 20-60 1243zfHF-HCFO-1233zdE-HFO-1234zeE-HFO- 5-70 10-60 * 1243zfHF-HCFO-1233zdE-HFO-1234zeZ-HFO- 5-75  5-70 10-55 1243zfHF-HFO-1234zeE-HFO-1234zeZ-HFO- 5-70 10-60 * 1243zfHF-HFO-1234yf-HCFO-1233zdE-HFO- 5-75 10-65 * 1243zf

EXAMPLE 7: PENTERNARY MIXTURES, ISOTHERM AT 25° C.

HF-HCFO-1233xf-HFC-245cb-HCFO-1233zdE-HFO-1243zf

Organics Organics Organics Organics Organics 0.9 F1233xf + 0.033F1233xf + 0.033 F1233xf + 0.034 F1233xf + 0.25 F1233xf + 0.033F1233zdE + 0.9 F1233zdE + 0.033 F1233zdE + 0.033 F1233zdE + 0.25F1233zdE + 0.033 F245cb + 0.033 F245cb + 0.9 F245cb + 0.033 F245cb +0.25 F245cb + 0.034 F1243zf 0.034 F1243zf 0.034 F1243zf 0.9 F1243zf 0.25F1243zf TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES- MASS- PRES- MASS-PRES- MASS- PRES- MASS- PRES- FRAC SURE FRAC SURE FRAC SURE FRAC SUREFRAC SURE HF bar HF bar HF bar HF bar HF bar 0 1.8 0 1.6 0 4.5 0 5.6 03.5 0.05 3.0 0.05 2.8 0.05 5.7 0.05 6.5 0.05 4.6 0.1 3.0 0.1 2.8 0.1 5.70.1 6.6 0.1 4.6 0.15 3.0 0.15 2.8 0.15 5.7 0.15 6.6 0.15 4.6 0.2 3.0 0.22.8 0.2 5.7 0.2 6.5 0.2 4.6 0.25 3.0 0.25 2.8 0.25 5.7 0.25 6.5 0.25 4.60.3 3.0 0.3 2.8 0.3 5.7 0.3 6.5 0.3 4.6 0.35 2.9 0.35 2.8 0.35 5.7 0.356.5 0.35 4.6 0.4 2.9 0.4 2.8 0.4 5.7 0.4 6.5 0.4 4.6 0.45 2.9 0.45 2.70.45 5.7 0.45 6.5 0.45 4.6 0.5 2.9 0.5 2.7 0.5 5.7 0.5 6.5 0.5 4.6 0.552.9 0.55 2.7 0.55 5.7 0.55 6.5 0.55 4.6 0.6 2.9 0.6 2.7 0.6 5.7 0.6 6.50.6 4.6 0.65 2.9 0.65 2.7 0.65 5.7 0.65 6.4 0.65 4.6 0.7 2.9 0.7 2.7 0.75.7 0.7 6.4 0.7 4.7 0.75 2.9 0.75 2.7 0.75 5.7 0.75 6.2 0.75 4.6 0.8 2.80.8 2.6 0.8 5.7 0.8 5.9 0.8 4.4 0.85 2.6 0.85 2.4 0.85 5.6 0.85 5.4 0.854.1 0.9 2.3 0.9 2.2 0.9 4.8 0.9 4.6 0.9 3.5 0.95 1.8 0.95 1.8 0.95 3.40.95 3.3 0.95 2.6 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HCFO-1233xf-HFC-245cb-HFO-1234zeE-HFO-1243zf

Organics Organics Organics Organics Organics 0.9 F1233xf + 0.033F1233xf + 0.033 F1233xf + 0.034 F1233xf + 0.25 F1233xf + 0.033F1234zeE + 0.9 F1234zeE + 0.033 F1234zeE + 0.033 F1234zeE + 0.25F1234zeE + 0.033 F245cb + 0.033 F245cb + 0.9 F245cb + 0.033 F245cb +0.25 F245cb + 0.034 F1243zf 0.034 F1243zf 0.034 F1243zf 0.9 F1243zf 0.25F1243zf TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES- MASS- PRES- MASS-PRES- MASS- PRES- MASS- PRES- FRAC SURE FRAC SURE FRAC SURE FRAC SUREFRAC SURE HF bar HF bar HF bar HF bar HF bar 0 2.0 0 4.8 0 4.6 0 5.7 04.4 0.05 3.1 0.05 5.8 0.05 5.8 0.05 6.6 0.05 5.4 0.1 3.1 0.1 5.8 0.1 5.80.1 6.7 0.1 5.4 0.15 3.1 0.15 5.8 0.15 5.8 0.15 6.6 0.15 5.4 0.2 3.1 0.25.8 0.2 5.8 0.2 6.6 0.2 5.4 0.25 3.1 0.25 5.8 0.25 5.8 0.25 6.6 0.25 5.40.3 3.1 0.3 5.8 0.3 5.8 0.3 6.6 0.3 5.4 0.35 3.1 0.35 5.8 0.35 5.8 0.356.6 0.35 5.4 0.4 3.1 0.4 5.8 0.4 5.8 0.4 6.6 0.4 5.4 0.45 3.1 0.45 5.80.45 5.8 0.45 6.6 0.45 5.4 0.5 3.1 0.5 5.7 0.5 5.8 0.5 6.6 0.5 5.4 0.553.1 0.55 5.7 0.55 5.8 0.55 6.6 0.55 5.4 0.6 3.1 0.6 5.6 0.6 5.8 0.6 6.60.6 5.4 0.65 3.1 0.65 5.5 0.65 5.8 0.65 6.5 0.65 5.4 0.7 3.1 0.7 5.4 0.75.8 0.7 6.4 0.7 5.4 0.75 3.0 0.75 5.2 0.75 5.8 0.75 6.3 0.75 5.3 0.8 2.90.8 4.8 0.8 5.8 0.8 6.0 0.8 5.0 0.85 2.7 0.85 4.3 0.85 5.7 0.85 5.5 0.854.6 0.9 2.3 0.9 3.6 0.9 4.9 0.9 4.7 0.9 3.9 0.95 1.9 0.95 2.6 0.95 3.50.95 3.3 0.95 2.8 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HCFO-1233xf-HFC-245cb-HFO-1234zeZ-HFO-1243zf

Organics Organics Organics Organics Organics 0.9 F1233xf + 0.033F1233xf + 0.033 F1233xf + 0.034 F1233xf + 0.25 F1233xf + 0.033F1234zeZ + 0.9 F1234zeZ + 0.033 F1234zeZ + 0.033 F1234zeZ + 0.25F1234zeZ + 0.033 F245cb + 0.033 F245cb + 0.9 F245cb + 0.033 F245cb +0.25 F245cb + 0.034 F1243zf 0.034 F1243zf 0.034 F1243zf 0.9 F1243zf 0.25F1243zf TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES- MASS- PRES- MASS-PRES- MASS- PRES- MASS- PRES- FRAC SURE FRAC SURE FRAC SURE FRAC SUREFRAC SURE HF bar HF bar HF bar HF bar HF bar 0 1.9 0 2.1 0 4.5 0 5.6 03.6 0.05 3.0 0.05 3.2 0.05 5.7 0.05 6.5 0.05 4.7 0.1 3.0 0.1 3.2 0.1 5.70.1 6.6 0.1 4.7 0.15 3.0 0.15 3.2 0.15 5.7 0.15 6.6 0.15 4.7 0.2 3.0 0.23.2 0.2 5.7 0.2 6.6 0.2 4.7 0.25 3.0 0.25 3.2 0.25 5.7 0.25 6.5 0.25 4.70.3 3.0 0.3 3.2 0.3 5.7 0.3 6.5 0.3 4.7 0.35 3.0 0.35 3.2 0.35 5.7 0.356.5 0.35 4.7 0.4 3.0 0.4 3.2 0.4 5.7 0.4 6.5 0.4 4.7 0.45 3.0 0.45 3.20.45 5.7 0.45 6.5 0.45 4.7 0.5 3.0 0.5 3.2 0.5 5.7 0.5 6.5 0.5 4.7 0.553.0 0.55 3.2 0.55 5.7 0.55 6.5 0.55 4.7 0.6 3.0 0.6 3.2 0.6 5.7 0.6 6.50.6 4.7 0.65 3.0 0.65 3.2 0.65 5.7 0.65 6.5 0.65 4.7 0.7 3.0 0.7 3.2 0.75.7 0.7 6.4 0.7 4.7 0.75 3.0 0.75 3.2 0.75 5.7 0.75 6.2 0.75 4.7 0.8 2.80.8 3.0 0.8 5.7 0.8 5.9 0.8 4.5 0.85 2.6 0.85 2.8 0.85 5.6 0.85 5.4 0.854.2 0.9 2.3 0.9 2.5 0.9 4.8 0.9 4.6 0.9 3.6 0.95 1.8 0.95 1.9 0.95 3.40.95 3.3 0.95 2.6 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HCFO-1233xf-HCFO-1233zdE-HFO-1234zeE-HFO-1243zf

Organics Organics Organics Organics Organics 0.9 F1233xf + 0.033F1233xf + 0.033 F1233xf + 0.034 F1233xf + 0.25 F1233xf + 0.033F1234zeE + 0.9 F1234zeE + 0.033 F1234zeE + 0.033 F1234zeE + 0.251234zeE + 0.033 F1233zdE + 0.033 F1233zdE + 0.9 F1233zdE + 0.033F1233zdE + 0.25 F1233zdE + 0.034 F1243zf 0.034 F1243zf 0.034 F1243zf 0.9F1243zf 0.25 F1243zf TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES- MASS-PRES- MASS- PRES- MASS- PRES- MASS- PRES- FRAC SURE FRAC SURE FRAC SUREFRAC SURE FRAC SURE HF bar HF bar HF bar HF bar HF bar 0 1.9 0 4.7 0 1.70 5.6 0 3.6 0.05 3.0 0.05 5.7 0.05 2.8 0.05 6.5 0.05 4.7 0.1 3.0 0.1 5.70.1 2.8 0.1 6.6 0.1 4.7 0.15 3.0 0.15 5.7 0.15 2.8 0.15 6.6 0.15 4.7 0.23.0 0.2 5.7 0.2 2.8 0.2 6.5 0.2 4.7 0.25 3.0 0.25 5.7 0.25 2.8 0.25 6.50.25 4.6 0.3 2.9 0.3 5.7 0.3 2.7 0.3 6.5 0.3 4.6 0.35 2.9 0.35 5.7 0.352.7 0.35 6.5 0.35 4.6 0.4 2.9 0.4 5.7 0.4 2.7 0.4 6.5 0.4 4.6 0.45 2.90.45 5.7 0.45 2.7 0.45 6.5 0.45 4.6 0.5 2.9 0.5 5.6 0.5 2.7 0.5 6.5 0.54.6 0.55 2.9 0.55 5.6 0.55 2.7 0.55 6.5 0.55 4.6 0.6 2.9 0.6 5.5 0.6 2.70.6 6.5 0.6 4.6 0.65 2.9 0.65 5.4 0.65 2.7 0.65 6.4 0.65 4.5 0.7 2.9 0.75.3 0.7 2.7 0.7 6.3 0.7 4.5 0.75 2.9 0.75 5.0 0.75 2.7 0.75 6.2 0.75 4.30.8 2.7 0.8 4.7 0.8 2.6 0.8 5.9 0.8 4.1 0.85 2.5 0.85 4.2 0.85 2.4 0.855.4 0.85 3.7 0.9 2.2 0.9 3.5 0.9 2.1 0.9 4.6 0.9 3.1 0.95 1.8 0.95 2.50.95 1.7 0.95 3.3 0.95 2.3 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HCFO-1233xf-HCFO-1233zdE-HFO-1234zeZ-HFO-1243zf

Organics Organics Organics Organics Organics 0.9 F1233xf + 0.033F1233xf + 0.033 F1233xf + 0.034 F1233xf + 0.25 F1233xf + 0.033F1234zeZ + 0.9 F1234zeZ + 0.033 F1234zeZ + 0.033 F1234zeZ + 0.25F1234zeZ + 0.033 F1233zdE + 0.033 F1233zdE + 0.9 F1233zdE + 0.033F1233zdE + 0.25 F1233zdE + 0.034 F1243zf 0.034 F1243zf 0.034 F1243zf 0.9F1243zf 0.25 F1243zf TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES- MASS-PRES- MASS- PRES- MASS- PRES- MASS- PRES- FRAC SURE FRAC SURE FRAC SUREFRAC SURE FRAC SURE HF bar HF bar HF bar HF bar HF bar 0 1.7 0 1.9 0 1.50 5.5 0 2.8 0.05 2.8 0.05 3.0 0.05 2.6 0.05 6.4 0.05 3.9 0.1 2.8 0.1 3.00.1 2.6 0.1 6.5 0.1 3.9 0.15 2.8 0.15 3.0 0.15 2.6 0.15 6.5 0.15 3.9 0.22.8 0.2 3.0 0.2 2.6 0.2 6.5 0.2 3.9 0.25 2.8 0.25 3.0 0.25 2.6 0.25 6.50.25 3.9 0.3 2.8 0.3 3.0 0.3 2.6 0.3 6.5 0.3 3.9 0.35 2.8 0.35 3.0 0.352.6 0.35 6.5 0.35 3.9 0.4 2.8 0.4 3.0 0.4 2.6 0.4 6.5 0.4 3.9 0.45 2.80.45 3.0 0.45 2.6 0.45 6.4 0.45 3.9 0.5 2.8 0.5 3.0 0.5 2.6 0.5 6.4 0.53.9 0.55 2.8 0.55 3.0 0.55 2.6 0.55 6.4 0.55 3.9 0.6 2.8 0.6 3.0 0.6 2.60.6 6.4 0.6 3.9 0.65 2.8 0.65 3.0 0.65 2.6 0.65 6.4 0.65 3.8 0.7 2.8 0.73.0 0.7 2.6 0.7 6.3 0.7 3.8 0.75 2.8 0.75 3.0 0.75 2.6 0.75 6.1 0.75 3.70.8 2.7 0.8 2.9 0.8 2.5 0.8 5.8 0.8 3.6 0.85 2.5 0.85 2.7 0.85 2.3 0.855.3 0.85 3.3 0.9 2.2 0.9 2.4 0.9 2.1 0.9 4.5 0.9 2.8 0.95 1.8 0.95 1.90.95 1.7 0.95 3.2 0.95 2.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HCFO-1233xf-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf

Organics Organics Organics Organics Organics 0.9 F1233xf + 0.033F1233xf + 0.033 F1233xf + 0.034 F1233xf + 0.25 F1233xf + 0.033F1234zeE + 0.9 F1234zeE + 0.033 F1234zeE + 0.033 F1234zeE + 0.25F1234zeE + 0.033 F1234zeZ + 0.033 F1234zeZ + 0.9 F1234zeZ + 0.033F1234zeZ + 0.25 F1234zeZ + 0.034 F1243zf 0.034 F1243zf 0.034 F1243zf 0.9F1243zf 0.25 F1243zf TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES- MASS-PRES- MASS- PRES- MASS- PRES- MASS- PRES- FRAC SURE FRAC SURE FRAC SUREFRAC SURE FRAC SURE HF bar HF bar HF bar HF bar HF bar 0 1.9 0 4.7 0 2.10 5.6 0 3.7 0.05 3.0 0.05 5.7 0.05 3.2 0.05 6.5 0.05 4.7 0.1 3.0 0.1 5.70.1 3.2 0.1 6.6 0.1 4.7 0.15 3.0 0.15 5.7 0.15 3.2 0.15 6.6 0.15 4.7 0.23.0 0.2 5.7 0.2 3.2 0.2 6.5 0.2 4.7 0.25 3.0 0.25 5.7 0.25 3.2 0.25 6.50.25 4.7 0.3 3.0 0.3 5.7 0.3 3.2 0.3 6.5 0.3 4.7 0.35 3.0 0.35 5.7 0.353.2 0.35 6.5 0.35 4.7 0.4 3.0 0.4 5.7 0.4 3.2 0.4 6.5 0.4 4.7 0.45 3.00.45 5.7 0.45 3.2 0.45 6.5 0.45 4.7 0.5 3.0 0.5 5.6 0.5 3.2 0.5 6.5 0.54.7 0.55 2.9 0.55 5.6 0.55 3.1 0.55 6.5 0.55 4.6 0.6 2.9 0.6 5.5 0.6 3.10.6 6.5 0.6 4.6 0.65 2.9 0.65 5.4 0.65 3.1 0.65 6.4 0.65 4.6 0.7 2.9 0.75.3 0.7 3.1 0.7 6.3 0.7 4.5 0.75 2.9 0.75 5.0 0.75 3.1 0.75 6.2 0.75 4.40.8 2.8 0.8 4.7 0.8 3.0 0.8 5.9 0.8 4.1 0.85 2.6 0.85 4.2 0.85 2.7 0.855.4 0.85 3.8 0.0 2.2 0.9 3.5 0.9 2.1 0.9 4.6 0.9 3.2 0.95 1.8 0.95 2.50.95 1.9 0.95 3.3 0.95 2.4 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HCFO-1233xf-HFC-245cb-HFO-1234yf-HFO-1243zf

Organics Organics Organics Organics Organics 0.9 F1233xf + 0.033F1233xf + 0.033 F1233xf + 0.034 F1233xf + 0.25 F1233xf + 0.033 F1234yf +0.9 F1234yf + 0.033 F1234yf + 0.033 F1234yf + 0.25 F1234yf + 0.033F245cb + 0.033 F245cb + 0.9 F245cb + 0.033 F245cb + 0.25 F245cb + 0.034F1243zf 0.034 F1243zf 0.034 F1243zf 0.9 F1243zf 0.25 F1243zf TOTAL TOTALTOTAL TOTAL TOTAL MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- MASS-PRES- FRAC SURE FRAC SURE FRAC SURE FRAC SURE FRAC SURE HF bar HF bar HFbar HF bar HF bar 0 2.0 0 6.5 0 4.7 0 5.7 0 4.8 0.05 3.2 0.05 7.5 0.055.8 0.05 6.7 0.05 5.9 0.1 3.2 0.1 7.5 0.1 5.9 0.1 6.7 0.1 5.9 0.15 3.20.15 7.5 0.15 5.9 0.15 6.7 0.15 5.9 0.2 3.2 0.2 7.5 0.2 5.9 0.2 6.7 0.25.9 0.25 3.2 0.25 7.5 0.25 5.9 0.25 6.7 0.25 5.9 0.3 3.2 0.3 7.5 0.3 5.90.3 6.7 0.3 5.9 0.35 3.2 0.35 7.5 0.35 5.9 0.35 6.7 0.35 5.9 0.4 3.2 0.47.5 0.4 5.9 0.4 6.7 0.4 5.9 0.45 3.2 0.45 7.5 0.45 5.9 0.45 6.7 0.45 5.90.5 3.1 0.5 7.5 0.5 5.9 0.5 6.7 0.5 5.9 0.55 3.1 0.55 7.5 0.55 5.9 0.556.7 0.55 5.9 0.6 3.1 0.6 7.5 0.6 5.9 0.6 6.6 0.6 5.9 0.65 3.1 0.65 7.50.65 5.9 0.65 6.6 0.65 5.9 0.7 3.1 0.7 7.5 0.7 5.9 0.7 6.5 0.7 5.9 0.753.1 0.75 7.4 0.75 5.9 0.75 6.3 0.75 5.9 0.8 3.0 0.8 7.0 0.8 5.9 0.8 6.10.8 5.6 0.85 2.7 0.85 6.5 0.85 5.8 0.85 5.6 0.85 5.2 0.9 2.4 0.9 5.4 0.95.0 0.9 4.7 0.9 4.4 0.95 1.9 0.95 3.8 0.95 3.5 0.95 3.4 0.95 3.1 1 1.2 11.2 1 1.2 1 1.2 1 1.2

HF-HCFO-1233xf-HFO-1234yf-HFO-1234zeE-HFO-1243zf

Organics Organics Organics Organics Organics 0.9 F1233xf + 0.033F1233xf + 0.033 F1233xf + 0.034 F1233xf + 0.25 F1233xf + 0.033F1234zeE + 0.9 F1234zeE + 0.033 F1234zeE + 0.033 F1234zeE + 0.25F1234zeE + 0.033 F1243zf + 0.033 F1243zf + 0.9 F1243zf + 0.033 F1243zf +0.25 F1243zf + 0.034 F1234yf 0.034 F1234yf 0.034 F1234yf 0.9 F1234yf0.25 F1234yf TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES- MASS- PRES- MASS-PRES- MASS- PRES- MASS- PRES- FRAC SURE FRAC SURE FRAC SURE FRAC SUREFRAC SURE HF bar HF bar HF bar HF bar HF bar 0 2.1 0 4.9 0 5.7 0 6.5 04.9 0.05 3.2 0.05 5.8 0.05 6.7 0.05 7.5 0.05 5.9 0.1 3.2 0.1 5.9 0.1 6.70.1 7.5 0.1 5.9 0.15 3.2 0.15 5.9 0.15 6.7 0.15 7.5 0.15 5.9 0.2 3.2 0.25.9 0.2 6.7 0.2 7.5 0.2 5.9 0.25 3.2 0.25 5.9 0.25 6.7 0.25 7.5 0.25 5.90.3 3.2 0.3 5.9 0.3 6.7 0.3 7.5 0.3 5.9 0.35 3.2 0.35 5.9 0.35 6.7 0.357.5 0.35 5.9 0.4 3.1 0.4 5.8 0.4 6.7 0.4 7.5 0.4 5.9 0.45 3.1 0.45 5.80.45 6.7 0.45 7.5 0.45 5.9 0.5 3.1 0.5 5.8 0.5 6.7 0.5 7.5 0.5 5.9 0.553.1 0.55 5.8 0.55 6.7 0.55 7.5 0.55 5.9 0.6 3.1 0.6 5.7 0.6 6.6 0.6 7.50.6 5.9 0.65 3.1 0.65 5.6 0.65 6.6 0.65 7.5 0.65 5.8 0.7 3.1 0.7 5.4 0.76.5 0.7 7.5 0.7 5.7 0.75 3.1 0.75 5.2 0.75 6.3 0.75 7.3 0.75 5.6 0.8 2.90.8 4.9 0.8 6.0 0.8 7.0 0.8 5.3 0.85 2.7 0.85 4.4 0.85 5.5 0.85 6.4 0.854.8 0.9 2.4 0.9 3.6 0.9 4.7 0.9 5.4 0.9 4.0 0.95 1.9 0.95 2.6 0.95 3.30.95 3.7 0.95 2.9 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HCFO-1233xf-HFO-1234yf-HFO-1234zeZ-HFO-1243zf

Organics Organics Organics Organics Organics 0.9 F1233xf + 0.033F1233xf + 0.033 F1233xf + 0.034 F1233xf + 0.25 F1233xf + 0.033F1234zeZ + 0.9 F1234zeZ + 0.033 F1234zeZ + 0.033 F1234zeZ + 0.25F1234zeZ + 0.033 F1243zf + 0.033 F1243zf + 0.9 F1243zf + 0.033 F1243zf +0.25 F1243zf + 0.034 F1234yf 0.034 F1234yf 0.034 F1234yf 0.9 F1234yf0.25 F1234yf TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES- MASS- PRES- MASS-PRES- MASS- PRES- MASS- PRES- FRAC SURE FRAC SURE FRAC SURE FRAC SUREFRAC SURE HF bar HF bar HF bar HF bar HF bar 0 1.9 0 2.1 0 5.6 0 6.4 04.1 0.05 3.1 0.05 3.2 0.05 6.6 0.05 7.4 0.05 5.2 0.1 3.1 0.1 3.2 0.1 6.60.1 7.4 0.1 5.2 0.15 3.1 0.15 3.2 0.15 6.6 0.15 7.4 0.15 5.2 0.2 3.1 0.23.2 0.2 6.6 0.2 7.4 0.2 5.2 0.25 3.1 0.25 3.2 0.25 6.6 0.25 7.4 0.25 5.20.3 3.1 0.3 3.2 0.3 6.6 0.3 7.4 0.3 5.2 0.35 3.0 0.35 3.2 0.35 6.6 0.357.4 0.35 5.2 0.4 3.0 0.4 3.2 0.4 6.6 0.4 7.4 0.4 5.2 0.45 3.0 0.45 3.20.45 6.6 0.45 7.4 0.45 5.2 0.5 3.0 0.5 3.2 0.5 6.6 0.5 7.4 0.5 5.2 0.553.0 0.55 3.2 0.55 6.6 0.55 7.4 0.55 5.2 0.5 3.0 0.6 3.2 0.6 6.5 0.6 7.40.6 5.2 0.65 3.0 0.65 3.2 0.65 6.5 0.65 7.4 0.65 5.2 0.7 3.0 0.7 3.2 0.76.4 0.7 7.4 0.7 5.1 0.75 3.0 0.75 3.2 0.75 6.2 0.75 7.2 0.75 5.0 0.8 2.90.8 3.1 0.8 6.0 0.8 6.9 0.8 4.8 0.85 2.6 0.85 2.8 0.85 5.5 0.85 6.3 0.854.4 0.9 2.3 0.9 2.5 0.9 4.6 0.9 5.3 0.9 3.7 0.95 1.8 0.95 2.0 0.95 3.30.95 3.7 0.95 2.7 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HCFO-1233xf-HFO-1234yf-HCFO-1233zdE-HFO-1243zf

Organics Organics Organics Organics Organics 0.9 F1233xf + 0.033F1233xf + 0.033 F1233xf + 0.034 F1233xf + 0.25 F1233xf + 0.033 F1243zf +0.9 F1243zf + 0.033 F1243zf + 0.033 F1243zf + 0.25 F1243zf + 0.033F1233zdE + 0.033 F1233zdE + 0.9 F1233zdE + 0.033 F1233zdE + 0.25F1233zdE + 0.034 F1234yf 0.034 F1234yf 0.034 F1234yf 0.9 F1234yf 0.25F1234yf TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES- MASS- PRES- MASS-PRES- MASS- PRES- MASS- PRES- FRAC SURE FRAC SURE FRAC SURE FRAC SUREFRAC SURE HF bar HF bar HF bar HF bar HF bar 0 1.9 0 5.6 0 1.7 0 6.4 04.1 0.05 3.0 0.05 6.6 0.05 2.8 0.05 7.4 0.05 5.2 0.1 3.0 0.1 6.6 0.1 2.80.1 7.4 0.1 5.2 0.15 3.0 0.15 6.6 0.15 2.8 0.15 7.4 0.15 5.2 0.2 3.0 0.26.6 0.2 2.8 0.2 7.4 0.2 5.2 0.25 3.0 0.25 6.6 0.25 2.8 0.25 7.4 0.25 5.20.3 3.0 0.3 6.6 0.3 2.8 0.3 7.4 0.3 5.2 0.35 3.0 0.35 6.6 0.35 2.8 0.357.4 0.35 5.2 0.4 3.0 0.4 6.6 0.4 2.8 0.4 7.4 0.4 5.2 0.45 3.0 0.45 6.60.45 2.8 0.45 7.4 0.45 5.2 0.5 3.0 0.5 6.6 0.5 2.8 0.5 7.4 0.5 5.1 0.553.0 0.55 6.6 0.55 2.8 0.55 7.4 0.55 5.1 0.6 3.0 0.6 6.5 0.6 2.8 0.6 7.40.6 5.1 0.65 3.0 0.65 6.5 0.65 2.8 0.65 7.4 0.65 5.1 0.7 3.0 0.7 6.4 0.72.8 0.7 7.4 0.7 5.1 0.75 3.0 0.75 6.2 0.75 2.8 0.75 7.2 0.75 4.9 0.8 2.80.8 6.0 0.8 2.7 0.8 6.9 0.8 4.7 0.85 2.6 0.85 5.5 0.85 2.5 0.85 6.3 0.854.3 0.9 2.3 0.9 4.6 0.9 2.2 0.9 5.3 0.9 3.7 0.95 1.8 0.95 3.3 0.95 1.80.95 3.7 0.95 2.7 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HFO-1234yf-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf

Organics Organics Organics Organics Organics 0.9 F1234yf + 0.033F1234yf + 0.033 F1234yf + 0.034 F1234yf + 0.25 F1234yf + 0.033F1234zeZ + 0.9 F1234zeZ + 0.033 F1234zeZ + 0.033 F1234zeZ + 0.25F1234zeZ + 0.033 F1234zeE + 0.033 F1234zeE + 0.9 F1234zeE + 0.033F1234zeE + 0.25 F1234zeE + 0.034 F1243zf 0.034 F1243zf 0.034 F1243zf 0.9F1243zf 0.25 F1243zf TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES- MASS-PRES- MASS- PRES- MASS- PRES- MASS- PRES- FRAC SURE FRAC SURE FRAC SUREFRAC SURE FRAC SURE HF bar HF bar HF bar HF bar HF bar 0 6.5 0 2.2 0 4.90 5.7 0 4.9 0.05 7.5 0.05 3.3 0.05 5.8 0.05 6.7 0.05 5.9 0.1 7.5 0.1 3.30.1 5.9 0.1 6.7 0.1 5.9 0.15 7.5 0.15 3.3 0.15 5.8 0.15 6.7 0.15 5.9 0.27.5 0.2 3.3 0.2 5.8 0.2 6.7 0.2 5.9 0.25 7.5 0.25 3.3 0.25 5.8 0.25 6.70.25 5.9 0.3 7.5 0.3 3.3 0.3 5.8 0.3 6.7 0.3 5.9 0.35 7.5 0.35 3.3 0.355.8 0.35 6.7 0.35 5.9 0.4 7.5 0.4 3.3 0.4 5.8 0.4 6.7 0.4 5.9 0.45 7.50.45 3.3 0.45 5.8 0.45 6.7 0.45 5.9 0.5 7.5 0.5 3.3 0.5 5.8 0.5 6.7 0.55.9 0.55 7.5 0.55 3.3 0.55 5.8 0.55 6.7 0.55 5.9 0.6 7.5 0.6 3.3 0.6 5.70.6 6.6 0.6 5.9 0.65 7.5 0.65 3.3 0.65 5.6 0.65 6.6 0.65 5.8 0.7 7.5 0.73.3 0.7 5.4 0.7 6.5 0.7 5.7 0.75 7.3 0.75 3.3 0.75 5.2 0.75 6.3 0.75 5.60.8 7.0 0.8 3.1 0.8 4.9 0.8 6.0 0.8 5.3 0.85 6.4 0.85 2.9 0.85 4.4 0.855.6 0.85 4.8 0.9 5.4 0.9 2.5 0.9 3.7 0.9 4.7 0.9 4.1 0.95 3.7 0.95 2.00.95 2.6 0.95 3.3 0.95 2.9 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HFO-1234yf-HFO-1234zeE-HCFO-1233zdE-HFO-1243zf

Organics Organics Organics Organics Organics 0.9 F1234yf + 0.033F1234yf + 0.033 F1234yf + 0.034 F1234yf + 0.25 F1234yf + 0.033F1233zdE + 0.9 F1233zdE + 0.033 F1233zdE + 0.033 F1233zdE + 0.25F1233zdE + 0.033 F1234zeE + 0.033 F1234zeE + 0.9 F1234zeE + 0.033F1234zeE + 0.25 F1234zeE + 0.034 F1243zf 0.034 F1243zf 0.034 F1243zf 0.9F1243zf 0.25 F1243zf TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES- MASS-PRES- MASS- PRES- MASS- PRES- MASS- PRES- FRAC SURE FRAC SURE FRAC SUREFRAC SURE FRAC SURE HF bar HF bar HF bar HF bar HF bar 0 6.5 0 1.9 0 4.90 5.7 0 4.8 0.05 7.5 0.05 3.0 0.05 5.8 0.05 6.7 0.05 5.8 0.1 7.5 0.1 3.00.1 5.9 0.1 6.7 0.1 5.9 0.15 7.5 0.15 3.0 0.15 5.8 0.15 6.7 0.15 5.9 0.27.5 0.2 3.0 0.2 5.8 0.2 6.7 0.2 5.9 0.25 7.5 0.25 3.0 0.25 5.8 0.25 6.70.25 5.9 0.3 7.5 0.3 3.0 0.3 5.8 0.3 6.7 0.3 5.9 0.35 7.5 0.35 2.9 0.355.8 0.35 6.7 0.35 5.9 0.4 7.5 0.4 2.9 0.4 5.8 0.4 6.7 0.4 5.9 0.45 7.50.45 2.9 0.45 5.8 0.45 6.7 0.45 5.9 0.5 7.5 0.5 2.9 0.5 5.8 0.5 6.7 0.55.8 0.55 7.5 0.55 2.9 0.55 5.8 0.55 6.6 0.55 5.8 0.6 7.5 0.6 2.9 0.6 5.70.6 6.6 0.6 5.8 0.65 7.5 0.65 2.9 0.65 5.6 0.65 6.6 0.65 5.8 0.7 7.5 0.72.9 0.7 5.4 0.7 6.5 0.7 5.7 0.75 7.3 0.75 2.9 0.75 5.2 0.75 6.3 0.75 5.50.8 7.0 0.8 2.7 0.8 4.9 0.8 6.0 0.8 5.2 0.85 6.4 0.85 2.5 0.85 4.4 0.855.5 0.85 4.8 0.9 5.4 0.9 2.2 0.9 3.6 0.9 4.7 0.9 4.0 0.95 3.7 0.95 1.80.95 2.6 0.95 3.3 0.95 2.9 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HFO-1234yf-HFO-1234zeZ-HCFO-1233zdE-HFO-1243zf

Organics Organics Organics Organics Organics 0.9 F1234yf + 0.033F1234yf + 0.033 F1234yf + 0.034 F1234yf + 0.25 F1234yf + 0.033F1233zdE + 0.9 F1233zdE + 0.033 F1233zdE + 0.033 F1233zdE + 0.25F1233zdE + 0.033 F1234zeZ + 0.033 F1234zeZ + 0.9 F1234zeZ + 0.033F1234zeZ + 0.25 F1234zeZ + 0.034 F1243zf 0.034 F1243zf 0.034 F1243zf 0.9F1243zf 0.25 F1243zf TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES- MASS-PRES- MASS- PRES- MASS- PRES- MASS- PRES- FRAC SURE FRAC SURE FRAC SUREFRAC SURE FRAC SURE HF bar HF bar HF bar HF bar HF bar 0 6.4 0 1.7 0 2.10 5.6 0 4.1 0.05 7.4 0.05 2.9 0.05 3.2 0.05 6.6 0.05 5.2 0.1 7.4 0.1 2.90.1 3.2 0.1 6.6 0.1 5.2 0.15 7.4 0.15 2.9 0.15 3.2 0.15 6.6 0.15 5.2 0.27.4 0.2 2.9 0.2 3.2 0.2 6.6 0.2 5.2 0.25 7.4 0.25 2.8 0.25 3.2 0.25 6.60.25 5.2 0.3 7.4 0.3 2.8 0.3 3.2 0.3 6.6 0.3 5.2 0.35 7.4 0.35 2.8 0.353.2 0.35 6.6 0.35 5.1 0.4 7.4 0.4 2.8 0.4 3.2 0.4 6.6 0.4 5.1 0.45 7.40.45 2.8 0.45 3.2 0.45 6.6 0.45 5.1 0.5 7.4 0.5 2.8 0.5 3.2 0.5 6.6 0.55.1 0.55 7.4 0.55 2.8 0.55 3.2 0.55 6.6 0.55 5.1 0.6 7.4 0.6 2.8 0.6 3.20.6 6.5 0.6 5.1 0.65 7.4 0.65 2.8 0.65 3.2 0.65 6.5 0.65 5.1 0.7 7.4 0.72.8 0.7 3.2 0.7 6.4 0.7 5.1 0.75 7.2 0.75 2.8 0.75 3.2 0.75 6.2 0.75 5.00.8 6.9 0.8 2.7 0.8 3.0 0.8 5.9 0.8 4.7 0.85 6.3 0.85 2.5 0.85 2.8 0.855.5 0.85 4.3 0.9 5.3 0.9 2.2 0.9 2.5 0.9 4.6 0.9 3.7 0.95 3.7 0.95 1.80.95 2.0 0.95 3.3 0.95 2.7 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HFO-1234yf-HFC-245cb-HFO-1234zeE-HFO-1243zf

Organics Organics Organics Organics Organics 0.9 F1234yf + 0.033F1234yf + 0.033 F1234yf + 0.034 F1234yf + 0.25 F1234yf + 0.033F1234zeE + 0.9 F1234zeE + 0.033 F1234zeE + 0.033 F1234zeE + 0.25F1234zeE + 0.033 F245cb + 0.033 F245cb + 0.09 F245cb + 0.033 F245cb +0.25 F245cb + 0.034 F1243zf 0.034 F1243zf 0.034 F1243zf 0.09 F1243zf0.25 F1243zf TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES- MASS- PRES- MASS-PRES- MASS- PRES- MASS- PRES- FRAC SURE FRAC SURE FRAC SURE FRAC SUREFRAC SURE HF bar HF bar HF bar HF bar HF bar 0 6.6 0 5.0 0 4.8 0 5.8 05.6 0.05 7.6 0.05 5.9 0.05 6.0 0.05 6.8 0.05 6.6 0.1 7.6 0.1 6.0 0.1 6.00.1 6.8 0.1 6.6 0.15 7.6 0.15 6.0 0.15 6.0 0.15 6.8 0.15 6.6 0.2 7.6 0.26.0 0.2 6.0 0.2 6.8 0.2 6.6 0.25 7.6 0.25 6.0 0.25 6.0 0.25 6.8 0.25 6.60.3 7.6 0.3 6.0 0.3 6.0 0.3 6.8 0.3 6.6 0.35 7.6 0.35 6.0 0.35 6.0 0.356.8 0.35 6.6 0.4 7.6 0.4 6.0 0.4 6.0 0.4 6.8 0.4 6.6 0.45 7.6 0.45 5.90.45 6.0 0.45 6.8 0.45 6.6 0.5 7.6 0.5 5.9 0.5 6.0 0.5 6.8 0.5 6.6 0.557.6 0.55 5.9 0.55 6.0 0.55 6.7 0.55 6.6 0.6 7.6 0.6 5.8 0.6 6.0 0.6 6.70.6 6.6 0.65 7.6 0.65 5.7 0.65 5.9 0.65 6.7 0.65 6.6 0.7 7.6 0.7 5.6 0.75.9 0.7 6.6 0.7 6.6 0.75 7.4 0.75 5.3 0.75 5.9 0.75 6.4 0.75 6.4 0.8 7.10.8 5.0 0.8 5.9 0.8 6.1 0.8 6.1 0.85 6.5 0.85 4.5 0.85 5.8 0.85 5.6 0.855.6 0.9 5.5 0.9 3.7 0.9 5.0 0.9 4.8 0.9 4.8 0.95 3.8 0.95 2.7 0.95 3.50.95 3.4 0.95 3.4 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HFO-1234yf-HFC-245cb-HFO-1234zeZ-HFO-1243zf

Organics Organics Organics Organics Organics 0.9 F1234yf + 0.033F1234yf + 0.033 F1234yf + 0.034 F1234yf + 0.25 F1234yf + 0.033F1234zeZ + 0.9 F1234zeZ + 0.033 F1234zeZ + 0.033 F1234zeZ + 0.25F1234zeZ + 0.033 F245cb + 0.033 F245cb + 0.9 F245cb + 0.033 F245cb +0.25 F245cb + 0.034 F1243zf 0.034 F1243zf 0.034 F1243zf 0.9 F1243zf 0.25F1243zf TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES- MASS- PRES- MASS-PRES- MASS- PRES- MASS- PRES- FRAC SURE FRAC SURE FRAC SURE FRAC SUREFRAC SURE HF bar HF bar HF bar HF bar HF bar 0 6.5 0 2.2 0 4.7 0 5.7 04.8 0.05 7.5 0.05 3.3 0.05 5.8 0.05 6.7 0.05 5.9 0.1 7.5 0.1 3.3 0.1 5.80.1 6.7 0.1 5.9 0.15 7.5 0.15 3.3 0.15 5.8 0.15 6.7 0.15 5.9 0.2 7.5 0.23.3 0.2 5.8 0.2 6.7 0.2 5.9 0.25 7.5 0.25 3.3 0.25 5.8 0.25 6.7 0.25 5.90.3 7.5 0.3 3.3 0.3 5.8 0.3 6.7 0.3 5.9 0.35 7.5 0.35 3.3 0.35 5.8 0.356.7 0.35 5.9 0.4 7.5 0.4 3.3 0.4 5.8 0.4 6.7 0.4 5.9 0.45 7.5 0.45 3.30.45 5.8 0.45 6.7 0.45 5.9 0.5 7.5 0.5 3.3 0.5 5.8 0.5 6.7 0.5 5.9 0.557.5 0.55 3.3 0.55 5.8 0.55 6.7 0.55 5.9 0.6 7.5 0.6 3.3 0.6 5.8 0.6 6.60.6 5.9 0.65 7.5 0.65 3.3 0.65 5.8 0.65 6.6 0.65 5.9 0.7 7.5 0.7 3.3 0.75.9 0.7 6.5 0.7 5.9 0.75 7.3 0.75 3.3 0.75 5.9 0.75 6.3 0.75 5.9 0.8 7.00.8 3.2 0.8 5.9 0.8 6.1 0.8 5.6 0.85 6.5 0.85 2.9 0.85 5.8 0.85 5.6 0.855.2 0.9 5.4 0.9 2.6 0.9 5.0 0.9 4.7 0.9 4.4 0.95 3.8 0.95 2.0 0.95 3.50.95 3.4 0.95 3.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HFO-1234yf-HFC-245cb-HCFO-1233zdE-HFO-1243zf

Organics Organics Organics Organics Organics 0.9 F1234yf + 0.033F1234yf + 0.033 F1234yf + 0.034 F1234yf + 0.25 F1234yf + 0.033F1233zdE + 0.9 F1233zdE + 0.033 F1233zdE + 0.033 F1233zdE + 0.25F1233zdE + 0.033 F245cb + 0.033 F245cb + 0.9 F245cb + 0.033 F245cb +0.25 F245cb + 0.034 F1243zf 0.034 F1243zf 0.034 F1243zf 0.9 F1243zf 0.25F1243zf TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES- MASS- PRES- MASS-PRES- MASS- PRES- MASS- PRES- FRAC SURE FRAC SURE FRAC SURE FRAC SUREFRAC SURE HF bar HF bar HF bar HF bar HF bar 0 6.5 0 1.8 0 4.7 0 5.7 04.8 0.05 7.5 0.05 2.9 0.05 5.8 0.05 6.7 0.05 5.9 0.1 7.5 0.1 2.9 0.1 5.80.1 6.7 0.1 5.9 0.15 7.5 0.15 2.9 0.15 5.8 0.15 6.7 0.15 5.9 0.2 7.5 0.22.9 0.2 5.8 0.2 6.7 0.2 5.9 0.25 7.5 0.25 2.9 0.25 5.8 0.25 6.7 0.25 5.90.3 7.5 0.3 2.9 0.3 5.8 0.3 6.7 0.3 5.9 0.35 7.5 0.35 2.9 0.35 5.8 0.356.7 0.35 5.9 0.4 7.5 0.4 2.9 0.4 5.8 0.4 6.7 0.4 5.9 0.45 7.5 0.45 2.90.45 5.8 0.45 6.7 0.45 5.9 0.5 7.5 0.5 2.9 0.5 5.8 0.5 6.7 0.5 5.9 0.557.5 0.55 2.9 0.55 5.8 0.55 6.7 0.55 5.9 0.6 7.5 0.6 2.9 0.6 5.8 0.6 6.60.6 5.9 0.65 7.5 0.65 2.9 0.65 5.8 0.55 6.6 0.65 5.9 0.7 7.5 0.7 2.9 0.75.8 0.7 6.5 0.7 5.9 0.75 7.3 0.75 2.9 0.75 5.8 0.75 6.3 0.75 5.8 0.8 7.00.8 2.8 0.8 5.8 0.8 6.1 0.8 5.6 0.85 6.5 0.85 2.6 0.85 5.8 0.85 5.6 0.855.1 0.9 5.4 0.9 2.3 0.9 5.0 0.9 4.7 0.9 4.4 0.95 3.8 0.95 1.3 0.95 3.50.95 3.4 0.95 3.1 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HFC-245cb-HCFO-1233zdE-HFO-1234zeE-HFO-1243zf

Organics Organics Organics Organics Organics 0.9 F245cb + 0.033 F245cb +0.033 F245cb + 0.034 F245cb + 0.25 F245cb + 0.033 F1234zeE + 0.9F1234zeE + 0.033 F1234zeE + 0.033 F1234zeE + 0.25 F1234zeE + 0.033F1233zdE + 0.033 F1233zdE + 0.9 F1233zdE + 0.033 F1233zdE + 0.25F1233zdE + 0.034 F1243zf 0.033 F1243zf 0.034 F1243zf 0.9 F1243zf 0.25F1243zf TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES- MASS- PRES- MASS-PRES- MASS- PRES- MASS- PRES- FRAC SURE FRAC SURE FRAC SURE FRAC SUREFRAC SURE HF bar HF bar HF bar HF bar HF bar 0 4.6 0 4.8 0 1.8 0 5.7 04.3 0.05 5.8 0.05 5.8 0.05 2.9 0.05 6.6 0.05 5.4 0.1 5.8 0.1 5.8 0.1 2.90.1 6.6 0.1 5.4 0.15 5.8 0.15 5.8 0.15 2.9 0.15 6.6 0.15 5.4 0.2 5.8 0.25.8 0.2 2.9 0.2 6.6 0.2 5.4 0.25 5.8 0.25 5.8 0.25 2.9 0.25 6.6 0.25 5.40.3 5.8 0.3 5.8 0.3 2.9 0.3 6.6 0.3 5.4 0.35 5.8 0.35 5.8 0.35 2.9 0.356.6 0.35 5.4 0.4 5.8 0.4 5.8 0.4 2.9 0.4 6.6 0.4 5.4 0.45 5.8 0.45 5.80.45 2.9 0.45 6.6 0.45 5.4 0.5 5.8 0.5 5.7 0.5 2.9 0.5 6.6 0.5 5.4 0.555.8 0.55 5.7 0.55 2.9 0.55 6.6 0.55 5.4 0.6 5.8 0.6 5.6 0.6 2.9 0.6 6.60.6 5.4 0.65 5.8 0.65 5.5 0.65 2.8 0.65 6.5 0.65 5.4 0.7 5.8 0.7 5.4 0.72.8 0.7 6.4 0.7 5.4 0.75 5.8 0.75 5.2 0.75 5.8 0.75 6.3 0.75 5.2 0.8 5.80.8 4.8 0.8 2.7 0.8 6.0 0.8 5.0 0.85 5.7 0.85 4.3 0.85 2.5 0.85 5.5 0.854.5 0.9 4.9 0.9 3.6 0.9 2.2 0.9 4.7 0.9 3.9 0.95 3.5 0.95 2.6 0.95 1.80.95 3.3 0.95 2.8 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HFC-245cb-HCFO-1233zdE-HFO-1234zeZ-HFO-1243zf

Organics Organics Organics Organics Organics 0.9 F245cb + 0.033 F245cb +0.033 F245cb + 0.034 F245cb + 0.25 F245cb + 0.033 F1234zeZ + 0.9F1234zeZ + 0.033 F1234zeZ + 0.033 F1234zeZ + 0.25 F1234zeZ + 0.033F1233zdE + 0.033 F1233zdE + 0.9 F1233zdE + 0.033 F1233zdE + 0.25F1233zdE + 0.034 F1243zf 0.034 F1243zf 0.034 F1243zf 0.9 F1243zf 0.25F1243zf TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES- MASS- PRES- MASS-PRES- MASS- PRES- MASS- PRES- FRAC SURE FRAC SURE FRAC SURE FRAC SUREFRAC SURE HF bar HF bar HF bar HF bar HF bar 0 4.5 0 2.0 0 1.7 0 5.6 03.5 0.05 5.7 0.05 3.2 0.05 2.8 0.05 6.5 0.05 4.6 0.1 5.7 0.1 3.2 0.1 2.80.1 6.6 0.1 4.6 0.15 5.7 0.15 3.2 0.15 2.8 0.15 6.6 0.15 4.6 0.2 5.7 0.23.2 0.2 2.8 0.2 6.5 0.2 4.6 0.25 5.7 0.25 3.2 0.25 2.8 0.25 6.5 0.25 4.60.3 5.7 0.3 3.2 0.3 2.8 0.3 6.5 0.3 4.6 0.35 5.7 0.35 3.2 0.35 2.8 0.356.5 0.35 4.6 0.4 5.7 0.4 3.2 0.4 2.8 0.4 6.5 0.4 4.6 0.45 5.7 0.45 3.20.45 2.8 0.45 6.5 0.45 4.6 0.5 5.7 0.5 3.2 0.5 2.8 0.5 6.5 0.5 4.7 0.555.7 0.55 3.2 0.55 2.8 0.55 6.5 0.55 4.7 0.6 5.7 0.6 3.2 0.6 2.8 0.6 6.50.6 4.7 0.65 5.7 0.65 3.2 0.65 2.8 0.65 6.4 0.65 4.7 0.7 5.7 0.7 3.2 0.72.8 0.7 6.4 0.7 4.7 0.75 5.7 0.75 3.1 0.75 2.8 0.75 6.2 0.75 4.7 0.8 5.70.8 3.0 0.8 2.6 0.8 5.9 0.8 4.5 0.85 5.6 0.85 2.8 0.85 2.4 0.85 5.4 0.854.1 0.9 4.8 0.9 2.5 0.9 2.2 0.9 4.6 0.9 3.5 0.95 3.4 0.95 1.9 0.95 1.80.95 3.3 0.95 2.6 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HCFO-1233zdE-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf

Organics Organics Organics Organics Organics 0.9 F1234zeE + 0.033F1234zeE + 0.033 F1234zeE + 0.034 F1234zeE + 0.25 F1234zeE + 0.033F1234zeZ + 0.9 F1234zeZ + 0.033 F1234zeZ + 0.033 F1234zeZ + 0.25F1234zeZ + 0.033 F1233zdE + 0.033 F1233zdE + 0.9 F1233zdE + 0.033F1233zdE + 0.25 F1233zdE + 0.034 F1243zf 0.034 F1243zf 0.034 F1243zf 0.9F1243zf 0.25 F1243zf MASS- TOTAL MASS- TOTAL MASS- TOTAL MASS- TOTALMASS- TOTAL FRAC PRES FRAC PRES FRAC PRES FRAC PRES FRAC PRES HF bar HFbar HF bar HF bar HF bar 0 4.7 0 2.1 0 1.7 0 5.6 0 3.6 0.05 5.7 0.05 3.20.05 2.8 0.05 6.5 0.05 4.7 0.1 5.7 0.1 3.2 0.1 2.8 0.1 6.6 0.1 4.7 0.155.7 0.15 3.2 0.15 2.8 0.15 6.5 0.15 4.7 0.2 5.7 0.2 3.2 0.2 2.8 0.2 6.50.2 4.7 0.25 5.7 0.25 3.2 0.25 2.8 0.25 6.5 0.25 4.7 0.3 5.7 0.3 3.2 0.32.8 0.3 6.5 0.3 4.6 0.35 5.7 0.35 3.1 0.35 2.8 0.35 6.5 0.35 4.6 0.4 5.70.4 3.1 0.4 2.8 0.4 6.5 0.4 4.6 0.45 5.7 0.45 3.1 0.45 2.7 0.45 6.5 0.454.6 0.5 5.6 0.5 3.1 0.5 2.7 0.5 6.5 0.5 4.6 0.55 5.6 0.55 3.1 0.55 2.70.55 6.5 0.55 4.6 0.6 5.5 0.6 3.1 0.6 2.7 0.6 6.5 0.6 4.6 0.65 5.4 0.653.1 0.65 2.7 0.65 6.4 0.65 4.6 0.7 5.3 0.7 3.1 0.7 2.7 0.7 6.3 0.7 4.50.75 5.0 0.75 3.1 0.75 2.7 0.75 6.2 0.75 4.3 0.8 4.7 0.8 3.0 0.8 2.6 0.85.9 0.8 4.1 0.85 4.2 0.85 2.7 0.85 2.4 0.85 5.4 0.85 3.7 0.9 3.5 0.9 2.40.9 2.1 0.9 4.6 0.0 3.2 0.95 2.5 0.95 1.9 0.95 1.7 0.95 3.3 0.95 2.4 11.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HFC-245cb-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf

Organics Organics Organics Organics Organics 0.9 F245cb + 0.033 F245cb +0.033 F245cb + 0.034 F245cb + 0.25 F245cb + 0.033 F1234zeE + 0.9F1234zeE + 0.033 F1234zeE + 0.033 F1234zeE + 0.25 F1234zeE + 0.033F1234zeZ + 0.033 F1234zeZ + 0.9 F1234zeZ + 0.033 F1234zeZ + 0.25F1234zeZ + 0.034 F1243zf 0.034 F1243zf 0.034 F1243zf 0.9 F1243zf 0.25F1243zf TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES- MASS- PRES- MASS-PRES- MASS- PRES- MASS- PRES- FRAC SURE FRAC SURE FRAC SURE FRAC SUREFRAC SURE HF bar HF bar HF bar HF bar HF bar 0 4.6 0 4.8 0 2.2 0 5.7 04.4 0.05 5.8 0.05 5.8 0.05 3.3 0.05 6.6 0.05 5.4 0.1 5.8 0.1 5.8 0.1 3.30.1 6.7 0.1 5.4 0.15 5.8 0.15 6.8 0.15 3.3 0.15 6.6 0.15 5.4 0.2 5.8 0.25.8 0.2 3.3 0.2 6.6 0.2 5.4 0.25 5.8 0.25 5.8 0.25 3.3 0.25 6.6 0.25 5.40.3 5.8 0.3 5.8 0.3 3.3 0.3 6.6 0.3 5.4 0.35 5.8 0.35 5.8 0.35 3.3 0.356.6 0.35 5.4 0.4 5.8 0.4 5.8 0.4 3.3 0.4 6.6 0.4 5.4 0.45 5.8 0.45 5.80.45 3.3 0.45 6.6 0.45 5.4 0.5 5.8 0.5 5.7 0.5 3.3 0.5 6.6 0.5 5.4 0.555.8 0.55 5.7 0.55 3.3 0.55 6.6 0.55 5.4 0.6 5.8 0.6 5.6 0.6 3.3 0.6 6.60.6 5.4 0.65 5.8 0.65 5.5 0.65 3.3 0.65 6.5 0.65 5.4 0.7 5.8 0.7 5.4 0.73.2 0.7 6.4 0.7 5.4 0.75 5.8 0.75 5.2 0.75 3.2 0.75 6.3 0.75 5.3 0.8 5.80.8 4.8 0.8 3.1 0.8 6.0 0.8 5.0 0.85 5.7 0.85 4.3 0.85 2.9 0.85 5.5 0.854.6 0.9 4.9 0.9 3.6 0.9 2.5 0.9 4.7 0.9 3.9 0.95 3.5 0.95 2.6 0.95 2.00.95 3.3 0.95 2.8 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

EXAMPLE 8: TEMPERATURE AND PRESSURE RANGE OF PENTERNARY MIXTURES

Boiling point range Temperature Pressure System with 5 compounds ° C.bar abs HF-HCFO-1233xf-HFC-245cb-HCFO- 0 to 40 ~1.0 to ~10.01233zdE-HFO-1243zf HF-HCFO-1233xf-HFC-245cb-HFO- 0 to 40 ~1.0 to ~10.21234zeE-HFO-1243zf HF-HCFO-1233xf-HFC-245cb-HFO- 0 to 40 ~1.1 to ~10.11234zeZ-HFO-1243zf HF-HCFO-1233xf-HFC-245cb-HFO- 0 to 40 ~1.2 to ~11.41234yf-HFO-1243zf HF-HCFO-1233xf-HFO-1234yf-HFO- 0 to 40 ~1.2 to ~11.41234zeE-HFO-1243zf HF-HCFO-1233xf-HFO-1234yf-HFO- 0 to 40 ~1.2 to ~11.21234zeZ-HFO-1243zf HF-HCFO-1233xf-HFO-1234yf-HCFO- 0 to 40 ~1.0 to ~11.21233zdE-HFO-1243zf HF-HCFO-1233xf-HCFO-1233zdE-HFO- 0 to 40 ~1.0 to~10.1 1234zeE-HFO-1243zf HF-HCFO-1233xf-HCFO-1233zdE-HFO- 0 to 40 ~1.0to ~9.9  1234zeZ-HFO-1243zf HF-HCFO-1233xf-HFO-1234zeE-HFO- 0 to 40 ~1.0to ~10.1 1234zeZ-HFO-1243zf HF-HFO-1234yf-HFO-1234zeE-HFO- 0 to 40 ~1.3to ~11.4 1234zeZ-HFO-1243zf HF-HFO-1234yf-HFO-1234zeE-HCFO- 0 to 40 ~1.0to ~11.4 1233zdE-HFO-1243zf HF-HFO-1234yf-HFO-1234zeZ-HCFO- 0 to 40 ~1.1to ~11.2 1233zdE-HFO-1243zf HF-HFO-1234yf-HFC-245cb-HFO- 0 to 40 ~2.5 to~11.6 1234zeE-HFO-1243zf HF-HFO-1234yf-HFC-245cb-HFO- 0 to 40 ~1.3 to~10.3 1234zeZ-HFO-1243zf HF-HFO-1234yf-HFC-245cb-HCFO- 0 to 40 ~1.1 to~11.4 1233zdE-HFO-1243zf HF-HFC-245cb-HCFO-1233zdE-HFO- 0 to 40 ~1.1 to~10.2 1234zeE-HFO-1243zf HF-HFC-245cb-HCFO-1233zdE-HFO- 0 to 40 ~1.0 to~10.1 1234zeZ-HFO-1243zf HF-HFC-245cb-HFO-1234zeE-HFO- 0 to 40 ~1.2 to~10.2 1234zeZ-HFO-1243zf HF-HCFO-1233zdE-HFO-1234zeE-HFO- 0 to 40 ~1.0to ~10.1 1234zeZ-HFO-1243zf

EXAMPLE 9: DECANTATION RANGE OF PENTERNARY MIXTURES

Decantation ranges Mass percentage of HF Isotherm Isotherm IsothermSystem with 5 compounds 0° C. 25° C. 40° C.HF-HCFO-1233xf-HFC-245cb-HCFO- 5-75  5-70  5-65 1233zdE-HFO-1243zfHF-HCFO-1233xf-HFC-245cb-HFO-1234zeE- 10-75 10-65 * HFO-1243zfHF-HCFO-1233xf-HFC-245cb-HFO-1234zeZ- 5-75  5-70 10-60 HFO-1243zfHF-HCFO-1233xf-HFC-245cb-HFO-1234yf- 5-75 10-70 * HFO-1243zfHF-HCFO-1233xf-HFO-1234yf-HFO- 5-70 10-60 * 1234zeE-HFO-1243zfHF-HCFO-1233xf-HFO-1234yf-HFO- 5-75 10-65 20-40 1234zeZ-HFO-1243zfHF-HCFO-1233xf-HFO-1234yf-HCFO- 5-75  5-65 15-45 1233zdE-HFO-1243zfHF-HCFO-1233xf-HCFO-1233zdE-HFO- 5-75  5-65 15-45 1234zeE-HFO-1243zfHF-HCFO-1233xf-HCFO-1233zdE-HFO- 5-75  5-70 10-60 1234zeZ-HFO-1243zfHF-HCFO-1233xf-HFO-1234zeE-HFO- 5-75 10-65 15-40 1234zeZ-HFO-1243zfHF-HFO-1234yf-HFO-1234zeE-HFO- 5-70 10-60 * 1234zeZ-HFO-1243zfHF-HFO-1234yf-HFO-1234zeE-HCFO- 5-70 10-60 * 1233zdE-HFO-1243zfHF-HFO-1234yf-HFO-1234zeZ-HCFO- 5-75 10-65 15-45 1233zdE-HFO-1243zfHF-HFO-1234yf-HFC-245cb-HFO-1234zeE- 5-75 15-65 * HFO-1243zfHF-HFO-1234yf-HFC-245cb-HFO-1234zeZ- 5-75 10-70 * HFO-1243zfHF-HFO-1234yf-HFC-245cb-HCFO- 5-75 10-70 * 1233zdE-HFO-1243zfHF-HFC-245cb-HCFO-1233zdE-HFO- 5-75 10-65 * 1234zeE-HFO-1243zfHF-HFC-245cb-HCFO-1233zdE-HFO- 5-75  5-70 10-60 1234zeZ-HFO-1243zfHF-HFC-245cb-HFO-1234zeE-HFO-1234zeZ- 5-75 10-65 * HFO-1243zfHF-HCFO-1233zdE-HFO-1234zeE-HFO- 5-75  5-65 15-50 1234zeZ-HFO-1243zf

EXAMPLE 10: SYSTEM WITH SIX COMPOUNDS, ISOTHERM AT 25° C.

HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HFO-1234zeE-HFO-1243zf

Organics Organics Organics Organics Organics Organics 0.2 F1233xf + 0.96F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.01 F1233xf +0.2 F1234yf + 0.01 F1234yf + 0.96 F1234yf + 0.01 F1234yf + 0.01F1234yf + 0.01 F1234yf + 0.2 F245cb 0.01 F245cb + 0.01 F245cb + 0.96F245cb + 0.01 F245cb + 0.01 F245cb + 0.2 F1234zeE + 0.01 F1234zeE + 0.01F1234zeE + 0.01 F1234zeE + 0.96 F1234zeE + 0.01 F1234zeE + 0.2 F1243zf0.01 F1243zf 0.01 F1243zf 0.01 F1243zf 0.01 F1243zf 0.96 F1243zf TOTALTOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES- MASS- PRES- MASS- PRES- MASS-PRES- MASS- PRES- MASS- PRES- FRAC SURE FRAC SURE FRAC SURE FRAC SUREFRAC SURE FRAC SURE HF bar HF bar HF bar HF bar HF bar HF bar 0 4.9 01.7 0 6.7 0 4.7 0 4.9 0 5.8 0.05 5.9 0.05 2.8 0.05 7.7 0.05 5.8 0.05 5.80.05 6.7 0.1 5.9 0.1 2.8 0.1 7.7 0.1 5.8 0.1 5.9 0.1 6.8 0.15 5.9 0.152.8 0.15 7.7 0.15 5.8 0.15 5.8 0.15 6.8 0.2 5.9 0.2 2.8 0.2 7.7 0.2 5.80.2 5.8 0.2 6.8 0.25 5.9 0.25 2.8 0.25 7.7 0.25 5.8 0.25 5.8 0.25 6.80.3 5.9 0.3 2.8 0.3 7.7 0.3 5.8 0.3 5.8 0.3 6.8 0.35 5.9 0.35 2.8 0.357.7 0.35 5.8 0.35 5.6 0.35 6.8 0.4 5.9 0.4 2.8 0.4 7.7 0.4 5.8 0.4 5.80.4 6.8 0.45 5.9 0.45 2.8 0.45 7.7 0.45 5.8 0.45 5.8 0.45 6.7 0.5 5.90.5 2.8 0.5 7.7 0.5 5.8 0.5 5.8 0.5 6.7 0.55 5.9 0.55 2.8 0.55 7.7 0.555.8 0.55 5.7 0.55 6.7 0.6 5.9 0.6 2.8 0.6 7.7 0.6 5.8 0.6 5.7 0.6 6.70.65 5.9 0.65 2.8 0.65 7.7 0.65 5.8 0.65 5.6 0.65 6.6 0.7 5.9 0.7 2.80.7 7.6 0.7 5.8 0.7 5.4 0.7 6.5 0.75 5.7 0.75 2.8 0.75 7.5 0.75 5.8 0.755.2 0.75 6.4 0.8 5.5 0.7 2.7 0.8 7.2 0.8 5.8 0.8 4.8 0.8 6.1 0.85 5.00.85 2.5 0.85 6.6 0.85 5.8 0.85 4.3 0.85 5.6 0.9 4.2 0.9 2.2 0.9 5.5 0.95.0 0.9 3.6 0.9 4.8 0.95 3.0 0.95 1.8 0.95 3.8 0.95 3.5 0.95 2.6 0.953.4 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HFO-1234zeZ-HFO-1243zf

Organics Organics Organics Organics Organics Organics 0.2 F1233xf + 0.96F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.01 F1233xf +0.2 F1234yf + 0.01 F1234yf + 0.96 F1234yf + 0.01 F1234yf + 0.01F1234yf + 0.01 F1234yf + 0.2 F245cb 0.01 F245cb + 0.01 F245cb + 0.96F245cb + 0.01 F245cb + 0.01 F245cb + 0.2 F1234zeZ + 0.01 F1234zeZ + 0.01F1234zeZ + 0.01 F1234zeZ + 0.96 F1234zeZ + 0.01 F1234zeZ + 0.2 F1243zf0.01 F1243zf 0.01 F1243zf 0.01 F1243zf 0.01 F1243zf 0.96 F1243zf TOTALTOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES- MASS- PRES- MASS- PRES- MASS-PRES- MASS- PRES- MASS- PRES- FRAC SURE FRAC SURE FRAC SURE FRAC SUREFRAC SURE FRAC SURE HF bar HF bar HF bar HF bar HF bar HF bar 0 4.2 01.7 0 6.7 0 4.6 0 1.9 0 5.8 0.05 5.3 0.05 2.8 0.05 7.6 0.05 5.8 0.05 3.00.05 6.7 0.1 5.3 0.1 2.8 0.1 7.7 0.1 5.8 0.1 3.0 0.1 6.8 0.15 5.3 0.152.8 0.15 7.6 0.15 5.8 0.15 3.0 0.15 6.7 0.2 5.3 0.2 2.8 0.2 7.6 0.2 5.80.2 3.0 0.2 6.7 0.25 5.3 0.25 2.8 0.25 7.6 0.25 5.8 0.25 3.0 0.25 6.70.3 5.3 0.3 2.8 0.3 7.6 0.3 5.8 0.3 3.0 0.3 6.7 0.35 5.3 0.35 2.8 0.357.6 0.35 5.8 0.35 3.0 0.35 6.7 0.4 5.3 0.4 2.8 0.4 7.6 0.4 5.8 0.4 3.00.4 6.7 0.45 5.3 0.45 2.8 0.45 7.6 0.45 5.8 0.45 3.0 0.45 6.7 0.5 5.30.5 2.8 0.5 7.6 0.5 5.8 0.5 3.0 0.5 6.7 0.55 5.3 0.55 2.8 0.55 7.6 0.555.8 0.55 3.0 0.55 6.7 0.6 5.3 0.6 2.8 0.6 7.6 0.6 5.8 0.6 3.0 0.6 6.70.65 5.3 0.65 2.8 0.65 7.6 0.65 5.8 0.65 3.0 0.65 6.6 0.7 5.3 0.7 2.80.7 7.6 0.7 5.8 0.7 3.0 0.7 6.5 0.75 5.3 0.75 2.8 0.75 7.5 0.75 5.8 0.753.0 0.75 6.4 0.8 5.1 0.8 2.7 0.8 7.2 0.8 5.8 0.8 2.9 0.8 6.1 0.85 4.70.85 2.5 0.85 6.6 0.85 5.8 0.85 2.7 0.85 5.6 0.9 4.0 0.9 2.2 0.9 5.5 0.95.0 0.9 2.4 0.9 4.7 0.95 2.9 0.95 1.8 0.95 3.8 0.95 3.5 0.95 1.9 0.953.4 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HCFO-1233zdE-HFO-1243zf

Organics Organics Organics Organics Organics Organics 0.2 F1233xf + 0.96F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.01 F1233xf +0.2 F1234yf + 0.01 F1234yf + 0.96 F1234yf + 0.01 F1234yf + 0.01F1234yf + 0.01 F1234yf + 0.2 F245cb 0.01 F245cb + 0.01 F245cb + 0.96F245cb + 0.01 F245cb + 0.01 F245cb + 0.2 F1233zdE + 0.01 F1233zdE + 0.01F1233zdE + 0.01 F1233zdE + 0.96 F1233zdE + 0.01 F1233zdE + 0.2 F1243zf0.01 F1243zf 0.01 F1243zf 0.01 F1243zf 0.01 F1243zf 0.96 F1243zf TOTALTOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES- MASS- PRES- MASS- PRES- MASS-PRES- MASS- PRES- MASS- PRES- FRAC SURE FRAC SURE FRAC SURE FRAC SUREFRAC SURE FRAC SURE HF bar HF bar HF bar HF bar HF bar HF bar 0 4.2 01.7 0 6.7 0 4.6 0 1.5 0 5.8 0.05 5.3 0.05 2.8 0.05 7.6 0.05 5.8 0.05 2.60.05 6.7 0.1 5.3 0.1 2.8 0.1 7.7 0.1 5.8 0.1 2.6 0.1 6.8 0.15 5.3 0.152.8 0.15 7.6 0.15 5.8 0.15 2.6 0.15 6.7 0.2 5.3 0.2 2.8 0.2 7.6 0.2 5.80.2 2.6 0.2 6.7 0.25 5.3 0.25 2.8 0.25 7.6 0.25 5.8 0.25 2.6 0.25 6.70.3 5.3 0.3 2.8 0.3 7.6 0.3 5.8 0.3 2.6 0.3 6.7 0.35 5.3 0.35 2.8 0.357.6 0.35 5.8 0.35 2.6 0.35 6.7 0.4 5.3 0.4 2.8 0.4 7.6 0.4 5.8 0.4 2.60.4 6.7 0.45 5.3 0.45 2.8 0.45 7.6 0.45 5.8 0.45 2.6 0.45 6.7 0.5 5.30.5 2.8 0.5 7.6 0.5 5.8 0.5 2.6 0.5 6.7 0.55 5.3 0.55 2.8 0.55 7.6 0.555.8 0.55 2.6 0.55 6.7 0.6 5.3 0.6 2.8 0.6 7.6 0.6 5.8 0.6 2.6 0.6 5.70.65 5.3 0.65 2.8 0.65 7.6 0.65 5.8 0.65 2.6 0.65 6.6 0.7 5.3 0.7 2.80.7 7.6 0.7 5.8 0.7 2.6 0.7 6.5 0.75 5.2 0.75 2.8 0.75 7.5 0.75 5.8 0.752.6 0.75 6.4 0.8 5.0 0.8 2.7 0.8 7.2 0.8 5.8 0.8 2.5 0.8 6.1 0.85 4.60.85 2.5 0.85 6.6 0.85 5.8 0.85 2.3 0.85 5.6 0.9 3.9 0.9 2.2 0.9 5.5 0.95.0 0.9 2.0 0.9 4.7 0.95 2.8 0.95 1.8 0.95 3.8 0.95 3.5 0.95 1.7 0.953.4 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HCFO-1233xf-HFO-1234yf-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf

Organics Organics Organics Organics Organics Organics 0.2 F1233xf + 0.96F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.01 F1233xf +0.2 F1234yf + 0.01 F1234yf + 0.95 F1234yf + 0.01 F1234yf + 0.01F1234yf + 0.01 F1234yf + 0.2 F1243zf 0.01 F1243zf + 0.01 F1243zf + 0.96F1243zf + 0.01 F1243zf + 0.01 F1243zf + 0.2 F1234zeE + 0.01 F1234zeE +0.01 F1234zeE + 0.01 F1234zeE + 0.96 F1234zeE + 0.01 F1234zeE + 0.2F1234zeZ 0.01 F1234zeZ 0.01 F1234zeZ 0.01 F1234zeZ 0.01 F1234zeZ 0.96F1234zeZ TOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES- MASS- PRES-MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- FRAC SURE FRAC SURE FRACSURE FRAC SURE FRAC SURE FRAC SURE HF bar HF bar HF bar HF bar HF bar HFbar 0 4.3 0 1.7 0 6.7 0 5.8 0 4.8 0 1.9 0.05 5.3 0.05 2.8 0.05 7.6 0.056.7 0.05 5.8 0.05 3.0 0.1 5.3 0.1 2.8 0.1 7.6 0.1 6.7 0.1 5.8 0.1 3.00.15 5.3 0.15 2.8 0.15 7.6 0.15 6.7 0.15 5.8 0.15 3.0 0.2 5.3 0.2 2.80.2 7.6 0.2 6.7 0.2 5.8 0.2 3.0 0.25 5.3 0.25 2.8 0.25 7.6 0.25 6.7 0.255.8 0.25 3.0 0.3 5.3 0.3 2.8 0.3 7.6 0.3 6.7 0.3 5.8 0.3 3.0 0.35 5.30.35 2.8 0.35 7.6 0.35 6.7 0.35 5.8 0.35 3.0 0.4 5.3 0.4 2.8 0.4 7.6 0.46.7 0.4 5.8 0.4 3.0 0.45 5.3 0.45 2.8 0.45 7.6 0.45 6.7 0.45 5.8 0.453.0 0.5 5.3 0.5 2.8 0.5 7.6 0.5 6.7 0.5 5.8 0.5 3.0 0.55 5.3 0.55 2.80.55 7.6 0.55 6.7 0.55 5.7 0.55 3.0 0.6 5.3 0.6 2.8 0.6 7.6 0.6 6.7 0.65.6 0.6 3.0 0.65 5.3 0.65 2.8 0.65 7.6 0.65 6.6 0.65 5.5 0.65 3.0 0.75.2 0.7 2.8 0.7 7.6 0.7 6.5 0.7 5.4 0.7 3.0 0.75 5.0 0.75 2.8 0.75 7.50.75 6.3 0.75 5.1 0.75 3.0 0.8 4.8 0.8 2.7 0.8 7.1 0.8 6.1 0.8 4.8 0.82.9 0.85 4.3 0.85 2.5 0.85 6.5 0.85 5.6 0.85 4.3 0.85 2.7 0.9 3.7 0.92.2 0.9 5.5 0.9 4.7 0.9 3.6 0.9 2.4 0.95 2.7 0.95 1.8 0.95 3.8 0.95 3.40.95 2.6 0.95 1.9 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HCFO-1233xf-HFO-1234yf-HFO-1234zeE-HCFO-1233zdE-HFO-1243zf

Organics Organics Organics Organics Organics Organics 0.2 F1233xf + 0.96F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.01 F1233xf +0.2 F1234yf + 0.01 F1234yf + 0.96 F1234yf + 0.01 F1234yf + 0.01F1234yf + 0.01 F1234yf + 0.2 F1243zf + 0.01 F1243zf + 0.01 F1243zf +0.96 F1243zf + 0.01 F1243zf + 0.01 F1243zf + 0.2 F1234zeE + 0.01F1234zeE + 0.01 F1234zeE + 0.01 F1234zeE + 0.96 F1234zeE + 0.01F1234zeE + 0.2 F1233zdE 0.01 F1233zdE 0.01 F1233zdE 0.01 F1233zdE 0.01F1233zdE 0.96 F1233zdE TOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES-MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- FRAC SUREFRAC SURE FRAC SURE FRAC SURE FRAC SURE FRAC SURE HF bar HF bar HF barHF bar HF bar HF bar 0 4.3 0 1.7 0 6.7 0 5.8 0 4.8 0 1.5 0.05 5.3 0.052.8 0.05 7.6 0.05 6.7 0.05 5.8 0.05 2.6 0.1 5.3 0.1 2.8 0.1 7.6 0.1 6.70.1 5.8 0.1 2.6 0.15 5.3 0.15 2.8 0.15 7.6 0.15 6.7 0.15 5.8 0.15 2.60.2 5.3 0.2 2.8 0.2 7.6 0.2 6.7 0.2 5.8 0.2 2.6 0.25 5.3 0.25 2.8 0.257.6 0.25 6.7 0.25 5.8 0.25 2.6 0.3 5.3 0.3 2.8 0.3 7.6 0.3 6.7 0.3 5.80.3 2.6 0.35 5.3 0.35 2.8 0.35 7.6 0.35 6.7 0.35 5.8 0.35 2.6 0.4 5.30.4 2.8 0.4 7.6 0.4 6.7 0.4 5.8 0.4 2.6 0.45 5.3 0.45 2.8 0.45 7.6 0.456.7 0.45 5.8 0.45 2.6 0.5 5.3 0.5 2.8 0.5 7.6 0.5 6.7 0.5 5.8 0.5 2.60.55 5.3 0.55 2.8 0.55 7.6 0.55 6.7 0.55 5.7 0.55 2.6 0.6 5.3 0.6 2.80.6 7.6 0.6 6.7 0.6 5.6 0.6 2.6 0.65 5.2 0.65 2.8 0.65 7.6 0.65 6.6 0.655.5 0.65 2.6 0.7 5.1 0.7 2.8 0.7 7.6 0.7 6.5 0.7 5.4 0.7 2.6 0.75 5.00.75 2.8 0.75 7.5 0.75 6.3 0.75 5.1 0.75 2.6 0.8 4.7 0.8 2.6 0.8 7.1 0.86.1 0.8 4.8 0.8 2.4 0.85 4.3 0.85 2.5 0.85 6.5 0.85 5.6 0.85 4.3 0.852.3 0.9 3.6 0.9 2.2 0.9 5.5 0.9 4.7 0.9 3.6 0.9 2.0 0.95 2.6 0.95 1.80.95 3.8 0.95 3.4 0.95 2.6 0.95 1.7 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HCFO-1233xf-HFO-1234yf-HFO-1234zeZ-HCFO-1233zdE-HFO-1243zf

Organics Organics Organics Organics Organics Organics 0.2 F1233xf + 0.96F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.01 F1233xf +0.2 F1234yf + 0.01 F1234yf + 0.96 F1234yf + 0.01 F1234yf + 0.01F1234yf + 0.01 F1234yf + 0.2 F1243zf + 0.01 F1243zf + 0.01 F1243zf +0.96 F1243zf + 0.01 F1243zf + 0.01 F1243zf + 0.2 F1234zeZ + 0.01F1234zeZ + 0.01 F1234zeZ + 0.01 F1234zeZ + 0.96 F1234zeZ + 0.01F1234zeZ + 0.2 F1233zdE 0.01 F1233zdE 0.01 F1233zdE 0.01 F1233zdE 0.01F1233zdE 0.96 F1233zdE TOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES-MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- FRAC SUREFRAC SURE FRAC SURE FRAC SURE FRAC SURE FRAC SURE HF bar HF bar HF barHF bar HF bar HF bar 0 3.6 0 1.7 0 6.6 0 5.7 0 1.9 0 1.4 0.05 4.7 0.052.8 0.05 7.6 0.05 6.7 0.05 3.0 0.05 2.6 0.1 4.7 0.1 2.8 0.1 7.6 0.1 6.70.1 3.0 0.1 2.6 0.15 4.7 0.15 2.8 0.15 7.6 0.15 6.7 0.15 3.0 0.15 2.60.2 4.7 0.2 2.8 0.2 7.6 0.2 6.7 0.2 3.0 0.2 2.6 0.25 4.7 0.25 2.8 0.257.6 0.25 6.7 0.25 3.0 0.25 2.6 0.3 4.7 0.3 2.8 0.3 7.6 0.3 6.7 0.3 3.00.3 2.6 0.35 4.7 0.35 2.8 0.35 7.6 0.35 6.7 0.35 3.0 0.35 2.5 0.4 4.70.4 2.8 0.4 7.6 0.4 6.7 0.4 3.0 0.4 2.5 0.45 4.7 0.45 2.8 0.45 7.6 0.456.7 0.45 3.0 0.45 2.5 0.5 4.7 0.5 2.8 0.5 7.6 0.5 6.7 0.5 3.0 0.5 2.50.55 4.7 0.55 2.8 0.55 7.6 0.55 6.7 0.55 3.0 0.55 2.5 0.6 4.7 0.6 2.80.6 7.5 0.5 6.6 0.6 3.0 0.6 2.5 0.65 4.7 0.65 2.8 0.65 7.6 0.65 6.6 0.653.0 0.65 2.5 0.7 4.7 0.7 2.8 0.7 7.6 0.7 6.5 0.7 3.0 0.7 2.5 0.75 4.50.75 2.8 0.75 7.4 0.75 6.3 0.75 3.0 0.75 2.5 0.8 4.3 0.8 2.6 0.8 7.1 0.86.0 0.8 2.9 0.8 2.4 0.85 3.9 0.85 2.4 0.85 6.5 0.85 5.5 0.85 2.7 0.852.3 0.9 3.4 0.9 2.2 0.9 5.5 0.9 4.7 0.9 2.3 0.9 2.0 0.95 2.5 0.95 1.70.95 3.8 0.95 3.3 0.95 1.9 0.95 1.7 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HCFO-1233xf-HFC-245cb-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf

Organics Organics Organics Organics Organics Organics 0.2 F1233xf + 0.96F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.01 F1233xf +0.2 F245cb + 0.01 F245cb + 0.96 F245cd + 0.01 F245cb + 0.01 F245cb +0.01 F245cb + 0.2 F1243zf 0.01 F1243zf + 0.01 F1243zf + 0.96 F1243zf +0.01 F1243zf + 0.01 F1243zf + 0.2 F1234zeE + 0.01 F1234zeE + 0.01F1234zeE + 0.01 F1234zeE + 0.96 F1234zeE + 0.01 F1234zeE + 0.2 F1234zeZ0.01 F1234zeZ 0.01 F1234zeZ 0.01 F1234zeZ 0.01 F1234zeZ 0.96 F1234zeZTOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES- MASS- PRES- MASS- PRES-MASS- PRES- MASS- PRES- MASS- PRES- FRAC SURE FRAC SURE FRAC SURE FRACSURE FRAC SURE FRAC SURE HF bar HF bar HF bar HF bar HF bar HF bar 0 3.80 1.7 0 4.6 0 5.8 0 4.8 0 1.9 0.05 4.9 0.05 2.8 0.05 5.8 0.05 6.7 0.055.8 0.05 3.0 0.1 4.9 0.1 2.8 0.1 5.8 0.1 6.7 0.1 5.8 0.1 3.0 0.15 4.90.15 2.8 0.15 5.8 0.15 6.7 0.15 5.8 0.15 3.0 0.2 4.9 0.2 2.8 0.2 5.8 0.26.7 0.2 5.8 0.2 3.0 0.25 4.9 0.25 2.8 0.25 5.8 0.25 6.7 0.25 5.8 0.253.0 0.3 4.9 0.3 2.8 0.3 5.8 0.3 6.7 0.3 5.8 0.3 3.0 0.35 4.9 0.35 2.80.35 5.8 0.35 6.7 0.35 5.8 0.35 3.0 0.4 4.9 0.4 2.8 0.4 5.8 0.4 6.7 0.45.8 0.4 3.0 0.45 4.9 0.45 2.8 0.45 5.8 0.45 6.7 0.45 5.8 0.45 3.0 0.54.9 0.5 2.8 0.5 5.8 0.5 6.7 0.5 5.7 0.5 3.0 0.55 4.9 0.55 2.8 0.55 5.80.55 6.7 0.55 5.7 0.55 3.0 0.6 4.9 0.6 2.8 0.6 5.8 0.6 6.6 0.6 5.6 0.63.0 0.65 4.9 0.65 2.8 0.65 5.8 0.65 6.6 0.65 5.5 0.65 3.0 0.7 4.9 0.72.8 0.7 5.8 0.7 6.5 0.7 5.4 0.7 3.0 0.75 4.8 0.75 2.8 0.75 5.8 0.75 6.30.75 5.1 0.75 3.0 0.8 4.6 0.8 2.6 0.8 5.8 0.8 6.0 0.8 4.8 0.0 2.9 0.854.2 0.85 2.4 0.85 5.8 0.85 5.6 0.85 4.3 0.85 2.7 0.9 3.6 0.9 2.2 0.9 5.00.9 4.7 0.9 3.6 0.9 2.4 0.95 2.6 0.95 1.8 0.95 3.5 0.95 3.4 0.95 2.60.95 1.9 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HCFO-1233xf-HFC-245cb-HFO-1234zeE-HCFO-1233zdE-HFO-1243zf

Organics Organics Organics Organics Organics Organics 0.2 F1233xf + 0.96F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.01 F1233xf +0.2 F245cb + 0.01 F245cb + 0.96 F245cb + 0.01 F245cb + 0.01 F245cb +0.01 F245cb + 0.2 F1243zf + 0.01 F1243zf + 0.01 F1243zf + 0.96 F1243zf +0.01 F1243zf + 0.01 F1243zf + 0.2 F1234zeE + 0.01 F1234zeE + 0.01F1234zeE + 0.01 F1234zeE + 0.96 F1234zeE + 0.01 F1234zeE + 0.2 F1233zdE0.01 F1233zdE 0.01 F1233zdE 0.01 F1233zdE 0.01 F1233zdE 0.96 F1233zdETOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES- MASS- PRES- MASS- PRES-MASS- PRES- MASS- PRES- MASS- PRES- FRAC SURE FRAC SURE FRAC SURE FRACSURE FRAC SURE FRAC SURE HF bar HF bar HF bar HF bar HF bar HF bar 0 3.80 1.7 0 4.6 0 5.8 0 4.8 0 1.5 0.05 4.9 0.05 2.8 0.05 5.8 0.05 6.7 0.055.8 0.05 2.6 0.1 4.9 0.1 2.8 0.1 5.8 0.1 6.7 0.1 5.8 0.1 2.6 0.15 4.90.15 2.8 0.15 5.8 0.15 6.7 0.15 5.8 0.15 2.6 0.2 4.9 0.2 2.8 0.2 5.8 0.26.7 0.2 5.8 0.2 2.6 0.25 4.9 0.25 2.8 0.25 5.8 0.25 6.7 0.25 5.8 0.252.6 0.3 4.9 0.3 2.8 0.3 5.8 0.3 6.7 0.3 5.8 0.3 2.6 0.35 4.9 0.35 2.80.35 5.8 0.35 6.7 0.35 5.8 0.35 2.6 0.4 4.9 0.4 2.8 0.4 5.8 0.4 6.7 0.45.8 0.4 2.6 0.45 4.9 0.45 2.8 0.45 5.8 0.45 6.7 0.45 5.8 0.45 2.6 0.54.9 0.5 2.8 0.5 5.8 0.5 6.7 0.5 5.7 0.5 2.6 0.55 4.9 0.55 2.8 0.55 5.80.55 6.7 0.55 5.7 0.55 2.6 0.6 4.9 0.6 2.8 0.6 5.8 0.6 6.6 0.6 5.6 0.62.6 0.65 4.9 0.65 2.8 0.65 5.8 0.65 6.6 0.65 5.5 0.65 2.5 0.7 4.9 0.72.8 0.7 5.8 0.7 6.5 0.7 5.4 0.7 2.5 0.75 4.7 0.75 2.8 0.75 5.8 0.75 6.30.75 5.1 0.75 2.5 0.8 4.5 0.8 2.6 0.8 5.8 0.8 6.0 0.8 4.8 0.8 2.4 0.854.1 0.85 2.4 0.85 5.8 0.85 5.6 0.85 4.3 0.85 2.3 0.9 3.5 0.9 2.2 0.9 5.00.9 4.7 0.9 3.6 0.9 2.0 0.95 2.6 0.95 1.7 0.95 3.5 0.95 3.3 0.95 2.60.95 1.7 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HCFO-1233xf-HFC-245cb-HFO-1234zeZ-HCFO-1233zdE-HFO-1243zf

Organics Organics Organics Organics Organics Organics 0.2 F1233xf + 0.96F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.01 F1233xf +0.2 F245cb + 0.01 F245cb + 0.96 F245cb + 0.01 F245cb + 0.01 F245cb +0.01 F245cb + 0.2 F1243zf + 0.01 F1243zf + 0.01 F1243zf + 0.96 F1243zf +0.01 F1243zf + 0.01 F1243zf + 0.2 F1234zeZ + 0.01 F1234zeZ + 0.01F1234zeZ + 0.01 F1234zeZ + 0.96 F1234zeZ + 0.01 F1234zeZ + 0.2 F1233zdE0.01 F1233zdE 0.01 F1233zdE 0.01 F1233zdE 0.01 F1233zdE 0.96 F1233zdETOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES- MASS- PRES- MASS- PRES-MASS- PRES- MASS- PRES- MASS- PRES- FRAC SURE FRAC SURE FRAC SURE FRACSURE FRAC SURE FRAC SURE HF bar HF bar HF bar HF bar HF bar HF bar 0 3.20 1.6 0 4.6 0 5.7 0 1.9 0 1.4 0.05 4.3 0.05 2.7 0.05 5.7 0.05 6.7 0.053.0 0.05 2.5 0.1 4.3 0.1 2.7 0.1 5.7 0.1 6.7 0.1 3.0 0.1 2.5 0.15 4.30.15 2.7 0.15 5.7 0.15 6.7 0.15 3.0 0.15 2.5 0.2 4.3 0.2 2.7 0.2 5.7 0.26.7 0.2 3.0 0.2 2.5 0.25 4.3 0.25 2.7 0.25 5.7 0.25 6.7 0.25 3.0 0.252.5 0.3 4.3 0.3 2.7 0.3 5.7 0.3 6.7 0.3 3.0 0.3 2.5 0.35 4.3 0.35 2.70.35 5.7 0.35 6.7 0.35 3.0 0.35 2.5 0.4 4.3 0.4 2.7 0.4 5.8 0.4 6.7 0.43.0 0.4 2.5 0.45 4.3 0.45 2.7 0.45 5.8 0.45 6.7 0.45 3.0 0.45 2.5 0.54.3 0.5 2.7 0.5 5.8 0.5 6.7 0.5 3.0 0.5 2.5 0.55 4.3 0.55 2.7 0.55 5.80.55 6.7 0.55 3.0 0.55 2.5 0.6 4.3 0.6 2.7 0.6 5.8 0.6 6.6 0.6 3.0 0.62.5 0.65 4.3 0.65 2.7 0.65 5.8 0.65 6.6 0.65 3.0 0.65 2.5 0.7 4.3 0.72.7 0.7 5.8 0.7 6.5 0.7 3.0 0.7 2.5 0.70 4.3 0.75 2.7 0.75 5.8 0.75 6.30.75 3.0 0.75 2.5 0.8 4.1 0.8 2.6 0.8 5.8 0.8 6.0 0.8 2.9 0.8 2.4 0.853.8 0.85 2.4 0.85 5.8 0.85 5.5 0.85 2.7 0.85 2.3 0.9 3.3 0.9 2.1 0.9 5.00.9 4.7 0.9 2.3 0.9 2.0 0.95 2.4 0.95 1.7 0.95 3.5 0.95 3.3 0.95 1.90.95 1.7 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HCFO-1233xf-HFO-1234zeE-HFO-1234zeZ-HCFO-1233zdE-HFO-1243zf

Organics Organics Organics Organics Organics Organics 0.2 F1233xf + 0.96F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.01 F1233xf +0.2 F1243zf + 0.01 F1243zf + 0.96 F1243zf + 0.01 F1243zf + 0.01F1243zf + 0.01 F1243zf + 0.2 F1233zdE 0.01 F1233zdE + 0.01 F1233zdE +0.96 F1233zdE + 0.01 F1233zdE + 0.01 F1233zdE + 0.2 F1234zeE + 0.01F1234zeE + 0.01 F1234zeE + 0.01 F1234zeE + 0.96 F1234zeE + 0.01F1234zeE + 0.2 F1234zeZ 0.01 F1234zeZ 0.01 F1234zeZ 0.01 F1234zeZ 0.01F1234zeZ 0.96 F1234zeZ TOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES-MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- FRAC SUREFRAC SURE FRAC SURE FRAC SURE FRAC SURE FRAC SURE HF bar HF bar HF barHF bar HF bar HF bar 0 3.2 0 1.6 0 5.7 0 1.4 0 4.8 0 1.9 0.05 4.3 0.052.7 0.05 6.7 0.05 2.5 0.05 5.7 0.05 3.0 0.1 4.3 0.1 2.7 0.1 6.7 0.1 2.50.1 5.8 0.1 3.0 0.15 4.3 0.15 2.7 0.15 6.7 0.15 2.5 0.15 5.8 0.15 3.00.2 4.3 0.2 2.7 0.2 6.7 0.2 2.5 0.2 5.8 0.2 3.0 0.25 4.3 0.25 2.7 0.256.7 0.25 2.5 0.25 5.8 0.25 3.0 0.3 4.3 0.2 2.7 0.3 6.7 0.3 2.5 0.3 5.80.3 3.0 0.35 4.3 0.35 2.7 0.35 6.7 0.35 2.5 0.35 5.8 0.35 3.0 0.4 4.30.4 2.7 0.4 6.7 0.4 2.5 0.4 5.8 0.4 3.0 0.45 4.3 0.45 2.7 0.45 6.7 0.452.5 0.45 5.7 0.45 3.0 0.5 4.3 0.5 2.7 0.5 6.7 0.5 2.5 0.5 5.7 0.5 3.00.55 4.2 0.55 2.7 0.55 6.6 0.55 2.5 0.55 5.7 0.55 3.0 0.6 4.2 0.6 2.70.6 6.6 0.6 2.5 0.6 5.6 0.6 3.0 0.65 4.2 0.65 2.7 0.65 6.6 0.65 2.5 0.655.5 0.65 3.0 0.7 4.2 0.7 2.7 0.7 6.5 0.7 2.5 0.7 5.3 0.70 3.0 0.75 4.00.75 2.7 0.75 6.3 0.75 2.5 0.75 5.1 0.75 3.0 0.8 3.8 0.8 2.6 0.8 6.0 0.82.4 0.8 4.7 0.8 2.3 0.85 3.5 0.85 2.4 0.85 5.5 0.85 2.2 0.85 4.3 0.852.6 0.9 3.0 0.9 2.1 0.9 4.7 0.9 2.0 0.9 3.6 0.9 2.3 0.95 2.2 0.95 1.70.95 3.3 0.95 1.7 0.95 2.6 0.95 1.9 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HFO-1234yf-HFC-245cb-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf

Organics Organics Organics Organics Organics Organics 0.2 F1234yf + 0.96F1234yf + 0.01 F1234yf + 0.01 F1234yf + 0.01 F1234yf + 0.01 F1234yf +0.2 F245cb + 0.01 F245cb + 0.96 F245cb + 0.01 F245cb + 0.01 F245cb +0.01 F245cb + 0.2 F1243zf + 0.01 F1243zf + 0.01 F1243zf + 0.96 F1243zf +0.01 F1243zf + 0.01 F1243zf + 0.2 F1234zeE + 0.01 F1234zeE + 0.01F1234zeE + 0.01 F1234zeE + 0.96 F1234zeE + 0.01 F1234zeE + 0.2 F1234zeZ0.01 F1234zeZ 0.01 F1234zeZ 0.01 F1234zeZ 0.01 F1234zeZ 0.96 F1234zeZTOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES- MASS- PRES- MASS- PRES-MASS- PRES- MASS- PRES- MASS- PRES- FRAC SURE FRAC SURE FRAC SURE FRACSURE FRAC SURE FRAC SURE HF bar HF bar HF bar HF bar HF bar HF bar 0 4.80 6.7 0 4.7 0 5.8 0 4.9 0 2.0 0.05 5.9 0.05 7.7 0.05 5.8 0.05 6.7 0.055.8 0.05 3.1 0.1 5.9 0.1 7.7 0.1 5.8 0.1 6.8 0.1 5.9 0.1 3.1 0.15 5.90.15 7.7 0.15 5.8 0.15 6.8 0.15 5.8 0.15 3.1 0.2 5.9 0.2 7.7 0.2 5.8 0.26.8 0.2 5.8 0.2 3.1 0.25 5.9 0.25 7.6 0.25 5.8 0.25 6.8 0.25 5.8 0.253.1 0.3 5.9 0.3 7.6 0.3 5.8 0.5 6.8 0.3 5.8 0.3 3.1 0.35 5.9 0.35 7.60.35 5.8 0.35 6.8 0.35 5.8 0.35 3.1 0.4 5.9 0.4 7.6 0.4 5.8 0.4 6.7 0.45.8 0.4 3.1 0.45 5.9 0.45 7.6 0.45 5.8 0.45 6.7 0.45 5.8 0.45 3.1 0.55.9 0.5 7.7 0.5 5.8 0.5 6.7 0.5 5.8 0.5 3.1 0.55 5.9 0.55 7.7 0.55 5.80.55 6.7 0.55 5.7 0.55 3.1 0.6 5.9 0.6 7.7 0.6 5.8 0.6 6.7 0.6 5.7 0.63.1 0.65 5.9 0.65 7.7 0.65 5.8 0.65 6.6 0.65 5.6 0.65 3.1 0.7 5.9 0.77.6 0.7 5.8 0.7 6.5 0.7 5.4 0.7 3.1 0.75 5.7 0.75 7.5 0.75 5.8 0.75 6.40.75 5.2 0.75 3.1 0.8 5.5 0.3 7.2 0.8 5.8 0.8 6.1 0.8 4.3 0.8 2.9 0.855.0 0.85 6.6 0.85 5.8 0.85 5.8 0.85 4.3 0.85 2.7 0.9 4.3 0.9 5.5 0.9 5.00.9 4.8 0.9 3.6 0.9 2.4 0.95 3.0 0.95 3.0 0.95 3.5 0.95 3.4 0.95 2.60.95 1.9 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HFO-1234yf-HFC-245cb-HFO-1234zeE-HCFO-1233zdE-HFO-1243zf

Organics Organics Organics Organics Organics Organics 0.2 F1234yf + 0.96F1234yf + 0.01 F1234yf + 0.01 F1234yf + 0.01 F1234yf + 0.01 F1234yf +0.2 F245cb + 0.01 F245cb + 0.96 F245cb + 0.01 F245cb + 0.01 F245cb +0.01 F245cb + 0.2 F1243zf + 0.01 F1243zf + 0.01 F1243zf + 0.96 F1243zf +0.01 F1243zf + 0.01 F1243zf + 0.2 F1234zeE + 0.01 F1234zeE + 0.01F1234zeE + 0.01 F1234zeE + 0.96 F1234zeE + 0.01 F1234zeE + 0.2 F1233zdE0.01 F1233zdE 0.01 F1233zdE 0.01 F1233zdE 0.01 F1233zdE 0.96 F1233zdETOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES- MASS- PRES- MASS- PRES-MASS- PRES- MASS- PRES- MASS- PRES- FRAC SURE FRAC SURE FRAC SURE FRACSURE FRAC SURE FRAC SURE HF bar HF bar HF bar HF bar HF bar HF bar 0 4.80 6.7 0 4.7 0 5.8 0 4.9 0 1.5 0.05 5.9 0.05 7.7 0.05 5.8 0.05 6.7 0.055.8 0.05 2.6 0.1 5.9 0.1 7.7 0.1 5.8 0.1 6.8 0.1 5.8 0.1 2.8 0.15 5.90.15 7.7 0.15 5.8 0.15 6.8 0.15 5.8 0.15 2.6 0.2 5.9 0.2 7.7 0.2 5.8 0.26.8 0.2 5.8 0.2 2.6 0.25 5.9 0.25 7.6 0.25 5.8 0.25 6.8 0.25 5.8 0.252.6 0.3 5.9 0.3 7.6 0.3 5.8 0.3 6.8 0.3 5.8 0.3 2.6 0.35 5.9 0.35 7.60.35 5.8 0.35 6.8 0.35 5.8 0.35 2.8 0.4 5.9 0.4 7.7 0.4 5.8 0.4 6.7 0.45.8 0.4 2.6 0.45 5.9 0.45 7.7 0.45 5.8 0.45 6.7 0.45 5.8 0.45 2.6 0.55.9 0.5 7.7 0.5 5.8 0.5 6.7 0.5 5.8 0.5 2.6 0.55 5.9 0.55 7.7 0.55 5.80.55 6.7 0.55 5.7 0.55 2.6 0.6 5.9 0.6 7.7 0.6 5.8 0.6 6.7 0.6 5.7 0.62.6 0.65 5.9 0.65 7.7 0.65 5.8 0.65 6.6 0.65 5.6 0.65 2.6 0.7 5.9 0.77.6 0.7 5.8 0.7 6.5 0.7 5.4 0.7 2.6 0.75 5.7 0.75 7.5 0.75 5.8 0.75 6.40.75 5.2 0.75 2.6 0.8 5.4 0.8 7.2 0.8 5.8 0.8 6.1 0.8 4.8 0.8 2.5 0.555.0 0.85 6.6 0.85 5.8 0.85 5.8 0.85 4.3 0.85 2.3 0.9 4.2 0.9 5.5 0.9 5.00.9 4.8 0.9 3.6 0.9 2.1 0.95 3.0 0.95 3.8 0.95 3.5 0.95 3.4 0.95 2.60.95 1.7 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HFO-1234yf-HFC-245th-HFO-1234zeZ-HCFO-1233zdE-HFO-1243zf

Organics Organics Organics Organics Organics Organics 0.2 F1234yf + 0.96F1234yf + 0.01 F1234yf + 0.01 F1234yf + 0.01 F1234yf + 0.01 F1234yf +0.2 F245cb + 0.01 F245cb + 0.96 F245cb + 0.01 F245cb + 0.01 F245cb +0.01 F245cb + 0.2 F1243zf + 0.01 F1243zf + 0.01 F1243zf + 0.96 F1243zf +0.01 F1243zf + 0.01 F1243zf + 0.2 F1234zeZ + 0.01 F1234zeZ + 0.01F1234zeZ + 0.01 F1234zeZ + 0.96 F1234zeZ + 0.01 F1234zeZ + 0.2 F1233zdE0.01 F1233zdE 0.01 F1233zdE 0.01 F1233zdE 0.01 F1233zdE 0.96 F1233zdETOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES- MASS- PRES- MASS- PRES-MASS- PRES- MASS- PRES- MASS- PRES- FRAC SURE FRAC SURE FRAC SURE FRACSURE FRAC SURE FRAC SURE HF bar HF bar HF bar HF bar HF bar HF bar 0 4.20 6.7 0 4.6 0 5.8 0 1.9 0 1.5 0.05 5.3 0.05 7.6 0.05 5.8 0.05 6.7 0.053.0 0.05 2.6 0.1 5.3 0.1 7.6 0.1 5.8 0.1 6.7 0.1 3.0 0.1 2.6 0.15 5.30.15 7.6 0.15 5.8 0.15 6.7 0.15 3.0 0.15 2.6 0.2 5.3 0.2 7.6 0.2 5.8 0.26.7 0.2 3.0 0.2 2.6 0.25 5.3 0.25 7.6 0.25 5.8 0.25 6.7 0.25 3.0 0.252.6 0.3 5.3 0.3 7.6 0.3 5.8 0.3 6.7 0.3 3.0 0.3 2.6 0.35 5.3 0.35 7.60.35 5.8 0.35 6.7 0.35 3.0 0.35 2.6 0.4 5.3 0.4 7.6 0.4 5.8 0.4 6.7 0.43.0 0.4 2.6 0.45 5.3 0.45 7.6 0.45 5.8 0.45 6.7 0.45 3.0 0.45 2.6 0.55.3 0.5 7.6 0.5 5.8 0.5 6.7 0.5 3.0 0.5 2.6 0.55 5.3 0.55 7.6 0.55 5.80.55 6.7 0.55 3.0 0.55 2.6 0.6 5.3 0.6 7.6 0.6 5.8 0.6 6.7 0.6 3.0 0.62.6 0.65 5.3 0.65 7.6 0.65 5.8 0.65 6.6 0.65 3.0 0.65 2.6 0.7 5.3 0.77.6 0.7 5.8 0.7 6.5 0.7 3.0 0.7 2.6 0.75 5.2 0.75 7.5 0.75 5.8 0.75 6.40.75 3.0 0.75 2.6 0.8 5.0 0.8 7.2 0.8 5.8 0.8 6.1 0.8 2.9 0.8 2.5 0.854.6 0.85 6.6 0.85 5.8 0.85 5.6 0.85 2.7 0.85 2.3 0.9 3.9 0.9 5.5 0.9 5.00.9 4.7 0.9 2.4 0.9 2.0 0.95 2.9 0.95 3.8 0.95 3.5 0.95 3.4 0.95 1.90.95 1.7 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HFO-1234yf-HFO-1234zeE-HFO-1234zeZ-HCFO-1233zdE-HFO-1243zf

Organics Organics Organics Organics Organics Organics 0.2 F1234yf + 0.96F1234yf + 0.01 F1234yf + 0.01 F1234yf + 0.01 F1234yf + 0.01 F1234yf +0.2 F1243zf + 0.01 F1243zf + 0.96 F1243zf + 0.01 F1243zf + 0.01F1243zf + 0.01 F1243zf + 0.2 F1233zdE 0.01 F1233zdE + 0.01 F1233zdE +0.96 F1233zdE + 0.01 F1233zdE + 0.01 F1233zdE + 0.2 F1234zeE + 0.01F1234zeE + 0.01 F1234zeE + 0.01 F1234zeE + 0.96 F1234zeE + 0.01F1234zeE + 0.2 F1234zeZ 0.01 F1234zeZ 0.01 F1234zeZ 0.01 F1234zeZ 0.01F1234zeZ 0.96 F1234zeZ TOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES-MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- FRAC SUREFRAC SURE FRAC SURE FRAC SURE FRAC SURE FRAC SURE HF bar HF bar HF barHF bar HF bar HF bar 0 4.2 0 6.7 0 5.8 0 1.5 0 4.8 0 1.9 0.05 5.3 0.057.6 0.05 6.7 0.05 2.6 0.05 5.8 0.05 3.0 0.1 5.3 0.1 7.6 0.1 6.7 0.1 2.60.1 5.8 0.1 3.0 0.15 5.3 0.15 7.6 0.15 8.7 0.15 2.6 0.15 5.8 0.15 3.00.2 5.3 0.2 7.6 0.2 6.7 0.2 2.6 0.2 5.8 0.2 3.0 0.25 5.3 0.25 7.6 0.256.7 0.25 2.6 0.25 5.8 0.25 3.0 0.3 5.3 0.3 7.6 0.3 6.7 0.3 2.6 0.3 5.80.3 3.0 0.35 5.3 0.35 7.6 0.35 6.7 0.35 2.6 0.35 5.8 0.35 3.0 0.4 5.30.4 7.6 0.4 6.7 0.4 2.6 0.4 5.8 0.4 3.0 0.45 5.3 0.45 7.6 0.45 6.7 0.452.6 0.45 5.8 0.45 3.0 0.5 5.3 0.5 7.6 0.5 6.7 0.5 2.6 0.5 5.8 0.5 3.00.55 5.2 0.55 7.6 0.55 6.7 0.55 2.6 0.55 5.7 0.55 3.0 0.6 5.2 0.6 7.60.6 6.7 0.6 2.6 0.6 5.6 0.6 3.0 0.65 5.2 0.65 7.6 0.65 6.6 0.65 2.6 0.655.5 0.65 3.0 0.7 5.2 0.7 7.6 0.7 6.5 0.7 2.6 0.7 5.4 0.7 3.0 0.75 5.00.75 7.5 0.75 6.3 0.75 2.6 0.75 5.1 0.75 3.0 0.8 4.7 0.8 7.1 0.8 6.1 0.82.5 0.8 4.8 0.8 2.9 0.85 4.3 0.80 6.5 0.85 5.6 0.85 2.3 0.85 4.3 0.852.7 0.9 3.7 0.9 5.5 0.9 4.7 0.9 2.0 0.9 3.6 0.9 2.4 0.95 2.7 0.95 3.80.95 3.4 0.95 1.7 0.95 2.6 0.95 1.9 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HFC-245cb-HFO-1234zeE-HFO-1234zeZ-HCFO-1233zdE-HFO-1243zf

Organics Organics Organics Organics Organics Organics 0.2 F245cb + 0.96F245cb + 0.01 F245cb + 0.01 F245cb + 0.01 F245cb + 0.01 F245cb + 0.2F1243zf + 0.01 F1243zf + 0.96 F1243zf + 0.01 F1243zf + 0.01 F1243zf +0.01 F1243zf + 0.2 F1233zdE 0.01 F1233zdE + 0.01 F1233zdE + 0.96F1233zdE + 0.01 F1233zdE + 0.01 F1233zdE + 0.2 F1234zeE + 0.01F1234zeE + 0.01 F1234zeE + 0.01 F1234zeE + 0.96 F1234zeE + 0.01F1234zeE + 0.2 F1234zeZ 0.01 F1234zeZ 0.01 F1234zeZ 0.01 F1234zeZ 0.01F1234zeZ 0.96 F1234zeZ TOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES-MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- FRAC SUREFRAC SURE FRAC SURE FRAC SURE FRAC SURE FRAC SURE HF bar HF bar HF barHF bar HF bar HF bar 0 3.8 0 4.6 0 5.8 0 1.5 0 4.8 0 1.9 0.05 4.9 0.055.8 0.05 6.7 0.05 2.6 0.05 5.8 0.05 3.0 0.1 4.9 0.1 5.8 0.1 6.7 0.1 2.60.1 5.8 0.1 3.0 0.15 4.9 0.15 5.8 0.15 6.7 0.15 2.6 0.15 5.8 0.15 3.00.2 4.9 0.2 5.8 0.2 6.7 0.2 2.6 0.2 5.8 0.2 3.0 0.25 4.9 0.25 5.8 0.256.7 0.25 2.6 0.25 5.8 0.25 3.0 0.3 4.9 0.3 5.8 0.3 6.7 0.3 2.6 0.3 5.80.3 3.0 0.35 4.9 0.35 5.8 0.35 6.7 0.35 2.6 0.35 5.8 0.35 3.0 0.4 4.90.4 5.8 0.4 6.7 0.4 2.6 0.4 5.8 0.4 3.0 0.45 4.9 0.45 5.8 0.45 6.7 0.452.6 0.45 5.8 0.45 3.0 0.5 4.9 0.5 5.8 0.5 6.7 0.5 2.6 0.5 5.7 0.5 3.00.55 4.9 0.55 5.8 0.55 6.7 0.55 2.6 0.55 5.7 0.55 3.0 0.6 4.9 0.6 5.80.6 6.6 0.6 2.6 0.6 5.6 0.6 3.0 0.65 4.9 0.65 5.8 0.65 6.6 0.65 2.6 0.655.5 0.65 3.0 0.7 4.9 0.7 5.8 0.7 6.5 0.7 2.6 0.7 5.4 0.7 3.0 0.75 4.80.75 5.8 0.75 6.3 0.75 2.6 0.75 5.1 0.75 3.0 0.8 4.5 0.8 5.8 0.8 6.0 0.82.4 0.8 4.8 0.8 2.9 0.85 4.2 0.85 5.0 0.85 5.6 0.85 2.3 0.85 4.3 0.852.7 0.9 3.5 0.9 5.0 0.9 4.7 0.9 2.0 0.9 3.6 0.9 2.4 0.95 2.6 0.95 3.50.95 3.4 0.95 1.7 0.95 2.6 0.95 1.9 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

EXAMPLE 11: TEMPERATURE AND PRESSURE RANGE OF SYSTEMS WITH 6 COMPOUNDS

Boiling point range Temperature Pressure System with 6 compounds ° C.bar abs HF-HCFO-1233xf-HFO-1234yf-HFC-245cb- 0 to 40 ~1.0 to ~11.6HFO-1234zeE-HFO-1243zf HF-HCFO-1233xf-HFO-1234yf-HFC-245cb- 0 to 40 ~1.0to ~11.6 HFO-1234zeZ-HFO-1243zf HF-HCFO-1233xf-HFO-1234yf-HFC-245cb- 0to 40 ~0.9 to ~11.6 HCFO-1233zdE-HFO-1243zfHF-HCFO-1233xf-HFO-1234yf-HFO- 0 to 40 ~1.0 to ~11.61234zeE-HFO-1234zeZ-HFO-1243zf HF-HCFO-1233xf-HFO-1234yf-HFO- 0 to 40~0.9 to ~11.6 1234zeE-HCFO-1233zdE-HFO-1243zfHF-HCFO-1233xf-HFO-1234yf-HFO- 0 to 40 ~0.9 to ~11.61234zeZ-HCFO-1233zdE-HFO-1243zf HF-HCFO-1233xf-HFC-245cb-HFO- 0 to 40~1.0 to ~10.3 1234zeE-HFO-1234zeZ-HFO-1243zfHF-HCFO-1233xf-HFC-245cb-HFO- 0 to 40 ~0.9 to ~10.31234zeE-HCFO-1233zdE-HFO-1243zf HF-HCFO-1233xf-HFC-245cb-HFO- 0 to 40~1.0 to ~10.3 1234zeZ-HCFO-1233zdE-HFO-1243zfHF-HCFO-1233xf-HFO-1234zeE-HFO- 0 to 40 ~0.9 to ~10.31234zeZ-HCFO-1233zdE-HFO-1243zf HF-HFO-1234yf-HFC-245cb-HFO-1234zeE- 0to 40 ~1.2 to ~11.6 HFO-1234zeZ-HFO-1243zfHF-HFO-1234yf-HFC-245cb-HFO-1234zeE- 0 to 40 ~1.0 to ~11.7HCFO-1233zdE-HFO-1243zf HF-HFO-1234yf-HFC-245cb-HFO-1234zeZ- 0 to 40~0.9 to ~11.6 HCFO-1233zdE-HFO-1243zf HF-HFO-1234yf-HFO-1234zeE-HFO- 0to 40 ~0.9 to ~11.6 1234zeZ-HCFO-1233zdE-HFO-1243zfHF-HFC-245cb-HFO-1234zeE-HFO- 0 to 40 ~0.9 to ~10.31234zeZ-HCFO-1233zdE-HFO-1243zf

EXAMPLE 12: DECANTATION RANGE OF SYSTEMS WITH 6 COMPOUNDS

Decantation ranges Mass percentage of HF Isotherm Isotherm IsothermSystem with 6 compounds 0° C. 25° C. 40° C.HF-HCFO-1233xf-HFO-1234yf-HFC-245cb- 5-75 10-65 * HFO-1234zeE-HFO-1243zfHF-HCFO-1233xf-HFO-1234yf-HFC-245cb- 5-75 10-70 15-50HFO-1234zeZ-HFO-1243zf HF-HCFO-1233xf-HFO-1234yf-HFC-245cb- 5-75  5-7015-55 HCFO-1233zdE-HFO-1243zf HF-HCFO-1233xf-HFO-1234yf-HFO- 5-7010-65 * 1234zeE-HFO-1234zeZ-HFO-1243zf HF-HCFO-1233xf-HFO-1234yf-HFO-5-70 10-75 * 1234zeE-HCFO-1233zdE-HFO-1243zfHF-HCFO-1233xf-HFO-1234yf-HFO- 5-75  5-70 10-551234zeZ-HCFO-1233zdE-HFO-1243zf HF-HCFO-1233xf-HFC-245cb-HFO- 5-75 10-7015-45 1234zeE-HFO-1234zeZ-HFO-1243zf HF-HCFO-1233xf-HFC-245cb-HFO- 5-75 5-70 15-50 1234zeE-HCFO-1233zdE-HFO-1243zfHF-HCFO-1233xf-HFC-245cb-HFO- 5-75  5-70 10-651234zeZ-HCFO-1233zdE-HFO-1243zf HF-HCFO-1233xf-HFO-1234zeE-HFO- 5-75 5-65 10-55 1234zeZ-HCFO-1233zdE-HFO-1243zfHF-HFO-1234yf-HFC-245cb-HFO-1234zeE- 5-75 10-65 * HFO-1234zeZ-HFO-1243zfHF-HFO-1234yf-HFC-245cb-HFO-1234zeE- 5-75 10-65 *HCFO-1233zdE-HFO-1243zf HF-HFO-1234yf-HFC-245cb-HFO-1234zeZ- 5-75 10-7015-55 HCFO-1233zdE-HFO-1243zf HF-HFO-1234yf-HFO-1234zeE-HFO- 5-7010-65 * 1234zeZ-HCFO-1233zdE-HFO-1243zf HF-HFC-245cb-HFO-1234zeE-HFO-5-75  5-70 15-50 1234zeZ-HCFO-1233zdE-HFO-1243zf

EXAMPLE 13: SYSTEMS WITH SEVEN COMPOUNDS, ISOTHERM AT 25° C.

HF-HCFO-1233xf-HFC-245cb-HCFO-1233zdE-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf

Organics Organics Organics Organics Organics Organics Organics 0.15F1233xf + 0.95 F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.01 F1233xf +0.01 F1233xf + 0.01 F1233xf + 0.17 F245cb + 0.01 F245cb + 0.95 F245cb +0.01 F245cb + 0.01 F245cb + 0.01 F245cb + 0.01 F245cb + 0.17 F1233zdE +0.01 F1233zdE + 0.01 F1233zdE + 0.95 F1233zdE + 0.01 F1233zdE + 0.01F1233zdE + 0.01 F1233zdE + 0.17 F1234zeE + 0.01 F1234zeE + 0.01F1234zeE + 0.01 F1234zeE + 0.95 F1234zeE + 0.01 F1234zeE + 0.01F1234zeE + 0.17 F1234zeZ + 0.01 F1234zeZ + 0.01 F1234zeZ + 0.01F1234zeZ + 0.01 F1234zeZ + 0.01 F1234zeZ + 0.95 F1234zeZ + 0.17 F1243zf0.01 F1243zf 0.01 F1243zf 0.01 F1243zf 0.01 F1243zf 0.95 F1243zf 0.01F1243zf TOTAL TOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES- MASS-PRES- MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- FRACSURE FRAC SURE FRAC SURE FRAC SURE FRAC SURE FRAC SURE FRAC SURE HF barHF bar HF bar HF bar HF bar HF bar HF bar 0 3.5 0 1.7 0 4.5 0 1.5 0 4.80 5.7 0 1.9 0.05 4.6 0.05 2.8 0.05 5.7 0.05 2.6 0.05 5.7 0.05 6.7 0.053.0 0.1 4.6 0.1 2.8 0.1 5.7 0.1 2.6 0.1 5.8 0.1 6.7 0.1 3.0 0.15 4.60.15 2.8 0.15 5.7 0.15 2.6 0.15 5.8 0.15 6.7 0.15 3.0 0.2 4.6 0.2 2.80.2 5.7 0.2 2.6 0.2 5.8 0.2 6.7 0.2 3.0 0.25 4.6 0.25 2.8 0.25 5.8 0.252.6 0.25 5.8 0.25 6.7 0.25 3.0 0.3 4.6 0.3 2.8 0.3 5.8 0.3 2.6 0.3 5.80.3 6.7 0.3 3.0 0.35 4.6 0.35 2.8 0.35 5.8 0.35 2.6 0.35 5.8 0.35 6.70.35 3.0 0.4 4.6 0.4 2.8 0.4 5.8 0.4 2.6 0.4 5.8 0.4 6.7 0.4 3.0 0.454.6 0.45 2.8 0.45 5.8 0.45 2.6 0.45 5.7 0.45 6.7 0.45 3.0 0.5 4.6 0.52.8 0.5 5.8 0.5 2.6 0.5 5.7 0.5 6.7 0.5 3.0 0.55 4.6 0.55 2.8 0.55 5.80.55 2.6 0.55 5.7 0.55 6.6 0.55 3.0 0.5 4.6 0.6 2.8 0.6 5.8 0.6 2.6 0.65.6 0.6 6.6 0.6 3.0 0.65 4.6 0.55 2.8 0.65 5.8 0.65 2.6 0.65 5.5 0.656.6 0.65 3.0 0.7 4.6 0.7 2.8 0.7 5.8 0.7 2.6 0.7 5.3 0.7 6.6 0.7 3.00.75 4.5 0.75 2.8 0.75 5.8 0.75 2.6 0.75 5.1 0.75 6.2 0.75 3.0 0.8 4.20.8 2.6 0.8 5.8 0.8 2.4 0.8 4.8 0.8 6.0 0.8 2.9 0.85 3.9 0.85 2.4 0.855.8 0.85 2.3 0.85 4.3 0.85 5.5 0.85 2.7 0.9 3.3 0.9 2.2 0.9 4.9 0.9 2.00.9 3.6 0.9 4.7 0.9 2.4 0.95 2.5 0.95 1.8 0.95 3.5 0.95 1.7 0.95 2.60.95 3.3 0.95 1.9 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HCFO-1233zdE-HFO-1234zeE-HFO-1243zf

Organics Organics Organics Organics Organics Organics Organics 0.15F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.01 F1233xf +0.01 F1233xf + 0.95 F1233xf + 0.17 F1234yf + 0.95 F1234yf + 0.01F1234yf + 0.01 F1234yf + 0.01 F1234yf + 0.01 F1234yf + 0.01 F1234yf +0.17 F245cb + 0.01 F245cb + 0.95 F245cb + 0.01 F245cb + 0.01 F245cb +0.01 F245cb + 0.01 F245cb + 0.17 F1233zdE + 0.01 F1233zdE + 0.01F1233zdE + 0.95 F1233zdE + 0.01 F1233zdE + 0.01 F1233zdE + 0.01F1233zdE + 0.17 F1234zeE + 0.01 F1234zeE + 0.01 F1234zeE + 0.01F1234zeE + 0.95 F1234zeE + 0.01 F1234zeE + 0.01 F1234zeE + 0.17 F1243zf0.01 F1243zf 0.01 F1243zf 0.01 F1243zf 0.01 F1243zf 0.95 F1243zf 0.01F1243zf TOTAL TOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES- MASS-PRES- MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- FRACSURE FRAC SURE FRAC SURE FRAC SURE FRAC SURE FRAC SURE FRAC SURE HF barHF bar HF bar HF bar HF bar HF bar HF bar 0 4.4 0 6.6 0 4.6 0 1.5 0 4.80 5.8 0 1.7 0.05 5.4 0.05 7.6 0.05 5.8 0.05 2.6 0.05 5.8 0.05 6.7 0.052.8 0.1 5.4 0.1 7.6 0.1 5.8 0.1 2.6 0.1 5.8 0.1 6.7 0.1 2.8 0.15 5.40.15 7.6 0.15 5.8 0.15 2.6 0.15 5.8 0.15 6.7 0.15 2.8 0.2 5.4 0.2 7.60.2 5.8 0.2 2.6 0.2 5.8 0.2 6.7 0.2 2.8 0.25 5.4 0.25 7.6 0.25 5.8 0.252.6 0.25 5.8 0.25 6.7 0.25 2.8 0.3 5.4 0.3 7.6 0.3 5.8 0.3 2.6 0.3 5.80.3 6.7 0.3 2.8 0.35 5.4 0.35 7.6 0.35 5.8 0.35 2.6 0.35 5.8 0.35 6.70.35 2.8 0.4 5.4 0.4 7.6 0.4 5.8 0.4 2.6 0.4 5.8 0.4 6.7 0.4 2.8 0.455.4 0.45 7.6 0.45 5.8 0.45 2.6 0.45 5.8 0.45 6.7 0.45 2.8 0.5 5.4 0.57.6 0.5 5.8 0.5 2.6 0.5 5.8 0.5 6.7 0.5 2.8 0.55 5.4 0.55 7.6 0.55 5.80.55 2.6 0.55 5.7 0.55 6.7 0.55 2.8 0.6 5.4 0.6 7.6 0.6 5.8 0.6 2.6 0.65.6 0.6 6.7 0.6 2.8 0.65 5.4 0.65 7.6 0.65 5.8 0.65 2.6 0.65 5.5 0.656.6 0.65 2.8 0.7 5.4 0.7 7.6 0.7 5.8 0.7 2.6 0.7 5.4 0.7 6.5 0.7 2.80.75 5.3 0.75 7.4 0.75 5.8 0.75 2.6 0.75 5.1 0.75 6.3 0.75 2.8 0.8 5.00.8 7.1 0.8 5.8 0.8 2.5 0.8 4.8 0.8 6.1 0.8 2.7 0.85 4.6 0.85 6.5 0.855.8 0.85 2.3 0.85 4.3 0.85 5.6 0.85 2.5 0.9 3.9 0.9 5.5 0.9 5.0 0.9 2.10.9 3.6 0.9 4.7 0.9 2.2 0.95 2.8 0.95 3.8 0.95 3.5 0.95 1.7 0.95 2.60.95 3.4 0.95 1.8 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HCFO-1233zdE-HFO-1234zeZ-HFO-1243zf

Organics Organics Organics Organics Organics Organics Organics 0.15F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.01 F1233xf +0.01 F1233xf + 0.95 F1233xf + 0.17 F1234yf + 0.95 F1234yf + 0.01F1234yf + 0.01 F1234yf + 0.01 F1234yf + 0.01 F1234yf + 0.01 F1234yf +0.17 F245cb + 0.01 F245cb + 0.95 F245cb + 0.01 F245cb + 0.01 F245cb +0.01 F245cb + 0.01 F245cb + 0.17 F1243zf + 0.01 F1243zf + 0.01 F1243zf +0.95 F1243zf + 0.01 F1243zf + 0.01 F1243zf + 0.01 F1243zf + 0.17F1233zdE + 0.01 F1233zdE + 0.01 F1233zdE + 0.01 F1233zdE + 0.95F1233zdE + 0.01 F1233zdE + 0.01 F1233zdE + 0.17 F1234zeZ 0.01 F1234zeZ0.01 F1234zeZ 0.01 F1234zeZ 0.01 F1234zeZ 0.95 F1234zeZ 0.01 F1234zeZTOTAL TOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES- MASS- PRES- MASS-PRES- MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- FRAC SURE FRACSURE FRAC SURE FRAC SURE FRAC SURE FRAC SURE FRAC SURE HF bar HF bar HFbar HF bar HF bar HF bar HF bar 0 3.8 0 6.6 0 4.6 0 5.7 0 1.5 0 1.9 01.7 0.05 4.9 0.05 7.6 0.05 5.8 0.05 6.7 0.05 2.6 0.05 3.0 0.05 2.8 0.14.9 0.1 7.6 0.1 5.8 0.1 6.7 0.1 2.6 0.1 3.0 0.1 2.8 0.15 4.9 0.15 7.60.15 5.8 0.15 6.7 0.15 2.6 0.15 3.0 0.15 2.8 0.2 4.9 0.2 7.6 0.2 5.8 0.26.7 0.2 2.6 0.2 3.0 0.2 2.8 0.25 4.9 0.25 7.6 0.25 5.8 0.25 6.7 0.25 2.60.25 3.0 0.25 2.8 0.3 4.9 0.3 7.6 0.3 5.8 0.3 6.7 0.3 2.6 0.3 3.0 0.32.8 0.35 4.9 0.35 7.6 0.35 5.8 0.35 6.7 0.35 2.6 0.35 3.0 0.35 2.8 0.44.9 0.4 7.6 0.4 5.8 0.4 6.7 0.4 2.6 0.4 3.0 0.4 2.8 0.45 4.9 0.45 7.60.45 5.8 0.45 6.7 0.45 2.6 0.45 3.0 0.45 2.8 0.5 4.9 0.5 7.6 0.5 5.8 0.56.7 0.5 2.6 0.5 3.0 0.5 2.8 0.55 4.9 0.55 7.6 0.55 5.3 0.55 6.7 0.55 2.60.55 3.0 0.55 2.8 0.6 4.9 0.6 7.6 0.6 5.8 0.6 6.6 0.6 2.6 0.6 3.0 0.62.8 0.65 4.9 0.65 7.6 0.65 5.8 0.65 6.6 0.65 2.6 0.65 3.0 0.65 2.8 0.74.9 0.7 7.6 0.7 5.8 0.7 6.5 0.7 2.6 0.7 3.0 0.7 2.8 0.75 4.9 0.75 7.40.75 5.8 0.75 6.3 0.75 2.6 0.75 3.0 0.75 2.8 0.8 4.7 0.8 7.1 0.8 5.8 0.86.0 0.8 2.5 0.8 2.9 0.8 2.7 0.85 4.3 0.85 6.5 0.85 5.8 0.85 5.5 0.85 2.30.85 2.7 0.85 2.5 0.9 3.7 0.9 5.5 0.9 5.0 0.9 4.7 0.9 2.0 0.9 2.4 0.92.2 0.95 2.7 0.95 3.8 0.95 3.5 0.95 3.3 0.95 1.7 0.95 1.9 0.95 1.8 1 1.21 1.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf

Organics Organics Organics Organics Organics Organics Organics 0.15F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.01 F1233xf +0.01 F1233xf + 0.95 F1233xf + 0.17 F1234yf + 0.95 F1234yf + 0.01F1234yf + 0.01 F1234yf + 0.01 F1234yf + 0.01 F1234yf + 0.01 F1234yf +0.17 F245cb + 0.01 F243cb + 0.95 F245cb + 0.01 F245cb + 0.01 F245cb +0.01 F245cb + 0.01 F245cb + 0.17 F1243zf + 0.01 F1243zf + 0.01 F1243zf +0.95 F1243zf + 0.01 F1243zf + 0.01 F1243zf + 0.01 F1243zf + 0.17F1234zeE + 0.01 F1234zeE + 0.01 F1234zeE + 0.01 F1234zeE + 0.95F1234zeE + 0.01 F1234zeE + 0.01 F1234zeE + 0.17 F1234zeZ 0.01 F1234zeZ0.01 F1234zeZ 0.01 F1234zeZ 0.01 F1234zeZ 0.95 F1234zeZ 0.01 F1234zeZTOTAL TOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES- MASS- PRES- MASS-PRES- MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- FRAC SURE FRACSURE FRAC SURE FRAC SURE FRAC SURE FRAC SURE FRAC SURE HF bar HF bar HFbar HF bar HF bar HF bar HF bar 0 4.4 0 6.5 0 4.6 0 5.8 0 4.8 0 2.0 01.7 0.05 5.5 0.05 7.6 0.05 5.8 0.05 6.7 0.05 5.8 0.05 3.1 0.05 2.8 0.15.5 0.1 7.6 0.1 5.8 0.1 6.7 0.1 5.8 0.1 3.1 0.1 2.8 0.15 5.5 0.15 7.60.15 5.8 0.15 6.7 0.15 5.8 0.15 3.1 0.15 2.8 0.2 5.5 0.2 7.6 0.2 5.8 0.26.7 0.2 5.8 0.2 3.1 0.2 2.8 0.25 5.5 0.25 7.6 0.25 5.8 0.25 6.7 0.25 5.80.25 3.1 0.25 2.8 0.3 5.5 0.3 7.6 0.3 5.8 0.3 6.7 0.3 5.8 0.3 3.1 0.32.8 0.35 5.5 0.35 7.6 0.35 5.8 0.35 6.7 0.35 5.8 0.35 3.1 0.35 2.8 0.45.5 0.4 7.6 0.4 5.8 0.4 6.7 0.4 5.8 0.4 3.1 0.4 2.8 0.45 5.5 0.45 7.60.45 5.8 0.45 6.7 0.45 5.8 0.45 3.1 0.45 2.8 0.5 5.5 0.5 7.6 0.5 5.8 0.56.7 0.5 5.8 0.5 3.1 0.5 2.8 0.55 5.5 0.55 7.6 0.55 5.8 0.55 6.7 0.55 5.70.55 3.1 0.55 2.8 0.6 5.5 0.6 7.6 0.6 5.8 0.6 6.7 0.6 5.6 0.6 3.1 0.62.8 0.65 5.5 0.65 7.6 0.55 5.8 0.65 6.6 0.65 5.5 0.65 3.1 0.65 2.8 0.75.5 0.7 7.6 0.7 5.8 0.7 6.5 0.7 5.4 0.7 3.1 0.7 2.8 0.75 5.3 0.75 7.40.75 5.8 0.75 6.3 0.75 5.1 0.75 3.1 0.75 2.8 0.8 5.1 0.8 7.1 0.8 5.8 0.86.1 0.8 4.8 0.8 2.9 0.8 2.7 0.85 4.6 0.85 6.5 0.85 5.8 0.85 5.6 0.85 4.30.85 2.7 0.85 2.5 0.9 3.9 0.9 5.5 0.9 5.0 0.9 4.7 0.9 3.6 0.9 2.4 0.92.2 0.95 2.8 0.95 3.8 0.95 3.5 0.95 3.4 0.95 2.6 0.95 1.9 0.95 1.8 1 1.21 1.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HCFO-1233xf-HFO-1234yf-HCFO-1233zdE-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf

Organics Organics Organics Organics Organics Organics Organics 0.15F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.01 F1233xf +0.01 F1233xf + 0.95 F1233xf + 0.17 F1234yf + 0.95 F1234yf + 0.01F1234yf + 0.01 F1234yf + 0.01 F1234yf + 0.01 F1234yf + 0.01 F1234yf +0.17 F1233zdE + 0.01 F1233zdE + 0.95 F1233zdE + 0.01 F1233zdE + 0.01F1233zdE + 0.01 F1233zdE + 0.01 F1233zdE + 0.17 F1243zf + 0.01 F1243zf +0.01 F1243zf + 0.95 F1243zf + 0.01 F1243zf + 0.01 F1243zf + 0.01F1243zf + 0.17 F1234zeE + 0.01 F1234zeE + 0.01 F1234zeE + 0.01F1234zeE + 0.95 F1234zeE + 0.01 F1234zeE + 0.01 F1234zeE + 0.17 F1234zeZ0.01 F1234zeZ 0.01 F1234zeZ 0.01 F1234zeZ 0.01 F1234zeZ 0.95 F1234zeZ0.01 F1234zeZ TOTAL TOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES-MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES-FRAC SURE FRAC SURE FRAC SURE FRAC SURE FRAC SURE FRAC SURE FRAC SURE HFbar HF bar HF bar HF bar HF bar HF bar HF bar 0 3.9 0 6.6 0 1.9 0 5.7 04.8 0 1.9 0 1.7 0.05 5.0 0.05 7.6 0.05 2.6 0.05 6.7 0.05 5.8 0.05 3.00.05 2.8 0.1 4.9 0.1 7.6 0.1 2.6 0.1 6.7 0.1 5.8 0.1 3.0 0.1 2.8 0.154.9 0.15 7.6 0.15 2.6 0.15 6.7 0.15 5.8 0.15 3.0 0.15 2.8 0.2 4.9 0.27.6 0.2 2.6 0.2 6.7 0.2 5.8 0.2 3.0 0.3 2.8 0.25 4.9 0.25 7.6 0.25 2.60.25 6.7 0.25 5.8 0.25 3.0 0.25 2.8 0.3 4.9 0.3 7.6 0.3 2.6 0.3 6.7 0.35.8 0.3 3.0 0.3 2.8 0.35 4.9 0.35 7.6 0.35 2.6 0.35 6.7 0.35 5.8 0.353.0 0.35 2.8 0.4 4.9 0.4 7.6 0.4 2.6 0.4 6.7 0.4 5.8 0.4 3.0 0.4 2.80.45 4.9 0.45 7.6 0.45 2.6 0.45 6.7 0.45 5.8 0.45 3.0 0.45 2.8 0.5 4.90.5 7.6 0.5 2.6 0.5 6.7 0.5 5.7 0.5 3.0 0.5 2.8 0.55 4.9 0.55 7.6 0.552.6 0.55 6.7 0.55 5.7 0.55 3.0 0.55 2.8 0.6 4.9 0.6 7.6 0.6 2.6 0.6 6.60.6 5.6 0.6 3.0 0.5 2.8 0.65 4.9 0.65 7.6 0.65 2.6 0.65 6.5 0.65 5.50.65 3.0 0.65 2.8 0.7 4.8 0.7 7.6 0.7 2.6 0.7 6.5 0.7 5.3 0.7 3.0 0.72.8 0.75 4.7 0.75 7.4 0.75 2.6 0.75 6.3 0.75 5.1 0.75 3.0 0.75 2.8 0.84.4 0.8 7.1 0.8 2.5 0.8 6.0 0.8 4.8 0.8 2.9 0.8 2.6 0.85 4.0 0.85 6.50.85 2.3 0.85 5.5 0.85 4.3 0.85 2.7 0.85 2.5 0.9 3.4 0.9 5.5 0.9 2.0 0.94.7 0.9 3.6 0.9 2.4 0.9 2.2 0.95 2.5 0.95 3.8 0.95 1.7 0.95 3.3 0.95 2.60.95 1.9 0.95 1.8 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HFO-1234yf-HFC-245cb-HCFO-1233zdE-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf

Organics Organics Organics Organics Organics Organics Organics 0.15F1234yf + 0.95 F1234yf + 0.01 F1234yf + 0.01 F1234yf + 0.01 F1234yf +0.01 F1234yf + 0.01 F1234yf + 0.17 F245cb + 0.01 F245cb + 0.95 F245cb +0.01 F245cb + 0.01 F245cb + 0.01 F245cb + 0.01 F245cb + 0.17 F1233zdE +0.01 F1233zdE + 0.01 F1233zdE + 0.95 F1233zdE + 0.01 F1233zdE + 0.01F1233zdE + 0.01 F1233zdE + 0.17 F1234zeE + 0.01 F1234zeE + 0.01F1234zeE + 0.01 F1234zeE + 0.95 F1234zeE + 0.01 F1234zeE + 0.01F1234zeE + 0.17 F1234zeZ + 0.01 F1234zeZ + 0.01 F1234zeZ + 0.01F1234zeZ + 0.01 F1234zeZ + 0.01 F1234zeZ + 0.95 F1234zeZ + 0.17 F1243zf0.01 F1243zf 0.01 F1243zf 0.01 F1243zf 0.01 F1243zf 0.95 F1243zf 0.01F1243zf TOTAL TOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES- MASS-PRES- MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- FRACSURE FRAC SURE FRAC SURE FRAC SURE FRAC SURE FRAC SURE FRAC SURE HF barHF bar HF bar HF bar HF bar HF bar HF bar 0 4.3 0 6.6 0 4.6 0 1.5 0 4.80 5.8 0 2.0 0.05 5.3 0.05 7.6 0.05 5.8 0.05 2.6 0.05 5.8 0.05 6.7 0.053.1 0.1 5.3 0.1 7.6 0.1 5.8 0.1 2.6 0.1 5.8 0.1 6.7 0.1 3.1 0.15 5.30.15 7.6 0.15 5.8 0.15 2.6 0.15 5.8 0.15 6.7 0.15 3.1 0.2 5.3 0.2 7.60.2 5.8 0.2 2.6 0.2 5.8 0.2 6.7 0.2 3.1 0.25 5.3 0.25 7.6 0.25 5.8 0.252.6 0.25 5.8 0.25 6.7 0.25 3.1 0.3 5.3 0.3 7.6 0.3 5.8 0.3 2.6 0.3 5.80.3 6.7 0.3 3.1 0.35 5.3 0.35 7.6 0.35 5.8 0.35 2.6 0.35 5.8 0.35 6.70.35 3.1 0.4 5.3 0.4 7.6 0.4 5.8 0.4 2.6 0.4 5.8 0.4 6.7 0.4 3.1 0.455.3 0.45 7.6 0.45 5.8 0.45 2.6 0.45 5.8 0.45 6.7 0.45 3.1 0.5 5.3 0.57.6 0.5 5.8 0.5 2.6 0.5 5.8 0.5 6.7 0.5 3.1 0.55 5.3 0.55 7.6 0.55 5.80.55 2.6 0.55 5.7 0.55 6.7 0.55 3.1 0.6 5.3 0.6 7.6 0.6 5.8 0.6 2.6 0.65.6 0.6 6.7 0.5 3.1 0.65 5.3 0.65 7.6 0.65 5.8 0.65 2.6 0.65 5.5 0.656.6 0.65 3.1 0.7 5.3 0.7 7.6 0.7 5.8 0.7 2.6 0.7 5.4 0.7 6.5 0.7 3.10.75 5.2 0.75 7.4 0.75 5.8 0.75 2.6 0.75 5.1 0.75 6.3 0.75 3.1 0.8 4.90.8 7.1 0.8 5.8 0.8 2.5 0.8 4.3 0.8 6.1 0.8 2.9 0.85 4.5 0.85 6.5 0.855.8 0.85 2.3 0.85 4.3 0.85 5.6 0.85 2.7 0.9 3.9 0.9 5.5 0.9 5.0 0.9 2.10.9 3.6 0.9 4.7 0.9 2.4 0.95 2.8 0.95 3.8 0.95 3.5 0.95 1.7 0.95 2.60.95 3.4 0.95 1.9 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

HF-HFF-1243zf-HCFC-244bb-HFC-245fa-Trifluoropropyne-HFO-1225yeZ-HFO-1225zc

Organics Organics Organics Organics Organics Organics Organics 0.15F1243zf + 0.95 F1243zf + 0.01 F1243zf + 0.01 F1243zf + 0.01 F1243zf +0.01 F1243zf + 0.01 F1243zf + 0.17 F244bb + 0.01 F244bb + 0.95 F244bb +0.01 F244bb + 0.01 F244bb + 0.01 F244bb + 0.01 F244bb + 0.17 F245fa +0.01 F245fa + 0.01 F245fa + 0.95 F245fa + 0.01 F245fa + 0.01 F245fa +0.01 F245fa + 0.17 TFP + 0.01 TFP + 0.01 TFP + 0.01 TFP + 0.95 TFP +0.01 TFP + 0.01 TFP + 0.17 F1225yeZ + 0.01 F1225yeZ + 0.01 F1225yeZ +0.01 F1225yeZ + 0.01 F1225yeZ + 0.95 F1225yeZ + 0.01 F1225yeZ + 0.17F1225zc 0.01 F1225zc 0.01 F1225zc 0.01 F1225zc 0.01 F1225zc 0.01 F1225zc0.95 F1225zc TOTAL TOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES- PRES-PRES- PRES- PRES- PRES- PRES- FRAC SURE SURE SURE SURE SURE SURE SURE HFbar bar bar bar bar bar bar 0 5.5 5.8 1.0 1.8 11.3 5.2 5.3 0.05 6.5 6.82.1 2.9 12.1 6.2 6.3 0.1 6.5 6.8 2.1 2.9 12.0 6.2 6.3 0.15 6.4 6.8 2.12.9 11.9 6.2 6.3 0.2 6.4 6.8 2.1 2.9 11.8 6.2 6.3 0.25 6.4 6.8 2.1 2.911.7 6.2 6.3 0.3 6.4 6.8 2.1 2.9 11.6 6.2 6.3 0.35 6.4 6.8 2.1 2.9 11.56.2 6.3 0.4 6.4 6.8 2.1 2.9 11.5 6.2 6.3 0.45 6.4 6.8 2.1 2.9 11.5 6.26.3 0.5 6.3 6.7 2.1 2.9 11.5 6.2 6.3 0.55 6.3 6.7 2.1 2.9 11.5 6.2 6.20.6 6.3 6.7 2.1 2.9 11.6 6.2 6.1 0.65 6.2 6.6 2.1 2.9 11.6 6.2 6.0 0.76.2 6.6 2.1 2.9 11.7 6.1 5.9 0.75 6.0 6.4 2.0 2.8 11.6 5.9 5.6 0.8 5.76.1 2.0 2.8 11.3 5.6 5.2 0.85 5.2 5.6 2.0 2.6 10.5 5.1 4.7 0.9 4.4 4.81.9 2.3 8.9 4.2 3.9 0.95 3.1 3.4 1.6 1.6 6.0 3.0 2.7 1 1.2 1.2 1.2 1.21.2 1.2 1.2

EXAMPLE 14: TEMPERATURE AND PRESSURE RANGE OF SYSTEM WITH 7 COMPOUNDS

Boiling point range Temperature Pressure System with 7 compounds ° C.bar abs HC-HCFO-1233xf-HFO-1234yf-HFC-245cb- 0 to 40 ~1.0 to ~11.6HCFO-1233zdE-HFO-1234zeE-HFO-1243zf HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-0 to 40 ~0.9 to ~11.5 HCFO-1233zdE-HFO-1234zeZ-HFO-1243zfHF-HCFO-1233xf-HFO-1234yf-HFC-245cb- 0 to 40 ~1.1 to ~11.6HFO-1234zeE-HFO-1234zeZ-HFO-1243zf HF-HCFO-1233xf-HFO-1234yf-HCFO- 0 to40 ~0.9 to ~11.5 1233zdE-HFO-1234zeE-HFO-1234zeZ-HFO- 1243zfHF-HCFO-1233xf-HFC-245cb-HCFO- 0 to 40 ~0.9 to ~10.31233zdE-HFO-1234zeE-HFO-1234zeZ-HFO- 1243zfHF-HFO-1234yf-HFC-245b-HCFO-1233zdE- 0 to 40 ~1.0 to ~11.6HFO-1234zeE-HFO-1234zeZ-HFO-1243zf HF-HFF-1243zf-HCFC-244bb-HFC-245fa- 0to 40 ~0.7 to ~17.5 Trifluoropropyne-HFO-1225yeZ-HFO-1225zc

EXAMPLE 15: DECANTATION RANGE OF SYSTEMS WITH 7 COMPOUNDS

Decantation ranges Mass percentage of HF Temperature System with 7compounds 0° C. 25° C. 40° C. HC-HCFO-1233xf-HFO-1234yf-HFC-245cb- 5-7510-65 20 HCFO-1233zdE-HFO-1234zeE-HFO-1243zfHF-HCFO-1233xf-HFO-1234yf-HFC-245cb- 5-70  5-70 10-60HCFO-1233zdE-HFO-1234zeZ-HFO-1243zf HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-5-75 10-65 * HFO-1234zeE-HFO-1234zeZ-HFO-1243zfHF-HCFO-1233xf-HFO-1234yf-HCFO-1233zdE- 5-75 10-65 15-45HFO-1234zeE-HFO-1234zeZ-HFO-1243zfHF-HCFO-1233xf-HFC-245cb-HCFO-1233zdE- 5-75  5-70 10-55HFO-1234zeE-HFO-1234zeZ-HFO-1243zf HF-HFO-1234yf-HFC-245b-HCFO-1233zdE-5-75 10-65 * HFO-1234zeE-HFO-1234zeZ-HFO-1243zfHF-HFF-1243zf-HCFC-244bb-HFC-245fa- 5-75 10-70 *Trifluoropropyne-HFO-1225yeZ-HFO-1225zc

EXAMPLE 16: SYSTEMS WITH 8 COMPOUNDS

HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HCFO-1233zdE-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf

Organics Organics Organics Organics Organics Organics Organics 0.01F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.01 F1233xf + 0.01 F1233xf +0.01 F1233xf + 0.16 F1233xf + 0.94 F1234yf + 0.01 F1234yf + 0.01F1234yf + 0.01 F1234yf + 0.01 F1234yf + 0.01 F1234yf + 0.14 F1234yf +0.01 F245cb + 0.94 F245cb + 0.01 F245cb + 0.01 F245cb + 0.01 F245cb +0.01 F245cb + 0.14 F245cb + 0.01 F1233zdE + 0.01 F1233zdE + 0.94F1233zdE + 0.01 F1233zdE + 0.01 F1233zdE + 0.01 F1233zdE + 0.14F1233zdE + 0.01 F1234zeE + 0.01 F1234zeE + 0.01 F1234zeE + 0.94F1234zeE + 0.01 F1234zeE + 0.01 F1234zeE + 0.14 F1234zeE + 0.01F1234zeZ + 0.01 F1234zeZ + 0.01 F1234zeZ + 0.01 F1234zeZ + 0.94F1234zeZ + 0.01 F1234zeZ + 0.14 F1234zeZ + 0.01 F1243zf 0.01 F1243zf0.01 F1243zf 0.01 F1243zf 0.01 F1243zf 0.94 F1243zf 0.14 F1243zf TOTALTOTAL TOTAL TOTAL TOTAL TOTAL TOTAL MASS- PRES- MASS- PRES- MASS- PRES-MASS- PRES- MASS- PRES- MASS- PRES- MASS- PRES- FRAC SURE FRAC SURE FRACSURE FRAC SURE FRAC SURE FRAC SURE FRAC SURE HF bar HF bar HF bar HF barHF bar HF bar HF bar 0 6 0 4.6 0 1.5 0 4.8 0 2.0 0 5.7 0 3.9 0.05 7.60.05 5.8 0.05 2.6 0.05 5.8 0.05 3.1 0.05 6.7 0.05 5.0 0.1 7.6 0.1 5.80.1 2.6 0.1 5.8 0.1 3.1 0.1 6.7 0.1 5.0 0.15 7.6 0.15 5.8 0.15 2.6 0.155.8 0.15 3.1 0.15 6.7 0.15 5.0 0.2 7.6 0.2 5.8 0.2 2.6 0.2 5.8 0.2 3.10.2 6.7 0.2 5.0 0.25 7.6 0.25 5.8 0.25 2.6 0.25 5.8 0.25 3.1 0.25 6.70.25 5.0 0.3 7.6 0.3 5.8 0.3 2.6 0.3 5.8 0.3 3.1 0.3 6.7 0.3 5.0 0.357.6 0.35 5.8 0.35 2.6 0.35 5.8 0.35 3.1 0.35 6.7 0.35 5.0 0.4 7.6 0.45.8 0.4 2.6 0.4 5.8 0.4 3.1 0.4 6.7 0.4 5.0 0.45 7.6 0.45 5.8 0.45 2.60.45 5.8 0.45 3.1 0.45 6.7 0.45 5.0 0.5 7.6 0.5 5.8 0.5 2.6 0.5 5.7 0.53.1 0.5 6.7 0.5 5.0 0.55 7.6 0.55 5.8 0.55 2.6 0.55 5.7 0.55 3.1 0.556.7 0.55 5.0 0.6 7.6 0.6 5.8 0.6 2.6 0.6 5.6 0.6 3.1 0.6 6.6 0.6 5.00.65 7.6 0.65 5.8 0.65 2.6 0.65 5.5 0.65 3.1 0.65 6.6 0.65 5.0 0.7 7.50.7 5.8 0.7 2.6 0.7 5.4 0.7 3.1 0.7 6.5 0.7 5.0 0.75 7.4 0.75 5.8 0.752.6 0.75 5.1 0.75 3.1 0.75 6.3 0.75 4.9 0.8 7.1 0.8 5.8 0.8 2.5 0.8 4.80.8 2.9 0.8 6.0 0.8 4.6 0.85 6.5 0.85 5.8 0.85 2.3 0.85 4.3 0.85 2.70.85 5.5 0.85 4.2 0.9 5.5 0.9 5.0 0.9 2.1 0.9 3.6 0.9 2.4 0.9 4.7 0.93.9 0.95 3.0 0.95 3.5 0.95 1.7 0.95 2.6 0.95 1.9 0.95 3.3 0.95 2.6 1 1.21 1.2 1 1.2 1 1.2 1 1.2 1 1.2 1 1.2

EXAMPLE 17: TEMPERATURE AND PRESSURE RANGE OF SYSTEM WITH 8 COMPOUNDS

Boiling point range Temperature Pressure System with 8 compounds ° C.bar abs HF-HCFO-1233xf-HFO-1234yf-HFC- 0 to 40 ~1.0 to ~11.5245cb-HCFO-1233zdE-HFO-1234zeE- HFO-1234zeZ-HFO-1243zf

EXAMPLE 18: DECANTATION RANGES OF SYSTEM WITH 8 COMPOUNDS

Decantation ranges Mass percentage of HF Temperature System with 8compounds 0° C. 25° C. 40° C. HF-HCFO-1233xf-HFO-1234yf-HFC-245cb- 5-75%5-70% 15-50% HCFO-1233zdE-HFO-1234zeE-HFO-1234zeZ- HFO-1243zf

EXAMPLE 19: SYSTEMS WITH 13 COMPOUNDS

HF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HCFO-1233zdE-HFO-1234zeE-HFO-1234zeZ-HFC-1243zf-HCFC-244bb-TFP-HFC-245fa-HFO-1225yeZ-HFO-1225zc

Organics 0.087 Organics Organics Organics Organics 012346F + 0.087 0.88F1234yf + 0.01 F1234yf + 0.01 F1234yf + 0.01 F1234yf + F245cb + 0.0830.01 F245cb + 0.01 F245cb + 0.01 F245cb + 0.01 F245cb + F1233xf + 0.0830.01 F1233xf + 0.89 F1233xf + 0.01 F1233xf + 0.01 F1233xf + F1233zdE +0.083 0.01 F1233zdE + 0.01 F1233zdE + 0.01 F1233zdE + 0.89 F1233zdE +F1234zeE + 0.083 0.01 F1234zeE + 0.01 F1234zeE + 0.89 F1234zeE + 0.01F1234zeE + F1234zeZ + 0.083 0.01 F1234zeZ + 0.01 F1234zeZ + 0.01F1234zeZ + 0.01 F1234zeZ + F1243zf + 0.083 0.01 F1243zf + 0.01 F1243zf +0.01 F1243zf + 0.01 F1243zf + F244bb + 0.083 0.01 F244bb + 0.01 F244bb +0.01 F244bb + 0.01 F244bb + F245fa + 0.083 0.01 F245fa + 0.01 F245fa +0.01 F245fa + 0.01 F245fa + TFP + 0.083 0.01 TFP + 0.01 0.01 TFP + 0.010.01 TFP + 0.01 0.01 TFP + 0.01 F1225yeZ + 0.83 F1225yeZ + 0.1F1225yeZ + 0.1 F1225yeZ + 0.1 F1225yeZ + 0.1 F1225zc F1225zc F1225zcF1225zc F1225zc TOTAL TOTAL TOTAL TOTAL TOTAL MASSFRAC PRESSURE PRESSUREPRESSURE PRESSURE PRESSURE HF bar bar bar bar bar 0 4.5 6.5 1.0 4.8 1.70.05 5.6 7.5 3.0 5.8 2.9 0.1 5.6 7.5 3.0 5.8 2.9 0.15 5.6 7.5 3.0 5.82.8 0.2 5.6 7.5 3.0 5.8 2.8 0.25 5.6 7.5 3.0 5.8 2.8 0.3 5.6 7.5 3.0 5.82.8 0.35 5.6 7.5 3.0 5.8 2.8 0.4 5.6 7.5 3.0 5.8 2.8 0.45 5.5 7.5 3.05.8 2.8 0.5 5.5 7 5 3.0 5.8 2.8 0.55 5.5 7.5 3.0 5.7 2.8 0.6 5.5 7.5 3.05.6 2.8 0.65 5.5 7.5 3.0 5.5 2.8 0.7 5.4 7.5 3.0 5.4 2.8 0.75 5.3 7.33.0 5.2 2.8 0.8 5.1 7.0 2.8 4.8 2.7 0.85 4.6 6.4 2.8 4.3 2.5 0.9 3.9 5.42.3 3.6 2.2 0.95 2.8 3.7 1.8 2.6 1.8 1 1.2 1.2 1.2 1.2 1.2

EXAMPLE 20: TEMPERATURE AND PRESSURE RANGE OF SYSTEM WITH 13 COMPOUNDS

Boiling point range Temperature Pressure System with 13 compounds ° C.bar abs HF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HCFO-1233zdE- 0 to 40 ~0.7to ~18.0 HFO-1234zeE-HFO-1234zeZ-HFC-1243zf-HCFC-244bb-TFP-HFC-245fa-HFO-1225yeZ-HFO-1225zc

EXAMPLE 21: DECANTATION RANGES OF SYSTEM WITH 13 COMPOUNDS

Decantation ranges Mass percentage of HF Temperature System with 13compounds 0° C. 25° C. 40° C. HF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HCFO-5-75% 10-70% 15-60% 1233zdE-HFO-1234zeE-HFO-1234zeZ-HFC-1243zf-HCFC-244bb-TFP-HFC-245fa-HFO-1225yeZ-HFO-1225zc

The invention claimed is:
 1. An azeotropic or quasi-azeotropiccomposition comprising hydrogen fluoride, 3,3,3-trifluoropropene, andone or more compounds selected from the group consisting of1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene,E-3,3,3-trifluoro-1-chloropropene, 3,3,3-trifluoro-2-chloropropene, and1,3,3,3-tetrafluoropropene, in which the boiling point of saidcomposition is between −20° C. and 80° C. and at a pressure of between0.1 and 44 bar absolute.
 2. An azeotropic or quasi-azeotropiccomposition comprising hydrogen fluoride, 3,3,3-trifluoropropene, andone or more compounds selected from the group consisting of1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene,1,3,3,3-tetrafluoropropene, 3,3,3-trifluoro-2-chloropropene,E-3,3,3-trifluoro-1-chloropropene, trifluoropropyne,1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene,1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane, inwhich the boiling point of said composition is between −20° C. and 80°C. and at a pressure of between 0.1 and 44 bar absolute.
 3. Thecomposition as claimed in claim 1, in which the composition compriseshydrogen fluoride, 3,3,3-trifluoropropene and at least one or moreorganic compounds chosen from E-1,3,3,3-tetrafluoropropene,Z-1,3,3,3-tetrafluoropropene, 3,3,3-trifluoro-2-chloropropene,E-3,3,3-trifluoro-1-chloropropene, 1,1,1,2,2-pentafluoropropane and2,3,3,3-tetrafluoropropene.
 4. The composition as claimed in claim 1, inwhich the composition is heteroazeotropic or quasi-heteroazeotropic. 5.The composition as claimed in claim 1, in which the compositioncomprises hydrogen fluoride, 3,3,3-trifluoropropene,E-1,3,3,3-tetrafluoropropene and optionally one or more organiccompounds chosen from Z-1,3,3,3-tetrafluoropropene,3,3,3-trifluoro-2-chloropropene, E-3,3,3-trifluoro-1-chloropropene,1,1,1,2,2-pentafluoropropane and 2,3,3,3-tetrafluoropropene.
 6. Thecomposition as claimed in claim 1, in which the composition compriseshydrogen fluoride, 3,3,3-trifluoropropene, Z-1,3,3,3-tetrafluoropropeneand optionally one or more organic compounds chosen from3,3,3-trifluoro-2-chloropropene, E-3,3,3-trifluoro-1-chloropropene,1,1,1,2,2-pentafluoropropane and 2,3,3,3-tetrafluoropropene.
 7. Thecomposition as claimed in claim 1, in which the composition compriseshydrogen fluoride, 3,3,3-trifluoropropene,3,3,3-trifluoro-2-chloropropene and optionally one or more organiccompounds chosen from E-3,3,3-trifluoro-1-chloropropene,1,1,1,2,2-pentafluoropropane and 2,3,3,3-tetrafluoropropene.
 8. Thecomposition as claimed in claim 1, in which the composition compriseshydrogen fluoride, 3,3,3-trifluoropropene,E-3,3,3-trifluoro-1-chloropropene and optionally one or more organiccompounds chosen from 1,1,1,2,2-pentafluoropropane and2,3,3,3-tetrafluoropropene.
 9. The composition as claimed in claim 1, inwhich the composition comprises hydrogen fluoride,3,3,3-trifluoropropene, 1,1,1,2,2-pentafluoropropane and optionally2,3,3,3-tetrafluoropropene.
 10. The composition as claimed in claim 1,in which the composition comprises hydrogen fluoride,3,3,3-trifluoropropene and 2,3,3,3-tetrafluoropropene.
 11. Thecomposition as claimed in claim 1, in which the composition comprisesfrom 1% to 85% by weight of hydrogen fluoride and from 99% to 15% byweight of the sum of the organic compounds.
 12. The composition asclaimed in claim 1, in which the composition comprises from 5% to 80% byweight of hydrogen fluoride and from 95% to 20% by weight of the sum ofthe organic compounds.
 13. The composition as claimed in claim 1, inwhich the boiling point of said composition is between 0° C. and 40° C.and at a pressure of between 0.7 and 18 bar absolute.
 14. Thecomposition as claimed in claim 1, in which the boiling point of saidcomposition is between 0° C. and 40° C. and at a pressure of between 0.9and 12.5 bar absolute.
 15. The composition as claimed in claim 1,comprising two or more compounds selected from the group consisting of1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene,E-3,3,3-trifluoro-1-chloropropene, 3,3,3-trifluoro-2-chloropropene, and1,3,3,3-tetrafluoropropene.
 16. An azeotropic or quasi-azeotropiccomposition comprising hydrogen fluoride, 3,3,3-trifluoropropene andthree or more compounds selected from the group consisting of1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene,E-3,3,3-trifluoro-1-chloropropene, 3,3,3-trifluoro-2-chloropropene, and1,3,3,3-tetrafluoropropene.